• Title/Summary/Keyword: I/O ratios

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Mineral Chemistry of Talc from Different Origins in the Dongyang Talc Deposit (동양활석광상에서 산출되는 서로 다른 기원의 활석에 대한 광물화학)

  • Shin Dongbok;Lee Insung;Koh Sang-Mo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.357-364
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    • 2004
  • Mineral chemistry of talc from the Dongyang talc deposits was studied to characterize the differences between dolomite-origin talc (talc I) and tremolite-origin talc (talc II). Average iron and aluminum contents are higher in talc II, 2.18 wt% FeO and 0.31 wt% $Al_2$O$_3$), than in talc I, 1.48 wt% FeO and 0.08 wt% $Al_2$O$_3$). Consistently lower Mg/(Mg+Fe+Mn) ratios and higher AI concentrations with uniform values of talc II compared to talc I seem to reflect the compositional differences of the original materials, tremolite and dolomite, respectively. Relative enrichment of Al as well as Fe in talc II compared to tremolite can be attributed to their immobile behaviors during alteration process and the rapid diffusion of hydrothermal fluids, which can accelerate instantaneous nucleation with immaturity growth of talc II. Increase in the concentrations of talc II can lower the ore grade by increasing concentrations of impure components such as AI and Fe, and by abundant presence of tremolite as well.

Petrochemistry of Granitoids in the Younggwang-Kimje area, Korea (영광-김제 지역 화강암류의 암석화학적 연구)

  • Park, Young-Seog;Kim, Jong-Kyun;Kim, Jin
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.55-70
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    • 2001
  • Granitoids in the Younggwang-Kimje area can be divided into two types of granite. One is foliated granite (Cheongup and Kochang foliated granites) developed along the NE-SW direction kwangju fault system and the other is undeformed granite (Kimje and Younggwang granites) developed in the western part of the area. $SiO_2$ content of study area, Younggwang granite is 62.8-74.0%, Kochang foliated granite is 64.5-74.4%, Cheongup foliated granite is 64.5-70.2%, Kimje granite is 63.4-72.0%. The result indicated that these granitoids belong to the intermediate and acidic rock. In Harker's diagram, as $SiO_2$ increases, $Al_2O_3$, $Fe_2O_3$, MgO, CaO, $TiO_2$> $P_2O_{5}$s and MnO decrease, but $K_2O$ increases. In AFM diagram, Younggwang granite, Kochang foliated granite, Cheongup foliated granite and Kimje granite belong to calk-alkaline rock series. And in triangular diagrams of normative Qz-Or-Pl and An-Ab-Or, they are located in granodiorite and granite region. On the co-variation diagrams of trace elements with silica, Ba, Co, Li, Nb, An, Rb elements show increasing patterns. The diagrams of ACF and $Na_2O$ vs. $K_2O$ ratios indicate that granitoids of the study area belong to I-type.

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Lignin signatures of vegetation and soils in tropical environments

  • Belanger, E.;Lucotte, M.;Gregoire, B.;Moingt, M.;Paquet, S.;Davidson, R.;Mertens, F.;Passos, C.J.S.;Romana, C.
    • Advances in environmental research
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    • v.4 no.4
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    • pp.247-262
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    • 2015
  • The few lignin biomarker studies conducted in tropical environments are hampered by having to use references signatures established for plants and soils characteristic of the temperate zone. This study presents a lignin biomarker analysis (vanillyls (V), p-hydroxyls (P), syringyls (S), cinnamyls (C)) of the dominant plant species and soil horizons as well as an analysis of the interrelated terrigenous organic matter (TOM) dynamics between vegetation and soil of the $Tapaj{\acute{o}}s$ river region, an active colonization front in the Brazilian Amazon. We collected and analyzed samples from 17 fresh dominant plant species and 48 soil cores at three depths (0-5 cm, 20-25 cm, 50-55 cm) from primary rainforest, fallow forest, subsistence agriculture fields and pastures. Lignin signatures in tropical plants clearly distinguish from temperate ones with high ratios of Acid/aldehyde of vanillyls ((Ad/Al)v) and P/V+S. Contrary to temperate environments, similarly high ratios in tropical soils are not related to TOM degradation along with pedogenesis but to direct influence of plants growing on them. Lignin signatures of both plants and soils of primary rainforest and fallow forest clearly distinguish from those of non-forested areas, i.e., agriculture fields and pastures. Attalea speciosa Palm trees, an invasive species in all perturbed landscapes of the Amazon, exhibit lignin signatures clearly distinct from other dominant plant species. The study of lignin signatures in tropical areas thus represents a powerful tool to evaluate the impact of primary rainforest clearing on TOM dynamics in tropical areas.

