• 한국주조공학회지
• /
• 제18권6호
• /
• pp.604-612
• /
• 1998

• 한국분말재료학회지
• /
• 제22권5호
• /
• pp.362-366
• /
• 2015

The effect of sublimable vehicle composition in the camphor-naphthalene system on the pore structure of porous Cu-Ni alloy is investigated. The CuO-NiO mixed slurries with hypoeutectic, eutectic and hypereutectic compositions are frozen into a mold at $-25^{\circ}C$. Pores are generated by sublimation of the vehicles at room temperature. After hydrogen reduction at $300^{\circ}C$ and sintering at $850^{\circ}C$ for 1 h, the green body of CuO-NiO is completely converted to porous Cu-Ni alloy with various pore structures. The sintered samples show large pores which are aligned parallel to the sublimable vehicle growth direction. The pore size and porosity decrease with increase in powder content due to the degree of powder rearrangement in slurry. In the hypoeutectic composition slurry, small pores with dendritic morphology are observed in the sintered Cu-Ni, whereas the specimen of hypereutectic composition shows pore structure of plate shape. The change of pore structure is explained by growth behavior of primary camphor and naphthalene crystals during solidification of camphor-naphthalene alloys.

• 한국주조공학회지
• /
• 제15권6호
• /
• pp.566-573
• /
• 1995

In this study, the microstructural characteristics such as primary silicon, eutectic silicon, $SiC_p$ dispersion behavior, compound amount and Si solubility in $Al/SiC_p$ composite fabricated by the squeeze casting under various conditions were investigated systematically. As applied pressure(MPa) increases, cooling rate and compound amount are increased. In gravity casting, the cooling rate of hypereutectic composite is slower than of hypoeutectic composite by exothermic reaction of primary Si crystallization. But the cooling rate of hypereutectic composite is faster than that of hypoeutectic composite fabricated by same applied pressure, because amount of primary Si crystallization in hypereutectic composite was decreased, on the contrary, primary ${\alpha}-Al$ in hypoeutetic composite was increased due to increase of Si solubility in matrix by applied pressure. The crystalized primary silicon in hypereutectic composite fabricated by squeeze casting become more fine than that in non-pressure casting This is because mush zone became narrow due to increase of Si content of eutectic composition by pressure and time for growth of primary silicon got shorter according to applied pressure. It is turned out that eutectic temperature and liquidus are decreased by the increasing of squeeze pressure in all the composite due to thermal unstability of matrix owing to increasing of Si solubility in matrix by the increasing of applied pressure, as indicated in thermal anaiysis(DSC) results.

• 열처리공학회지
• /
• 제23권2호
• /
• pp.96-103
• /
• 2010

$Ni_3Al$ is known as a good high temperature structural material because of high yield strength at ambient temperature. However, it is too brittle to use as a structural material because of their weak grain boundary. In this work, orientation measurement and related mechanical properties of directionally solidified NiAl/$Ni_3Al$ two-phase alloys with various compositions (Ni-23~27 at.%Al) were investigated for developing multi-phase DS-processed alloys with the growth rates of 10, 50 and 100 ${\mu}m/s$ in a modified Bridgeman type furnace. It was found that the multi-phase microstructures such as the $\gamma$ dendrite +${\gamma}'$ matrix duplex microstructure was formed in the hypoeutectic composition of 23 at.%Al, $\beta$ dendrite +${\gamma}'$ matrix duplex microstructure in the hypereutectic composition of 26 and 27 at.%Al. And ${\gamma}'$ single phase was formed in the composition of 24.5 and 25 at.%Al. The hypoeutectic alloy including $\gamma$ dendrites with ${\gamma}'$ matrix showed a large elongation of over 70% at room temperature. However, the room-temperature tensile elongation decreased with increasing Al contents because the volume fraction of brittle $\beta$ dendrites in the ductile ${\gamma}'$ matrix increased.

