• Journal of Aerospace System Engineering
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• v.17 no.1
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• pp.51-58
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• 2023

Hypergolic propellants, which can ignite themselves without an ignition source, are difficult to handle due to their corrosiveness and toxicity. Therefore, it is necessary to develop green hypergolic propellants with little or no toxicity. In this study, basic research on green hypergolic ignition propellants was conducted. With 95% hydrogen peroxide as an oxidizer and CNU_HGFv1 as a fuel, ignition and combustion characteristics of propellants were evaluated through a drop test, an ignition test, and a combustion test. As a result of the drop test, the ignition delay time was 9.7 ms. It was 27 ms in the ignition test, which was fast enough to be used as a propellant. As a result of the combustion test, a combustion efficiency of 95.4~98.1% was achieved at about 11.7 bar. It was confirmed that fast and stable combustion was possible without hard start or combustion instability.

• Journal of the Korean Society of Propulsion Engineers
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• v.24 no.4
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• pp.79-88
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• 2020

Hypergolic propellants have been widely used for space propulsion systems based their long-term storability and high ignition reliability. Since conventional hypergolic propellants are highly toxic and carcinogenic, handling and operating costs are significant. To overcome the drawbacks, numerous studies have been actively performed to develope new hypergolic propellants, ensuring that the combinations are high performance, low toxicity and low environmental impact. In the present study, a comprehensive survey was conducted to summarize the research and development of green hypergolic propellants involving hydrogen peroxide, nitric acid, and ionic liquids.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.2
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• pp.20-27
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• 2022

Hypergolic propellant ignited spontaneously when fuel and oxidizer contact without ignition system. Due to this characteristic, the risk of accidents is high when new propellants are evaluated. Prevention of accidents is very important because the damage can be large when the accident occur. In this work, we proposed non-ignition evaluation method which can replace conventional ignition evaluation method by using microreactor. The reactor was fabricated by MEMS. The heat of reaction as according to fuel and NaBH₄ was estimated. At the condition of highest heat of reaction ignition was observed by drop test.

• Journal of Aerospace System Engineering
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• v.14 no.3
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• pp.24-31
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• 2020

A study on the H2O2 based low toxic hypergolic propellant was conducted. The fuel candidates were chosen as a mixture of Amine solvent and reactive additive. The analytical performance was calculated via the NASA CEA code and 96% Isp of the NTO/UDMH was confirmed. The ignition delay measurement with drop test was performed and all candidates showed less than 10 ms in the best performance cases. Based on these results, the feasibility of high response H2O2 based low toxic hypergolic propellant was confirmed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.1060-1060
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• 2017

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.265-268
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• 2005

A series of ignition tests had been conducted for a thrust chamber propelled by Jet A-1 and liquid oxygen with a chamber pressure of 52.5 bara and a thrust of 30 tonf. The chamber ignited by a hypergolic fluid, TEAL, keeps its first constant pressure low at $63\%$ of the design value by $61\%$ of a liquid oxygen mass flow rate and $67\%$ of fuel for 0.25 sec. The operating O/F ratio of the chamber was kept at lower values than that of the design operating condition throughout the whole ignition procedure. Surge of the chamber pressure is below $6\%$ of the design value.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.97-100
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• 2011

It is critical to set up the starting sequence of liquid rocket engines because not carefully arranged process can lead the engine damages. Thus, many efforts were made to prevent the hard start at the ignition. Hypergolic fuels are frequently used to ignite LRE and TEAL, one of the hypergolic fuel is also used for kerosene-LOx LRE ignition. However, since we are still lack of experiences igniting oxygen rich preburners of the staged combustion cycle engines, it would be helpful to estimate the TEAL ignition phenomena before the actual tests.

• Aerospace Engineering and Technology
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• v.11 no.2
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• pp.122-128
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• 2012

Many of the liquid rocket engines use a hypergolic igniter with rupture disc ends located in the combustion chamber ignition line. In this study, the flow coefficient tests of the igniter, which have a solenoid valve upstream, were performed. The tension-type rupture discs for radial and circumferential scores and the igniter with them were tested using water at room temperature. The effects of the score, flow rate, the disc thickness, gas pocket and the solenoid valve on the coefficient were analyzed.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.5
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• pp.90-100
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• 2019

Hypergolic thrusters have been extensively researched and applied to spacecraft propulsion based on their simplicity and high reliability of ignition. Research on the impingement characteristics of $N_2O_4$/amine has been profoundly carried out since the 1960s in advanced countries, especially the United States. Recently, enhancements to advanced hypergolic thrusters using MON/MMH have been planned by NASA to improve compactness and high performance. In this work, technical studies were investigated on the mixing of hypergolic propellant and its combustion instabilities such as reactive separation flow and popping.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.6
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• pp.74-85
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• 2022

Since the late 1990s, the demand for developing green or reduced-toxic storable propellants has been rising to replace the existing toxic propellants. Most of the research activities are focusing on development of new hypergolic fuels and either white fuming nitric acid or hydrogen peroxide is utilized as an oxidizer. The newly-developed hypergolic fuels are classified as three types, catalytic fuel, reactive fuel, and ionic fuel. In the present study, recent R&D trend of ionic liquid propellants is described and the main results in the previous studies are analyzed.