Synthesis and Antitumor Evaluation of Acyclic 1-[${\omega}$-(N^I-2-chloroethyl-N^I-nitrosoureido)alkyl]thymidine Nucleoside Analogues

  • Kim, Jack-C.;Kim, Young-Hyun;Park, Jin-Il;Kim, Seon-Hee;Choi, Soon-Kyu
    • Archives of Pharmacal Research
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    • v.20 no.3
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    • pp.259-263
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    • 1997
  • In the preparation of acyclic thymidine nucleoside analogues, $K_2CO_3$(or NaH) treated thymine in DMSO was alkylated with .omega.-chloroalkyl nitrite (Cl-(CH_2)n-CN; n=1, 2, 3, 4) to provide an isomeric mixture of 1-(${\omega}$-cyanoalkyl)thymine (2a-d) and 1,3-bis(${\omega}$-cyanoalkyl)thymine in approximately 5:1 ratios. Reduction of the cyano function 2a-d with $NaBH_{4}/CoCl_{2}$ center dot$ 6H_{2}O$gave the corresponding 1-(${\omega}$aminoalkyl)thymine (3a-d). The newly formed primary amino function in 3a-d was directly reacted with 2-chloroethylisocyanate to afford the 1-[.omega.($N^{I}$-2-chloroethylureido) alkyl]thymine (4a-d) in good yields. Nitrosation of 1-[5-($ N^{I}-2$-chloroethylureido)pentyl] thymine (4d) with glacial acetic acid and dry $NaNO_{2}$-powder in anhydrous $CH_{2}Cl_{2}$gave two types of regioisomeric nitrosoureas, 1-[5-($N^{I}$--chloroethyl-$N^{I}$--nitrosoureido)pentylithymine (5d) and 1-[5-($N^{I}-2$-chloroethyl-N-nitrosoureido)pentyllthymine in approximately 5 :1 ratios. The in vitro cytotoxicity of the synthesized compounds (2a-d, 3a-d, 4a-d and 5a-d) against three cell lines (K-562, P-388 and FM-3A) are measured as $IC^{50}$ values. Compounds 3b and 4c showed moderate activities against all three cell lines, and all other compounds were found to be not active.

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Effect of $UO_2$ Powder Property and Oxygen Potential on Sintering Characteristics of $UO_2-Gd_2O_3$ Fuel

  • Song, Kun-Woo;Kim, Keon-Sik;Yoo, Ho-Sik;Jung, Youn-Ho
    • Nuclear Engineering and Technology
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    • v.30 no.2
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    • pp.128-139
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    • 1998
  • The effect of UO$_2$ powder property and oxygen potential on characteristics of sintered UO$_2$-Gd$_2$O$_3$ fuel pellets has been investigated. Two types of powder, mixture of AUC-UO$_2$ and Gd$_2$O$_3$powders (type I) and mixture of ADU-UO$_2$ and Gd$_2$O$_3$powders (type II), have been prepared, pressed, and sintered at 168$0^{\circ}C$ for 4 hours. Four sintering atmospheres with different mixing ratios of $CO_2$to H$_2$ gas ranging from 0 to 0.3 have been used. UO$_2$-Gd$_2$O$_3$ fuel has lower sintered density than UO$_2$ fuel, and the density drop is larger for powder type I than for powder type II. As the oxygen potential increases, the sintered density of UO$_2$-2wt% Gd$_2$O$_3$pellets increases but that of UO$_2$-10wt% Gd$_2$O$_3$ pellets decreases. It is found that pores are newly formed in UO$_2$-10wt% Gd$_2$O$_3$ pellets in accordance with the decrease in density. The grain size of UO$_2$-Gd$_2$O$_3$ fuel increases and a short range G4 distribution becomes homogeneous as the oxygen potential increases. A long range ed distribution and grain structure are inhomogeneous for powder type II. The lattice parameter of (U,Gd)O$_2$solid solution decreases linearly with Gd$_2$O$_3$ content. The dependence of UO$_2$-Gd$_2$O$_3$fuel characteristics on powder type and sintering atmosphere have been discussed.

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A Vowel Discrimination of Korean Monophthongs [i, e, a, o, u, ${\omega}$] Using Vocal Tract Magnetic Resonance Image and F1/F2 (성도 자기공명 영상과 음향정보(F1/F2)를 이용한 한국어 단모음 [이, 에, 아, 오, 우, 으] 판별)

  • Seong, Cheol-Jae;Park, Jong-Won;Kim, Gui-Ryong
    • MALSORI
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    • no.56
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    • pp.103-125
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    • 2005
  • We present a new method of measuring the volume and cross-sectional area of the vocal tract from magnetic resonance images. The vocal tract was divided by the 2 constriction points on the horizontal and vertical planes. The ratios of the volumes of the segment vocal tracts to that of the entire vocal tract play a crucial role in discriminating Korean monophthongs in that vowels were successfully discriminated by the ratios. The discriminant analysis also demonstrated that the acoustic parameters F1 and F2, in addition to the segment volumes, serve as significant parameters in discriminating Korean monophthongs.