• Journal of Advanced Marine Engineering and Technology
• /
• 제24권1호
• /
• pp.59-66
• /
• 2000

To investigate the optimum brazing condition, variation of bonded structure and mechanical properties of novel brazed pure Al with bonding condition (brazing temperature, time and Si/flux ratio) was studied. A basic study of the bonding mechanism was also examined. The optimum brazing condition was obtained at $590^{\circ}$ for 2 minutes and the bonded structure showed that it is composed of almost entirely eutectic Al-Si with near eutectic composition. At higher brazing temperature $630^{\circ}$, hypoeutectic Al-Si structure was observed in the bonded area and resulted in erosion of base metal. The thickness of eutectic layer formed in optimum brazing temperature increased linearly with the square root of time, showing a general diffusion controlled process. The ultimate tensile strength of bonded joint brazed at an optimum brazing condition was about 60% of base metal and its fracture surface showed a brittle mode.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2001년도 춘계학술대회 논문집
• /
• pp.381-384
• /
• 2001

The combined stirring method to uniform distribution of particle is consisted of two strring force both electro-magnetic stirring generated from induction heating and mechanical stirring with graphite stirrer. PMMC billets were fabricated with the volume fractions ranged from 0% to 20% and particle sizes ranged from 14$\mu\textrm{m}$ to 25$\mu\textrm{m}$. It is important to control the size of primary ${\alpha}$-AI solid particles because it could become the cause of the particle pushing or capture phenomena from the fact that secondary dendrite arm spacing size depends on the cooling rate during the solidification in hypoeutectic AI-Si alloy.

• 한국윤활학회:학술대회논문집
• /
• 한국윤활학회 1998년도 제28회 추계학술대회
• /
• pp.38-48
• /
• 1998

To apply the high chromium white cast irons for sliding parts of construction equipments, the wear characteristics of these alloys which have three kinds of microstructure(hypoeutectic, near-eutectic, hypereutectic) were investigated by dry sand/rubber wheel tester. Also, the effect of heat treatment was investigated for the same alloys. As result of the test, heat treatment have no effect on the wear characteristics. And, hypereutectic composition alloy has the highest wear resistance against SiO$_2$. Also after test, cracking was observed in eutectic and primary carbides of all materials tested. This phenomenon was important factor in the wear resistance.

• 한국주조공학회지
• /
• 제4권4호
• /
• pp.14-19
• /
• 1984

In order to clarify the solidification mechanism of Al-Si alloy, Mushy Degree of Eutectic Solidification (MDE) and Centerline Feeding Resistance (CFR) were systematically studied by casting with various compositions of $Al-(6{\sim}18%)$ Si alloys into several kinds of molds having different cooling rates. The results are as follows: 1. CFR% increases slightly as solute concentration increases, but decreases remarkably as the cooling rate of the mold increases, that is, the composition dependence of the alloys has more effect on the change of CFR% than that of the mold cooling rate. 2. The composition dependence of MDE value has the same tendency as that of Degree of Eutectic Solidification (DES). MDE value within the range of hypereutectic composition is larger than that of hypoeutectic and it represents the maximum value at eutectic composition. The higher the cooling rate is, the less the MDE value is.

• Journal of Welding and Joining
• /
• 제16권2호
• /
• pp.64-72
• /
• 1998

This study aims a investigating the effect of volume fraction of chromium carbide phase(VFC) of hardfaced iron/chromium alloys on fracture toughness. The alloys were deposited twice on a mild steel plate using self-shielding flux cored arc welding process. In order to examine VFC effect, different VFC (0.28∼0.62) were employed by changing the Cr and C content, while the ratio of Cr/C was fixed in the range of 5.7∼6.6. Fracture toughness was constant as increasing VFC because fracture surface was developed in the eutectic phase which was growing parallel with introduced sharp notch in the hypoeutectic alloys, but fracture toughness did not decreased in spite of increasing volume fraction of coarse primary chromium carbide phase which was easily craced at the low stress because the growth direction of chromium carbide phase were more irregular as increasing VFC in the hypereutectic alloys.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2004년도 International Symposium on Powder Materials and Processing
• /
• pp.46-47
• /
• 2004

The microstructure and mechanical properties of the hypereutectic prealloyed Al-Si powders prepared by the gas atomization process were described in this paper. With increasing the gas pressure of the atomization, the average powder size was decreased from about $145{\mu}m\;to\;80{\mu}m$. The primary eutectic Si particles were uniformly distributed in the Al matrix and their size varied in the range of $8-10{\mu}m$. The high densified specimens with above 96% of the theoretical density were fabricated the hot pressing process. The UTS mechanical properties of VN1 specimens were much higher than that of conventional hypoeutectic Al-Si alloys.