• Title/Summary/Keyword: I-partition

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Slow-Stirring Methods for Determining the n-Octanol/Water Partition Coefficient(Pow) of Highly Hydrophobic Chemicals (극소수성 물질들에 대한 Slow-Stirring방법에 의한 옥탄올/물 분배계수 측정)

  • Chang Hee Ra;Lee Bong Jae;Kim Kyun;Kim Yong Hwa
    • Environmental Analysis Health and Toxicology
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    • v.20 no.4 s.51
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    • pp.351-358
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    • 2005
  • The n -octanol/water partition coefficient (Pow) is one of the most important parameters employed for estimating a chemiral's environmental fate and toxicity. The shake-flask method, one direct experimental method, i.1 prone to experimental artifacts for highly hydrophobic compounds. Thus, a valid method for direct determination of the Pow of highly hydrophobic compounds is needed. The slow -stirring method has been demonstrated to provide reliable log Pow data to log Pow greater than 5. This study was performed to evaluate the accuracy of slow- stirring experiment for determination of log Pow, particularly for highly hydrophobic compounds. 1, 2, 3, 4-tetrachlorobenzene, hexachlorobezene, 2, 2', 3, 3', 5, 5', 6, 6'-octachlorobiphenyl, decachlorobiphenyl, and p, p'-DDT (4.5$\times$0.02, 5.41$\times$0.06, 7.26$\times$0.04, 7.87$\times$0.10, and 6.03$\times$0.06, respectively. The octanol/water partition coefficient by the slow-stirring method were very similar to the literature values. These results indicate that the slow- stirring method allows for reliable determination of log Pow of highly hydrophobic chemicals.

A Study on the Surface Temperature Rise in Spur Gear Part I - Flash Temperature (Spur Gear의 표면온도상승에 관한 연구 Part I - Flash Temperature)

  • 김희진;문석만;김태완;구영필;조용주
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.06a
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    • pp.251-257
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    • 2000
  • A numerical simulation of the temperature rise for sliding surface in dry contact is based on Jaeger's formula combined with a calculated heat input. A gear tooth temperature analysis was performed. The pressure distribution has the Hertzian pressure distribution on the heat source. The heat partition factor is calculated along line of action. A Temperature distribution of tooth surface is calculated about before and after profile modification. A Temperature of addendum and deddendum in modified gear have reduced.

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Ecological modeling for toxic substances - I . Numerical simulation of transport and fate of Nonylphenol in Tokyo Bay- (유해화학물질의 생태계 모델링 - I. 동경만 Nonylphenol의 환경동태 해석 -)

  • Kim Dong-Myung;Shiraishi Hiroaki
    • Journal of Environmental Science International
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    • v.14 no.9
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    • pp.827-835
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    • 2005
  • A three-dimensional ecological model (EMT -3D) was applied to Nonylphenol in Tokyo Bay. EMT -3D was calibrated with data obtained in the study area. The simulated results of dissolved Nonylphenol were in good agreement with the observed values, with a correlation coefficient(R) of 0.7707 and a coefficient of determination (R2) of 0.5940. The results of sensitivity analysis showed that biodegradation rate and bioconcentration factor are most important factors for dissolved Nonylphenol and Nonylphenol in phytoplankton, respectively. In the case of Nonylphenol in particulate organic carbon, biodegradation rate and partition coefficient were important factors. Therefore, the parameters must be carefully considered in the modeling. The mass balance results showed that standing stocks of Nonylphenol in water, in particulate organic carbon and in phytoplankton are $8.60\times 10^5\;g,\;2.19\times 10^2\;g\;and\;3.78\times 10^0\;g$ respectively. With respect to the flux of dissolved Nonylphenol, biodegradation in the water column, effluent to the open sea and partition to particulate organic carbon were $6.02\times10^3\;g/day,\;6.02\times10^2\;g/day\;and\;1.02\times10^1\;g/day$, respectively.

Preformulation Study of Aloesin in Buffered Aqueous Solutions (완충 수용액 중 Aloesin의 전처방화 연구)

  • 이윤진;곽혜선;전인구
    • YAKHAK HOEJI
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    • v.46 no.3
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    • pp.168-173
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    • 2002
  • The physicochemical properties of aloesin, which has been recently found to reduce renal toxicity induced by cis-platin, were studied including solubility, partition coefficient ( $P_{c}$ ), osmolality, and stability. The solubility of aloesin was about 500 mg/mι, and the $P_{c}$ value for n-octanol/water was 1.01 $\pm$ 0.03. The degradation of aloesin followed the pseudo-first-order kinetics and was dependent on temperature, pH and ionic strength. From the pH-rate profile, the optimal pH was found to be 2.0~3.0. Some metal ions increased the degradation rate in the rank order of M $n^{2+}$ > F $e^{3+}$ > C $u^{2+}$ > F $e^{2+}$. On the other hand, other metal ions such as B $i^{3+}$, $Ba^{2+}$, Z $n^{2+}$, N $i^{2+}$, $Co^{2+}$ and $Mg^{2+}$ did not show the unfavorable effects. After autoclaving, aloesin contents remaining were 81.8~98.8% of initial concentrations depending on pH. The most stable pH was 3.98 in the autoclaving. Osmolality increased linearly as concentration increased.sed.creased.sed.

