• 제목/요약/키워드: Hydrothermal stability

검색결과 99건 처리시간 0.022초

육방정계 텅스텐옥사이드 나노분말의 합성과 고성능 가스센서응용을 위한 성능 평가 (Fabrication and Characterization of Hexagonal Tungsten Oxide Nanopowders for High Performance Gas Sensing Application)

  • 박진수
    • 한국분말재료학회지
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    • 제26권1호
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    • pp.28-33
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    • 2019
  • The gas sensor is essential to monitoring dangerous gases in our environment. Metal oxide (MO) gas sensors are primarily utilized for flammable, toxic and organic gases and $O_3$ because of their high sensitivity, high response and high stability. Tungsten oxides ($WO_3$) have versatile applications, particularly for gas sensor applications because of the wide bandgap and stability of $WO_3$. Nanosize $WO_3$ are synthesized using the hydrothermal method. As-prepared $WO_3$ nanopowders are in the form of nanorods and nanorulers. The crystal structure is hexagonal tungsten bronze ($MxWO_3$, x =< 0.33), characterized as a tunnel structure that accommodates alkali ions and the phase stabilizer. A gas detection test reveals that $WO_3$ can detect acetone, butanol, ethanol, and gasoline. This is the first study to report this capability of $WO_3$.

Cost effective and low energy consuming hydrothermal synthesis of Ni based MOF

  • Israr, Farrukh;Kim, Duk Kyung;Kim, Yeongmin;Oh, Seung Jin;Ng, Kim Choon;Chun, Wongee
    • 에너지공학
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    • 제24권2호
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    • pp.51-54
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    • 2015
  • The mesoporous metal organic framework structure of Ni-BTC was successfully synthesized in a low temperature and short operation time via hydrothermal synthesis process. Such operational route virtuously consumed less electrical and thermal energy. It proved time saving along with acceptable product yield (38%). The product was characterized through FESEM, FT-IR, XRD and $N_2$ gas adsorption measurement. Hightemperature stability of synthesized MOF was gauged by diffraction indexing of XRD patterns of as synthesized and heat treated samples of MOFs. The mathematically calculated particle size of Ni-BTC was found to be 42nm.

Hydrothermal Synthesis of Fe Based MOFs with Energy Economy Approach

  • Israr, Farrukh;Kim, Duk Kyung;Kim, Yeongmin;Oh, Seung Jin;Ng, Kim Choon;Chun, Wongee
    • 에너지공학
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    • 제24권2호
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    • pp.55-58
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    • 2015
  • The mesoporous metal organic framework structure Fe-BTC was successfully synthesized by hydrothermal process with noticeable yield. The synthesis operation was conducted at intermediate temperature and for shortened operation time as compared to conventional procedures. This process approach with reduced operating temperature and shortened operation time may open an opportunity window towards process economy with reduction in energy consumption. A simple mathematical approach of diffraction indexing using X-ray diffraction patterns of synthesized powder was employed to confirm its crystalline nature and to investigate its high temperature stability. The crystallite size was calculated by using Debye-Scherrer equation.

열수변질 점토맥과 산사태

  • 조환주;정경문;조호영
    • 광물과산업
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    • 제29권
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    • pp.56-66
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    • 2016
  • 열수변질대가 폭넓게 분포하고 있는 우리나라에서 자연사면이나 인공사면에서 열수변질대 내에 산출되는 점토맥이 산사태 발생에 중요한 역할을 할 수 있다. 점토맥이 존재하는 지반에 지표수가 침투되면 점토광물의 팽윤성 때문에 국지적으로 간극수압이 급격히 상승할 수 있다. 간극수압의 상승으로 세립의 점토광물이 침식될 수 있다. 침식된 점토광물은 수두가 큰 곳에서 작은 곳으로 유동하면서 동수경사가 작은 부분에서 유속이 느려져 퇴적된다. 점토광물이 퇴적된 곳에서 국지적인 간극수압의 증가로 인한 지하수의 유출이 사면파괴를 일으킬 수 있다. 이에 본고에서는 열수변질 점토맥과 산사태와 관련한 국내외 자료를 소개하고자 한다.

