• Title/Summary/Keyword: I-Cube

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Synthesis and Ion Conducting Properties of Anion Exchange Membranes Based on PBI Copolymers for Alkaline Fuel Cells (PBI 공중합체를 이용한 알카라인 연료전지용 음이온교환막의 합성과 이온전도특성)

  • Lee, Dong-Hoon;Kim, Se-Jong;Nam, Sang-Yong;Kim, Hyonng-Juhn
    • Membrane Journal
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    • v.20 no.3
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    • pp.217-221
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    • 2010
  • In order to overcome the drawback of proton exchange membrane fuel cells (PEMFCs), solid alkalime membrane fuel cells (SAMFCs) have been studied. In this report, we synthesized new sulfonated polybenzimidazole derivatives for SAMFCs. The polyimidazole derivatives were doped by KOH, and base-doped polybenzimidazoles showed high hydroxy ion conductivity and excellent mechanical properties. Especially, sPBI-co-PBI (75 : 25 for molar ratio of sulfonated and non-sulfonated moiety) showed good possibility for the anion exchange membrane. It has $2.98{\times}10^{-2}\;S/cm$ at $90^{\circ}C$ under 100% relative humidity.

Influence of Yb2O3 Doping Amount on Screen-printed Barium Strontium Calcium Titanate Thick Films

  • Noh, Hyun-Ji;Lee, Sung-Gap;Ahn, Byeong-Lib;Lee, Ju
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.241-245
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    • 2007
  • [ $(Ba_{0.9-x}Sr_xCa_{0.10})TiO_3$ ] (x=0.33, 0.36) powders were prepared by sol-gel method. $(Ba,Sr,Ca)TiO_3$(BSCT) thick films, undoped and doped with $MnCO_3$ and $Yb_2O_3(0.1{\sim}0.7mol%)$, were fabricated by the screen printing method on the alumina substrate. The coating and drying procedure was repeated 6-times. The Pt bottom electrode was screen printing method on the alumina substrate. These BSCT thick films were annealed at $1420^{\circ}C$ for 2 hr in atmosphere. The upper electrodes were fabricated by screen printing the Ag paste and then firing at $590^{\circ}C$ for 10 min. And then the structured and dielectric properties as a function of the doping amount of $Yb_2O_3$ were studied. As a result of the TG-DTA, exothermic peak was observed at around $670^{\circ}C$ due to the formation of the polycrystalline perovskite phase. All BSCT thick films showed XRD patterns of typical cubic peroveskite structure. The average thickness of BSCT thick films was about $70^{\mu}m$. The curie temperature and the dielectric constant decreased with increasing $Yb_2O_3$ doped content and the relative dielectric constant of the specimen, doped with 0.5 mol% $Yb_2O_3$ at BSCT(54/36/10), showed a best value of 5018 at curie temperature.

Research Trend of Organic/Inorganic Composite Membrane for Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지용 유.무기 복합막의 연구개발동향)

  • Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.3
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    • pp.155-170
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    • 2012
  • Fuel cells have been considered as alternative power generation system in the twenty-first century because of eco-friendly system, high power density and efficiency compare with petroleum engine system. Proton exchange membranes (PEMs) are the key components in fuel cell system. Currently, Nafion has been used in fuel cell system. However, Nafion has disadvantages such as low conductivity at high temperature and high cost. The researchers have focused to reach the high properties such as high proton conductivity, low permeability to fuel, good chemical/thermal stability, good mechanical properties and low manufacturing cost. Various methods have been developed for preparation of proton exchange membrane with high performance and commercialization of fuel cell system. The hybrid organic/inorganic membrane has the potentials to provide a unique combination of organic and inorganic properties with improved proton conductivity and mechanical property at high temperatures. So, this paper presents an overview of research trend for the composite membranes prepared by organic/inorganic system using various inorganic materials.