TG-SPSR: A Systematic Targeted Password Attacking Model

  • Zhang, Mengli;Zhang, Qihui;Liu, Wenfen;Hu, Xuexian;Wei, Jianghong
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.13 no.5
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    • pp.2674-2697
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    • 2019
  • Identity authentication is a crucial line of defense for network security, and passwords are still the mainstream of identity authentication. So far trawling password attacking has been extensively studied, but the research related with personal information is always sporadic. Probabilistic context-free grammar (PCFG) and Markov chain-based models perform greatly well in trawling guessing. In this paper we propose a systematic targeted attacking model based on structure partition and string reorganization by migrating the above two models to targeted attacking, denoted as TG-SPSR. In structure partition phase, besides dividing passwords to basic structure similar to PCFG, we additionally define a trajectory-based keyboard pattern in the basic grammar and introduce index bits to accurately characterize the position of special characters. Moreover, we also construct a BiLSTM recurrent neural network classifier to characterize the behavior of password reuse and modification after defining nine kinds of modification rules. Extensive experimental results indicate that in online attacking, TG-SPSR outperforms traditional trawling attacking algorithms by average about 275%, and respectively outperforms its foremost counterparts, Personal-PCFG, TarGuess-I, by about 70% and 19%; In offline attacking, TG-SPSR outperforms traditional trawling attacking algorithms by average about 90%, outperforms Personal-PCFG and TarGuess-I by 85% and 30%, respectively.

Adsorption of Hydrophobic Organic Compounds from Aqueous Solution with CTAB Coated Silicate (CTAB가 코팅된 Silicate을 이용한 소수성 유기물질의 흡착)

  • 김학성;정영도;한훈석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.78-84
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    • 1995
  • Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

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A Study on Preference for telecommuting Center design Criteria (텔레커뮤팅 센터의 실내공간계획요소에 대한 선호 조사 연구)

  • 하미경;권미연
    • Korean Institute of Interior Design Journal
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    • no.20
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    • pp.91-97
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    • 1999
  • Telecommuting becomes a new form of work according to the development of information technology. Therefore, the purpose of this study is to provide basic data for the interior space planning of telecommuting centers by means of surveying office workers' opinions. The major findings of this research are as follows. The opinion about whether to use telecommuting center if provided is showed highly positively. In the matter of space type of telecommuting center, 'mixing type I (open plan office but division with high partition)' is the most preferred, the next, is 'closed type'. The most preferred type of workstation is 'independent type', the next is 'X type' and the third is 'link type'. Preferred partition height is '1,300-1,500mm'. When planning telecommuting center, the most important element of space plan is 'size and layout of workstation' and the second is 'private space for confidential work'. In public workplace, the most important element 'refreshment space', and the second one is 'mailing system'.

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A Study on Preferences for Telecommuting Center Design Criteria (텔레커뮤팅 센터의 실내공간계획요소에 대한 선호 조사 연구)

  • 권미연;하미경
    • Proceedings of the Korean Institute of Interior Design Conference
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    • 1999.04a
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    • pp.27-30
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    • 1999
  • Telecommuting becomes a new form of work according to the development of computer and telecommunication technology. Therefore, the purpose of this study is to provide basic data for the interior space planning of telecommuting centers by means of surveying office workers' opinions. The major findings of this research are as follows. The opinion about whether to use telecommuting center if provided is showed highly positively. In the matter of space type of telecommuting center, 'mixing type I (open plan office but division with high partition)' is the most preferred, the next is 'closed type'. The most preferred type of workstation is 'individual space type ', the next if 'X type' and the third is 'link type'. referred partition height is '1m300-1,500mm'.

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A Partition Function for Liquid Metals (液體金屬의 常態和)

  • Kim, Wan-Kyue
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.36-46
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    • 1962
  • The author assumes that pure liquid metal is composed of molecular oscillators whose energy states are classified into two subgroups, i.e., A and B states, each being accesible to either one of the two sorts of lattice sites. The partition function involves constants characteristic of substance, which are obtainable from the Debye characteristic temperature assigned to its solid state. Calculation has been made for the various thermodynamic properties such as the vapor pressure, the entropy, and the heat capacity of liquid metals of GroupⅠelements over the temperature range from the melting points to the boiling points. The theoretical values thus obtained are in good accordances with those observed, within experimental error, although a slight derivation is observed in the atomic heat capacity.

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Application of Liquid Theory to Sodium-Ammonia Solution

  • Lee, Jong-Myung;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.2 no.3
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    • pp.90-96
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    • 1981
  • The significant structure theory of liquids has been successfully applied to the sodium ammonia solution. In applying the theory to sodium ammonia solution, we assumed there were four species in solution, i.e., sodium cation, solvated electron, triple ion, and free electron and equilibria existed between them. Based on these assumptions, we set up the model explaining the anomalous properties of sodium ammonia solution. The partition function for sodium ammonia solution is composed of the partition functions for the above four species and also for the Debye-Huckel excess free energy term. Agreements between calculated and experimental values of the thermodynamic quantities, such as molar volume, vapor pressure, partial molar enthalpy and entropy, and chemical potential as well as viscosity are quite satisfactory.