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2단계 수열합성을 이용한 ZnO 계층 나노구조 기반 UV 센서 제작 (Fabrication of UV Sensor Based on ZnO Hierarchical Nanostructure Using Two-step Hydrothermal Growth)

  • 우현수;김건휘;김수현;안태창;임근배
    • 센서학회지
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    • 제29권3호
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    • pp.187-193
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    • 2020
  • Ultraviolet (UV) sensors are widely applied in industrial and military fields such as environmental monitoring, medicine and astronomy. Zinc oxide (ZnO) is considered as one of the promising materials for UV sensors because of its ease of fabrication, wide bandgap (3.37 eV) and high chemical stability. In this study, we used the hydrothermal growth of ZnO to form two types of ZnO nanostructures (Nanoflower and nanorod) and applied them to a UV sensor. To improve the performance of the UV sensor, the hydrothermal growth was used in a two-step process for fabricating ZnO hierarchical nanostructures. The fabricated ZnO hierarchical nanostructure improved the performance of the UV sensor by increasing the ratio of volume to surface area and the number of nanojunctions compared to one-step hydrothermal grown ZnO nanostructure. The UV sensor based on the ZnO hierarchical nanostructure had a maximum photocurrent of 44 ㎂, which is approximately 3 times higher than that of a single nanostructure. The UV sensor fabrication method presented in this study is simple and based on the hydrothermal solution process, which is advantageous for large-area production and mass production; this provides scope for extensive research in the field of UV sensors.

열수변질 점토맥이 사면 안정성에 미치는 영향에 관한 모델링 연구 (Modeling Study for Effects of Hydrothermal Clay Vein on Slope Stability)

  • 조환주;조호영;정경문
    • 자원환경지질
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    • 제43권2호
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    • pp.185-196
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    • 2010
  • 열수변질에 의한 점토맥이 존재하는 사면 발생시 사면의 안전성에 영향을 미치는 것으로 알려져 있다. 파괴면의 형성 위치에 따라 접촉면 조건과 비접촉면 조건으로 분류하여 점토맥의 점착력, 내부마찰각, 방향성, 지하수위, 강우강도, 강우 지속시간 등의 인자에 따라 점토맥이 사면 안전율에 미치는 영향을 수치 모델링 연구를 통해 조사하였다. 지반 정수가 클수록 사면 안전율이 증가하였다. 사면 내 지히수위가 상승하면 사면 안전율이 감소하는 것을 확인하였다. 다양한 토양에 대한 강우 침투 모델링 결과 이질토는 강우강도에 따라 다양한 지하수위 발달 경향을 보인다. 반면에 사질토는 빠른 배수로 인해 지하수위의 상승이 거의 나타나지 않았다. 따라서 점토맥이 존재하는 사면에서 사질토는 이질토에 비해 사면 안전율에 미치는 영향이 적었다.

전기자동차 배터리 안정성 확보를 위한 냉각장치 열특성 연구 (A Study on the Thermal Characteristics of Cooling System for Securing Battery Stability in Electric Vehicle)

  • ;고광수;박윤철
    • 한국지열·수열에너지학회논문집
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    • 제16권2호
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    • pp.7-12
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    • 2020
  • The battery of an electric vehicle is a key part of the energy supply to operate the vehicles. There are many factors affecting battery life such as charging method, discharge rate, and ambient temperature those are requires systematic monitoring and management. To solve the issues like environmental problems and fuel consumption reduction the battery needs more performance improvement. In this study, it was analyzed the thermal characteristics and securing battery stability for electric vehicle battery cooling system. The simulation test was operated using GT-suite software with several conditions like cooling capacity 1, 2 and 4 kW, cooling flow rate 5, 10, 20 and 30 LPM, and battery initial temperatures 40, 35, and 30℃ at the temperature of ambient 25℃. The results shown that the case of cooling flow rate at 20 LPM was most efficient among all above conditions.