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Daylength Effects on Stress and Fear Responses in Broiler Chickens

  • Zulkifli, I.;Rasedee, A.;Nor Syaadah, O.;Che Norma, M.T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.6
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    • pp.751-754
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    • 1998
  • Heterophil (H) to lymphocyte (L) ratios and durations of tonic immobility (TI) were measured to assess stress and fear responses, respectively, in broiler chickens provided either 12 h of natural lighting (12L) or 12 h natural lighting and 12 h of supplementary lighting (24L). Birds illuminated 24L had greater H/L ratios and TI durations than their 12L counterparts. Neither age, sex nor cage level had significant effect on TI reactions.

Synthesis of Iron and Copper Complexes of 2-Formylpyridine Thiosemicarbazone Derivatives, Potential Antitumor Agents (실험 항암제 2-Formylpyridine Thiosemicarbazone유도체의 철 및 동착물의 합성)

  • 김종윤;최보길;우순형
    • YAKHAK HOEJI
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    • v.26 no.3
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    • pp.181-184
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    • 1982
  • The iron and copper chelates of 4-dimethylamino-2-formylpyridine thiosemicarbazone, one of the amine substituted derivatives at 4-C of 2-formylpyridine thiosemicarbazones which are known as the more improved potential antitumor agents, have been synthesized to make them more effective than the ligand (denoted as HL) itself. Their ligand-to-metal ratios were 2:1 and 1:1 for the iron and copper chelates, and the data along with those of elemental analysis and IR spectroscopy showed that. the compositions are [$FeI_{2}{\times}2H_{2}SO_{4}$ and [CuL($H_{2}Cl$O)], respectively.

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Cyclic testing of steel I-beams reinforced with GFRP

  • Egilmez, O. Ozgur;Yormaz, Doruk
    • Steel and Composite Structures
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    • v.11 no.2
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    • pp.93-114
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    • 2011
  • Flange and web local buckling in beam plastic hinge regions of steel moment frames can prevent beam-column connections from achieving adequate plastic rotations under earthquake-induced forces. This threat is especially valid for existing steel moment frame buildings with beams that lack adequate flange/web slenderness ratios. As the use of fiber reinforced polymers (FRP) have increased in strengthening and repair of steel members in recent years, using FRPs in stabilizing local instabilities have also attracted attention. Previous computational studies have shown that longitudinally oriented glass FRP (GFRP) strips may serve to moderately brace beam flanges against the occurrence of local buckling during plastic hinging. An experimental study was conducted at Izmir Institute of Technology investigating the effects of GFRP reinforcement on local buckling behavior of existing steel I-beams with flange slenderness ratios (FSR) exceeding the slenderness limits set forth in current seismic design specifications and modified by a bottom flange triangular welded haunch. Four European HE400AA steel beams with a depth/width ratio of 1.26 and FSR of 11.4 were cyclically loaded up to 4% rotation in a cantilever beam test set-up. Both bare beams and beams with GFRP sheets were tested in order to investigate the contribution of GFRP sheets in mitigating local flange buckling. Different configurations of GFRP sheets were considered. The tests have shown that GFRP reinforcement can moderately mitigate inelastic flange local buckling.

THE CHEMICAL PROPERTIES OF PG QUASARS

  • Shin, Jaejin;Woo, Jong-Hak;Nagao, Tohru
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.74.2-74.2
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    • 2012
  • Metallicity is an important tracer of star formation in galaxy evolution. Based on the flux ratios of broad emission lines, AGN metallicity has shown a correlation with AGN luminosity. However, it is not clear what physical parameter drives the observed correlation. Using a sample 69 Palomar-Green QSOs at low-z (z<0.5), we determine BLR gas metallicity from emission line flux ratios, i.e., N V1240/C IV1549, (Si IV1398+O IV1402)/C IV1549 and N V1240/He II1640 based on the UV spectra from the HST and IUE archives. We compare BLR gas metallicity with various AGN properties, i.e., black hole mass, AGN luminosity and Eddington ratio, in order to investigate physical connection between metal enrichment and AGN activity. In contrast to high-z QSOs, which show the correlation between metallicity and black hole mass, we find that the metallicity of low-z QSOs correlates with Eddington ratio, but not with black hole mass, suggesting that metallicity enrichment mechanism is different between low-z and high-z.

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