• Title/Summary/Keyword: Hydrothermal Stability

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Fabrication and Characterization of Hexagonal Tungsten Oxide Nanopowders for High Performance Gas Sensing Application (육방정계 텅스텐옥사이드 나노분말의 합성과 고성능 가스센서응용을 위한 성능 평가)

  • Park, Jinsoo
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.28-33
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    • 2019
  • The gas sensor is essential to monitoring dangerous gases in our environment. Metal oxide (MO) gas sensors are primarily utilized for flammable, toxic and organic gases and $O_3$ because of their high sensitivity, high response and high stability. Tungsten oxides ($WO_3$) have versatile applications, particularly for gas sensor applications because of the wide bandgap and stability of $WO_3$. Nanosize $WO_3$ are synthesized using the hydrothermal method. As-prepared $WO_3$ nanopowders are in the form of nanorods and nanorulers. The crystal structure is hexagonal tungsten bronze ($MxWO_3$, x =< 0.33), characterized as a tunnel structure that accommodates alkali ions and the phase stabilizer. A gas detection test reveals that $WO_3$ can detect acetone, butanol, ethanol, and gasoline. This is the first study to report this capability of $WO_3$.

Cost effective and low energy consuming hydrothermal synthesis of Ni based MOF

  • Israr, Farrukh;Kim, Duk Kyung;Kim, Yeongmin;Oh, Seung Jin;Ng, Kim Choon;Chun, Wongee
    • Journal of Energy Engineering
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    • v.24 no.2
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    • pp.51-54
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    • 2015
  • The mesoporous metal organic framework structure of Ni-BTC was successfully synthesized in a low temperature and short operation time via hydrothermal synthesis process. Such operational route virtuously consumed less electrical and thermal energy. It proved time saving along with acceptable product yield (38%). The product was characterized through FESEM, FT-IR, XRD and $N_2$ gas adsorption measurement. Hightemperature stability of synthesized MOF was gauged by diffraction indexing of XRD patterns of as synthesized and heat treated samples of MOFs. The mathematically calculated particle size of Ni-BTC was found to be 42nm.

Hydrothermal Synthesis of Fe Based MOFs with Energy Economy Approach

  • Israr, Farrukh;Kim, Duk Kyung;Kim, Yeongmin;Oh, Seung Jin;Ng, Kim Choon;Chun, Wongee
    • Journal of Energy Engineering
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    • v.24 no.2
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    • pp.55-58
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    • 2015
  • The mesoporous metal organic framework structure Fe-BTC was successfully synthesized by hydrothermal process with noticeable yield. The synthesis operation was conducted at intermediate temperature and for shortened operation time as compared to conventional procedures. This process approach with reduced operating temperature and shortened operation time may open an opportunity window towards process economy with reduction in energy consumption. A simple mathematical approach of diffraction indexing using X-ray diffraction patterns of synthesized powder was employed to confirm its crystalline nature and to investigate its high temperature stability. The crystallite size was calculated by using Debye-Scherrer equation.

열수변질 점토맥과 산사태

  • Jo, Hwan-Ju;Jeong, Gyeong-Mun;Jo, Ho-Yeong
    • Mineral and Industry
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    • v.29
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    • pp.56-66
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    • 2016
  • In Korea, where hydrothermal alteration zones are widely distributed, clay veins formed by hydrothermal alteration processes on natural slopes or artificial slopes can play an important role in the slope stability. When the surface water infiltrates the ground where the clay vein exists, the pore water pressure in the ground can be locally increased due to impermeable properties of clay minerals. Infiltration of the surface water induces the increase in the pore water pressure, which can cause erosion of the fine clay particles. The eroded clay particles flow and deposit in an area where the flow velocity is slowed down. Where clay minerals are deposited, ground water can leak due to an increase in local pore pressures, which can cause slope failure. In this paper, studies related to hydrothermal clay vein and landslide are introduced.

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Fabrication of UV Sensor Based on ZnO Hierarchical Nanostructure Using Two-step Hydrothermal Growth (2단계 수열합성을 이용한 ZnO 계층 나노구조 기반 UV 센서 제작)

  • Woo, Hyeonsu;Kim, Geon Hwee;Kim, Suhyeon;An, Taechang;Lim, Geunbae
    • Journal of Sensor Science and Technology
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    • v.29 no.3
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    • pp.187-193
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    • 2020
  • Ultraviolet (UV) sensors are widely applied in industrial and military fields such as environmental monitoring, medicine and astronomy. Zinc oxide (ZnO) is considered as one of the promising materials for UV sensors because of its ease of fabrication, wide bandgap (3.37 eV) and high chemical stability. In this study, we used the hydrothermal growth of ZnO to form two types of ZnO nanostructures (Nanoflower and nanorod) and applied them to a UV sensor. To improve the performance of the UV sensor, the hydrothermal growth was used in a two-step process for fabricating ZnO hierarchical nanostructures. The fabricated ZnO hierarchical nanostructure improved the performance of the UV sensor by increasing the ratio of volume to surface area and the number of nanojunctions compared to one-step hydrothermal grown ZnO nanostructure. The UV sensor based on the ZnO hierarchical nanostructure had a maximum photocurrent of 44 ㎂, which is approximately 3 times higher than that of a single nanostructure. The UV sensor fabrication method presented in this study is simple and based on the hydrothermal solution process, which is advantageous for large-area production and mass production; this provides scope for extensive research in the field of UV sensors.