Kennicutt-Schmidt law with H I velocity profile decomposition in NGC 6822

  • Park, Hye-Jin;Oh, Se-Heon;Wang, Jing;Zheng, Yun;Zhang, Hong-Xin;de Blok, W.J.G.
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.32.3-33
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    • 2021
  • We present H I gas kinematics and star formation activities of NGC 6822, a dwarf galaxy located in the Local Volume at a distance of ~ 490 kpc. We perform profile decomposition of the line-of-sight velocity profiles of the high-resolution (42.4" × 12" spatial; 1.6 km/s spectral) H I data cube taken with the Australia Telescope Compact Array (ATCA). For this, we use a new tool, the so-called BAYGAUD (BAYesian GAUssian Decompositor) which is based on Bayesian Markov Chain Monte Carlo (MCMC) techniques, allowing us to decompose a line-of-sight velocity profile into an optimal number of Gaussian components in a quantitative manner. We classify the decomposed H I gas components of NGC 6822 into bulk-narrow, bulk-broad, and non_bulk with respect to their velocity and velocity dispersion. We correlate their gas surface densities with the surface star formation rates derived using both GALEX far-ultraviolet and WISE 22 micron data to examine the impact of gas turbulence caused by stellar feedback on the Kennicutt-Schmidt (K-S) law. The bulk-narrow component that resides within r25 is likely to follow the linear extension of the Kennicutt-Schmidt (K-S) law for molecular hydrogen (H2) at the low gas surface density regime where H I is not saturated.

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Tilted-Ring Modeling of Warped Spiral Galaxies

  • Bae, Hyun-Jin;Chung, Ae-Ree;Jozsa, Gyula I.G.;Kim, Sung-Soo;Yoon, Suk-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.30.2-30.2
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    • 2010
  • A direct tilted-ring fitting method allows us to investigate kinematic structure of spiral galaxies. By employing the method to high-resolution HI data cubes, we can more easily trace warp characteristics of spiral galaxies than ever. In this contribution, we make use of TiRiFiC to VLA HI data cube of spiral galaxies in Virgo cluster, and present our preliminary yet interesting results. The TiRiFiC (Tilted-Ring-Fitting-Code) is publicly available code that provides 'best-fit' tilted-ring parameters (i.e. position angle and inclination) via chi-square minimization technique. We also discuss possible biases (e.g., resolution dependency) and its effect on our conclusions.

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Personal Computer Aided 3-D Model Generation (I) (PC를 이용한 3차원 입체형상 모델생성 연구 (I))

  • 변문현;오익수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.1
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    • pp.59-66
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    • 1989
  • The purpose of this study is to develop a personal computer aided 3-D geometric modeller. To perform this study, we set up a cube, cylinder, and a prism as primitives in the first segment of this study. By modelling the 3-D object through their transformation, addition, and subtraction, we proved the validity of the developed algorithm and its computer program. Some examples show the results of applying the program to model a few simple shapes of the machine parts. These results met the first aim of this study.

Study on the Bond Mechanism of the Reinforcing Bars by Casting Direction of Recycled Coarse Aggregate Concrete using Acoustic Emission Method (음향방출기법을 이용한 순환굵은골재 콘크리트의 타설방향에 따른 철근의 부착메커니즘에 관한 연구)

  • Jeon, Su-Man;Yun, Hyun-Do;You, Young-Chan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.245-248
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    • 2006
  • The objective of this study is to take the first step in creating a user-friendly health monitoring system for recycled aggregate concrete structure using acoustic emission(AE). Each specimen was a cube, the edge of which was 150mm. For pull-out tests, a steel rebar, 13mm in diameter, was embedded in the center of each specimen and casting directions(i.e., vertical and horizontal) were considered in this paper. The AE parameters were analyzed for damage levels(i.e. internal cracking stage, pull-out stage) of all specimens. Results from this study show that event, duration versus amplitude of a signal, showed a clear difference for different loading stages depending upon the concrete casting directions.

