• Title/Summary/Keyword: Hydrophobic/hydrophilic surface

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A study of defrosting behavior according to surface characteristics in a fin-tube heat exchanger (표면 특성에 따른 휜-관 열교환기의 제상 거동에 관한 연구)

  • Lee, Kwan-Soo;Kim, Jun-Mo;Ji, Sung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.6
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    • pp.921-927
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    • 1999
  • In this study, the defrosting behaviors according to the surface characteristics in the fin-tube heat exchanger is experimentally examined. It is found that the draining rate of the hydrophilic and hydrophobic heat exchangers are evenly dispersed during defrosting, compared with that of the bare one. It is caused by the high density frost for the hydrophilic heat exchanger, and surface characteristic for the hydrophobic heat exchanger, respectively. The rest period of the hydrophilic and hydrophobic heat exchangers are shorter and their weight of residual water are smaller than those of the bare heat exchanger The hydrophilic and hydrophobic heat exchangers are more effective than the bare one in terms of defrosting efficiency, and the hydrophobic heat exchanger is better than the hydrophilic one.

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Surface modification of polymeric membranes for low protein binding

  • Higuchi, Akon;Tamai, Miho;Tagawa, Yoh-Ichi;Chang, Yung;Ling, Qing-Dong
    • Membrane and Water Treatment
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    • v.1 no.2
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    • pp.103-120
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    • 2010
  • Surface modification of microfiltration and ultrafiltration membranes has been widely used to improve the protein adsorption resistance and permeation properties of hydrophobic membranes. Several surface modification methods for converting conventional membranes into low-protein-binding membranes are reviewed. They are categorized as either physical modification or chemical modification of the membrane surface. Physical modification of the membrane surface can be achieved by coating it with hydrophilic polymers, hydrophilic-hydrophobic copolymers, surfactants or proteins. Another method of physical modification is plasma treatment with gases. A hydrophilic membrane surface can be also generated during phase-inverted micro-separation during membrane formation, by blending hydrophilic or hydrophilic-hydrophobic polymers with a hydrophobic base membrane polymer. The most widely used method of chemical modification is surface grafting of a hydrophilic polymer by UV polymerization because it is the easiest method; the membranes are dipped into monomers with and without photo-initiators, then irradiated with UV. Plasma-induced polymerization of hydrophilic monomers on the surface is another popular method, and surface chemical reactions have also been developed by several researchers. Several important examples of physical and chemical modifications of membrane surfaces for low-protein-binding are summarized in this article.

A Study of the Defrosting Behavior according to Surface Characteristics of a Fin-Tube Heat Exchanger

  • Jhee, Sung;Lee, Kwan-Soo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.8 no.2
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    • pp.101-107
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    • 2000
  • In this study, the defrosting behavior according to the surface characteristics of a fin-tube heat exchanger is experimentally examined. It has been found that the draining rates of the hydrophilic and hydrophobic heat exchangers are evenly dispersed during do-frosting, compared with that of the bare one. This is due to the high density frost of the hydrophilic heat exchanger, and the surface characteristics of the hydrophobic heat ex-changer, The rest periods of the hydrophilic and hydrophobic heat exchangers are shorter, and their weight of residual water is also smaller than that of the bare heat exchanger. The hydrophobic heat exchanger is the most efficient in terms of the defrosting efficiency.

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${\mu}-PIV$ Visualization of Flow in Hydrophilic and Hydrophobic Micro-nozzle (친수성 및 소수성 마이크로 노즐 내 유동 ${\mu}-PIV$ 연구)

  • Byun, Do-Young;Kim, Ji-Hoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.15-18
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    • 2006
  • Recently, experimental visualization of microscale fluid transport has attacted considerable attention in designing microelectromechanical systems. Fluid-surface interactions on hydrophobic and hydrophilic surfaces can play a key role in passively controlling microfluidics. Here we investigate the slip boundary condition depending on the surface characteristics; hydrophilic, hydrophobic wettabilities. Using the micro-PIV, velocity profiles are measured in the glass (hydrophilic), PDMS (hydrophobic) microchannels.

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An Experimental Study of the Surface Treatment Effect on the Frosting/Defrosting Behavior of a Fin-Tube Heat Exchanger (휜-관 열교환기의 착.제상 거동에 대한 표면처리의 영향에 관한 실험적 연구)

  • Jhee, Sung;Lee, Kwan-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.8
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    • pp.1062-1068
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    • 2000
  • The effect of heat exchanger surface treatment on the frosting/defrosting behavior in a fin-tube heat exchanger is investigated experimentally. It is found that the hydrophilic surface mainly influences on the frosting behavior, however, the hydrophobic surface gives some influence on the defrosting behavior. In view of frosting performance, surface-treated heat exchanger with either hydrophilic or hydrophobic characteristic shows a little improvement in the thermal performance than the aluminium heat exchanger with no surface treatment. The result reveals that the heat exchanger with hydrophobic surface treatment is more effective in view of the defrosting efficiency and time. The amounts of residual water on the surface-treated heat exchangers are shown to be smaller than those of the bare heat exchanger, therefore further improvements on the performance of re-operations are expected.