Modeling Study for Effects of Hydrothermal Clay Vein on Slope Stability (열수변질 점토맥이 사면 안정성에 미치는 영향에 관한 모델링 연구)

  • Jo, Hwan-Ju;Jo, Ho-Young;Jeong, Kyung-Mun
    • Economic and Environmental Geology
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    • v.43 no.2
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    • pp.185-196
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    • 2010
  • Clay veins that occurred in a slope by hydrothermal alteration, can significantly affect its slope stability. The effect of clay veins on the slope stability was investigated by numerical modeling study. Various parameters such as cohesion, internal friction angle, orientation, groundwater level, rainfall intensity and duration, have been modelled. As shear strength increased, factor of safety increased. As groundwater level developed, factor of safety decreased. For the case of slip surface developed on interface, factor of safety was lower than that for case of slip surface developed on either weathered soil or clay vein. The effect of various soil types of the slope stability was also investigated by simulating seepage through the slopes with various soils. The groundwater level significantly increased on the slopes with silty and generic soils. For the slope with sandy soil, almost no change in groundwater level was observed due to rapid drainage.

A Study on the Thermal Characteristics of Cooling System for Securing Battery Stability in Electric Vehicle (전기자동차 배터리 안정성 확보를 위한 냉각장치 열특성 연구)

  • Otgonpurev, Tuul;Ko, Gwang Soo;Park, Youn Cheol
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.16 no.2
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    • pp.7-12
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    • 2020
  • The battery of an electric vehicle is a key part of the energy supply to operate the vehicles. There are many factors affecting battery life such as charging method, discharge rate, and ambient temperature those are requires systematic monitoring and management. To solve the issues like environmental problems and fuel consumption reduction the battery needs more performance improvement. In this study, it was analyzed the thermal characteristics and securing battery stability for electric vehicle battery cooling system. The simulation test was operated using GT-suite software with several conditions like cooling capacity 1, 2 and 4 kW, cooling flow rate 5, 10, 20 and 30 LPM, and battery initial temperatures 40, 35, and 30℃ at the temperature of ambient 25℃. The results shown that the case of cooling flow rate at 20 LPM was most efficient among all above conditions.

Daily Cooling Performance Comparison of a Geothermal Heat Pump System between Energy-Pile and Energy-Slab (에너지파일과 에너지슬래브 적용 지열원 열펌프 시스템의 일일 냉방 운전 특성 비교)

  • Choi, Jong-Min;Park, Yong-Jung;Kang, Shin-Hyung
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.8 no.3
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    • pp.29-35
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    • 2012
  • Geothermal heat pump system has been spotlighted as an efficient building energy system, because it has great potentials for reducing energy in building air conditioning and reducing $CO_2$ emissions. However, higher initial cost is a barrier to the promotion of its use. Energy-pile and energy-slab are known as low cost ground heat exchangers comparing with conventional ground heat exchangers, because they utilize building structures as ground heat exchangers. This paper presents the daily cooling performance of a geothermal heat pump system with energy-pile and energy-slab. The energy-piles and the energy-slabs are connected to heat pump units in parallel. The cooling capacity of the system was nearly constant due to the stability of the ground heat exchangers. The stability of the energy-pile was a little higher than that of the energy-stab as a heat sink.

Comparing the methods of making $SnO_2$ nanomaterials with and without templates of anode material for Li-ion battery (Li-ion battery용 음극재료인 $SnO_2$의 합성법의 차이에 따른 음극 성능비교)

  • Shim, Young-Sun;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.132.2-132.2
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    • 2010
  • Mesoporous tinoxide ($SnO_2$) as anode materials for Li-ion battery were prepared by hydrothermal method and templating method using SBA-15 as template. And electrochemical properties of $SnO_2$ electrode were investigated with cyclic voltammogram (CV). The morphology and structures of $SnO_2$ were characterized by transmission electron microscopy (TEM) and X-ray diffractometer (XRD), respectively. The specific surface area was defined by $N_2$ adsorption with BET(Brunauer-Emmett-Teller) method. As a result, the surface area of mesoporous $SnO_2$ which was made from templating method is higher than the case of using hydrothermal method. In addition, in anodic performance, mesoporous $SnO_2$ which is prepared by templating method showed higher charge-discharge capasity compared to hydrothermal method and exhibited excellent stability over the entire cycle number. It was indicated that electrochemical performances of mesoporous $SnO_2$mainly affected to the structural features, such as specific surface area and porosity.

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Carboxylic Acids Produced from Hydrothermal Treatment of Organic Wastes (유기성 폐기물의 고온고압수 반응에 의한 카르복시산 생성)

  • 강길윤;오창섭;김용하
    • Journal of Energy Engineering
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    • v.13 no.3
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    • pp.228-233
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    • 2004
  • This paper reports production of low-molecular weight carboxylic acids from the hydrothermal treatment of representative organic wastes and compounds with or without oxidant (H$_2$O$_2$). Organic acids such as acetic, formic, succinic and lactic acids were obtained. This result increased to 42mg/g dry waste fish entrails in the presence of H$_2$O$_2$. Experiments on glucose representing cellulosic wastes were also carried out, getting acetic acid of about 29mg/g glucose. Studies on temperature dependance of formation of organic acids showed thermal stability of acetic acid, whereas, formic acid decomposed readily under hydrothermal conditions. In general. results demonstrated that the presence of oxidants favored formation of organic acids with acetic acid being the major product.