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Effects of Multi-layer and TiCl4 Treatment for TiO2 Electrode in Dye-sensitized Solar Cell (염료감응 태양전지의 TiO2 전극의 다중층 및 TiCl4 처리에 따른 효과)

  • Kim, Gyeong-Ok;Kim, Ki-Won;Cho, Kwon-Koo;Ryu, Kwang-Sun
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.190-195
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    • 2011
  • To investigate the photon-trapping effect and scattering layer effect of $TiO_2$ multi-layer in dye-sensitized solar cell (DSSC) and the degree of recombination of electrons at the electrode treated $TiCl_4$, we formed electrodes of different conditions and obtained the most optimal electrode conditions. To estimate characteristics of the cell, IV curve, UV-Vis spectrophotometer, electrochemical impedance spectroscopy (EIS) and incident photon-to-current conversion efficiency (IPCE) were measured. As a result, we confirmed that the multi-layer's efficiency was higher than that of monolayer in the IV curve and the performance of $TiCl_4$ treated electrode was increased according to decreasing the impedance of EIS. Among several conditions, the efficiency of the cell with scattering layer is higher than that of a layer with the base electrode about 19%. Because the light scattering layer enhances the efficiency of the transmission wavelength and has long electron transfer path. Therefore, the value of the short circuit current increases approximately 10% and IPCE in the maximum peak also increases about 12%.

Performance of concrete modified with SCBA and GGBFS subjected to elevated temperature

  • Palaskar, Satish Muralidhar;Vesmawala, Gaurang R.
    • Advances in materials Research
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    • v.9 no.3
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    • pp.203-218
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    • 2020
  • This research paper presents the outcomes in terms of mechanical and microstructural characteristics of binary and ternary concrete when exposed to elevated temperature. Three parameter were taken into account, (a) elevated temperature (i.e., 200, 400, 600 and 800℃) (b) binary concrete with cementitious material sugarcane bagasse ash (SCBA) and ground granulated blast furnace slag (GGBFS) replacement percentage (i.e., 0, 15, 20, 25 and 30%) and (c) ternary concrete with cementitious material SCBA and GGBFS replacement percentage (i.e., 0, 15, 20, 25 and 30%). A total of 285 standard cube specimens (150 mm × 150 mm × 150 mm) containing Ordinary Portland Cement (OPC), SCBA, and GGBFS were made. These specimens then exposed to several elevated temperatures for 2 h, afterword is allowed to cool at room temperature. The following basic physical, mechanical, and microstructural characteristics were then determined and discussed. (a) mass loss ratio, (b) ultrasonic pulse velocity (UPV) (c) physical behavior, (d) compressive strength, and (e) field emission scanning electron microscope (FESEM). It was found that compressive strength increases up to 400℃; beyond this temperature, it decreases. UPV value and massloss decrease with increase in temperature as well as the change in color and crack were observed at a higher temperature.

Pressure distribution on rectangular buildings with changes in aspect ratio and wind direction

  • Lee, Young Tae;Boo, Soo Ii;Lim, Hee Chang;Misutani, Kunio
    • Wind and Structures
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    • v.23 no.5
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    • pp.465-483
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    • 2016
  • This study aims to enhance the understanding of the surface pressure distribution around rectangular bodies, by considering aspects such as the suction pressure at the leading edge on the top and side faces when the body aspect ratio and wind direction are changed. We carried out wind tunnel measurements and numerical simulations of flow around a series of rectangular bodies (a cube and two rectangular bodies) that were placed in a deep turbulent boundary layer. Based on a modern numerical platform, the Navier-Stokes equations with the typical two-equation model (i.e., the standard $k-{\varepsilon}$ model) were solved, and the results were compared with the wind tunnel measurement data. Regarding the turbulence model, the results of the $k-{\varepsilon}$ model are in overall agreement with the experimental results, including the existing data. However, because of the blockage effects in the computational domain, the pressure recovery region is underpredicted compared to the experimental data. In addition, the $k-{\varepsilon}$ model sometimes will fail to capture the exact flow features. The primary emphasis in this study is on the flow characteristics around rectangular bodies with various aspect ratios and approaching wind directions. The aspect ratio and wind direction influence the type of wake that is generated and ultimately the structural loading and pressure, and in particular, the structural excitation. The results show that the surface pressure variation is highly dependent upon the approaching wind direction, especially on the top and side faces of the cube. In addition, the transverse width has a substantial effect on the variations in surface pressure around the bodies, while the longitudinal length has less influence compared to the transverse width.