에너지파일과 에너지슬래브 적용 지열원 열펌프 시스템의 일일 냉방 운전 특성 비교 (Daily Cooling Performance Comparison of a Geothermal Heat Pump System between Energy-Pile and Energy-Slab)

  • 최종민;박용정;강신형
    • 한국지열·수열에너지학회논문집
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    • 제8권3호
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    • pp.29-35
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    • 2012
  • Geothermal heat pump system has been spotlighted as an efficient building energy system, because it has great potentials for reducing energy in building air conditioning and reducing $CO_2$ emissions. However, higher initial cost is a barrier to the promotion of its use. Energy-pile and energy-slab are known as low cost ground heat exchangers comparing with conventional ground heat exchangers, because they utilize building structures as ground heat exchangers. This paper presents the daily cooling performance of a geothermal heat pump system with energy-pile and energy-slab. The energy-piles and the energy-slabs are connected to heat pump units in parallel. The cooling capacity of the system was nearly constant due to the stability of the ground heat exchangers. The stability of the energy-pile was a little higher than that of the energy-stab as a heat sink.

Li-ion battery용 음극재료인 $SnO_2$의 합성법의 차이에 따른 음극 성능비교 (Comparing the methods of making $SnO_2$ nanomaterials with and without templates of anode material for Li-ion battery)

  • 심영선;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.132.2-132.2
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    • 2010
  • Mesoporous tinoxide ($SnO_2$) as anode materials for Li-ion battery were prepared by hydrothermal method and templating method using SBA-15 as template. And electrochemical properties of $SnO_2$ electrode were investigated with cyclic voltammogram (CV). The morphology and structures of $SnO_2$ were characterized by transmission electron microscopy (TEM) and X-ray diffractometer (XRD), respectively. The specific surface area was defined by $N_2$ adsorption with BET(Brunauer-Emmett-Teller) method. As a result, the surface area of mesoporous $SnO_2$ which was made from templating method is higher than the case of using hydrothermal method. In addition, in anodic performance, mesoporous $SnO_2$ which is prepared by templating method showed higher charge-discharge capasity compared to hydrothermal method and exhibited excellent stability over the entire cycle number. It was indicated that electrochemical performances of mesoporous $SnO_2$mainly affected to the structural features, such as specific surface area and porosity.

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유기성 폐기물의 고온고압수 반응에 의한 카르복시산 생성 (Carboxylic Acids Produced from Hydrothermal Treatment of Organic Wastes)

  • 강길윤;오창섭;김용하
    • 에너지공학
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    • 제13권3호
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    • pp.228-233
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    • 2004
  • 본 논문은 다양한 종류의 유기성 폐기물을 이용하여 고온고압수 반응에 의해 생성되는 저분자 카르복시산의 거동에 관해 고찰하였으며 산화제 첨가에 대한 영향도 동시에 검토를 행하였다. 그 결과 acetic, formic, succinic 및 lactic acid와 같은 유기산이 주된 생성물임을 알 수 있었다. 생선내장의 경우 35$0^{\circ}C$(P=16 MPa)의 조건에서 acetic acid비 수율은 26mg/g-dry를 얻을 수 있었으며 산화제로서 $H_2O$$_2$를 첨가했을 경우 42mg/g-dry로 수율이 증가함을 알 수 있었다. 또한 글루코오스를 이용한 실험결과에서는 약 29mg/g-dry의 acetic acid를 얻을 수 있었다. 유기산 생성에 관한 온도 의존성을 검토한 결과, acetic acid는 열적 안정성이 있음을 알 수 있었으나 formic acid는 상대적으로 쉽게 분해하는 경향을 나타내었다. 또한 산화제를 첨가 할 경우, acetic acid와 같은 유기산의 생성을 촉진 시키는 결과를 얻을 수 있었다.