The effect of surface contact angle on the behavior of frost formation in a fin-tube heat exchanger (핀-관 열교환기의 착상 거동에 대한 표면 접촉각의 영향)

  • Lee, K. S.;Jhee, S.;Lee, D. W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.95-101
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    • 2000
  • The effect of surface contact angle on the behavior of frost formation in a fin-tube heat exchanger is investigated experimentally. It is shown that both heat exchangers with hydrophilic and hydrophobic surfaces appear to have a better thermal performance than bare aluminium heat exchanger, but the improvements are very small. There is a little increase in the amount of the frost deposited onto the heat exchanger with both hydrophilic and hydrophobic surface. However, the effect of contact angle on the frost density is observed ; the frost with high density forms on the heat exchanger with hydrophilic surface ; and the frost with low density is deposited onto the heat exchanger with hydrophobic surface when compared with the frost deposited onto the heat exchanger with bare aluminium surface. This may be attributed to the fact that the shape of water droplets which condense on the surface of heat exchanger at the early stage of frosting varies with contact angle, and thus makes a difference on the structure of frost formation. From the experiments with different relative humidity of inlet air, it is shown that the variations of operating parameter make no influence on the effect of surface contact angle on the frosting behavior in the heat exchanger.

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Hydrophilic/Hydrophobic Conversion of $TiO_2$ Films by Reactive Magnetron Sputtering (Reactive Magnetron Sputtering법으로 제조된 $TiO_2$의 친수성/소수성 변환 특성)

  • 이영철;박용환;안재환;고경현
    • Journal of the Korean Ceramic Society
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    • v.36 no.11
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    • pp.1211-1216
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    • 1999
  • TiO2 thin films were prepared by reactive magnetron sputtering on glass substrate and subjected into investigation about their hydrophilic properties. Varing Ar/O2 ration and post annealing at 50$0^{\circ}C$ for 12h anatase and rutile phases of TiO2 films were obtained. Hydrophilic properties were evaluated by determination of contact angle of water droplet on TiO2 surface. On as-annealed TiO2 films water droplet spreaded widely with ~0$^{\circ}$contact angle. Sonication(60 Hz, 28kHz 40kHz) and following dark room treatments turned these hydrophilic TiO2 films into hydrophobic state. All of hydrophobic films were converted recersibly into their original state after UV illumination. Hydrophobic states of anatase films were saturated after sonication and remain same during dark room treatment. But it was found that the conversion into hydrophobic state of rutile films progressed. further after sonication. Therefore it was concluded that Ti3+/Ti+4 ratio is the key to determine hydrophilicity of TiO2 surface so that different surface structure of polymorphs could lead to unique characteristics.

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Wetting Characteristic of Single Droplet Impinging on Hole-Patterned Texture Surfaces (홀 패턴 텍스쳐 표면에서 충돌하는 단일 액적의 젖음 특성)

  • Moon, Joo Hyun;Lee, Sangmin;Jung, Jung-Yeul;Lee, Seong Hyuk
    • Journal of ILASS-Korea
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    • v.20 no.3
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    • pp.181-186
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    • 2015
  • This study presents the dynamic wetting characteristics of an impact droplet on hole-patterned textured surfaces. The flat surfaces were manufactured by a drilling machine to generate the micro-order holes, leading to make the surface hydrophobic. Other flat surfaces were fabricated by the anodizing technique to make hydrophilic texture surfaces with a nanometer order. For hydrophilic and hydrophobic textured surfaces with similar texture area fractions, the impinging droplet experiments were conducted and compared with flat surface cases. As results, an anodized textured surface decreases apparent equilibrium contact angle and increases contact diameters, because of increase in contact area and surface energy. This is attributed to more penetration inside holes from larger capillary pressure on nanometer-order holes. On the other hand, temporal evolution of the contact diameter is smaller for the hydrophobic textured surface from less penetration on the micro-order holes.

Highly Stable Photoluminescent and Magnetic Multilayers Using Nucleophilic Substitution Reaction in Organic Media

  • Jo, Jin-Han
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.262-262
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    • 2010
  • We introduce a novel and efficient strategy for producing free-standing functional films via photo-crosslinking and electrostatic layer-by-layer (LbL) assembly, which can allow the buildup of hydrophilic multilayers onto hydrophobic surfaces. Hydrophobic multilayers were deposited on ionic substrates by a photo-crosslinking LbL process using photo-crosslinkable polymers. The photo-crosslinked surface was converted to an anionic surface by excess UV light irradiation. This treatment allowed also the stable adhesion between metal electrode or cationic polyelectrolyte and hydrophobic multilayers. After dissolving the ionic substrates in water, the formed free-standing films exhibited unique functionalities of inserted components within hydrophobic and/or hydrophilic multilayers.

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Surface and Interfacial Energetic Analysis of Amphiphilic Copolymers

  • Kim, Min-Kyun;Yuk, Soon-Hong;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.8 no.3
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    • pp.158-161
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    • 1987
  • A Series of hydrophilic-hydrophobic copolymeric surfaces of 2-hydroxyethyl methacrylate (HEMA) and various alkyl methacrylate (RMA) have been prepared by in-situ solution copolymerization using a redox radical initiator. Contact angles of various probing fluids on the polymeric surfaces were determined in air (hydrophobic environment) and under water (hydrophilic environment). From contact angle data, the dispersive interaction contribution (${\gamma}^d_s$) and the polar contribution (${\gamma}^p_s$) to the total surface free energy (${\gamma}^d_s$) and interfacial energetic quantities (e.g., water-polymer, liquid-polymer interface, etc.) were estimated by surface and interface physicochemical theory. From the comparison of surface energetic components between hydrophobic and hydrophilic media, it is found that surface and interface energetic components of polymeric surface as a representative low-energy surface are highly dependent on environmental fluids. Also, from the correlation between interfacial energetic results and surface energetic criterion of biocompatibility, we found that HEMA/BMA, HEMA/HMA copolymer systems are in the region of biocompatibility.