• Title/Summary/Keyword: Hydrophilic Treatment

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Hydrophilic Modification of Polypropylene Hollow Fiber Membrane by Dip Coating, UV Irradiation and Plasma Treatment

  • Kim Hyun-Il;Kim Jin Ho;Kim Sung Soo
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.19-27
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    • 2005
  • PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

Variation of dissolved organic matter in 2nd treated sewage water by Al(III) coagulant (Al(III) 응집제에 의한 하수처리수 중의 유기물 성상 변화)

  • Kim, Jungsun;Han, Seungwoo;Kim, Suhyun;Kang, Limseok
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.233-240
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    • 2016
  • Control degree and property changes of dissolved organic matter (DOM) were conducted by coagulation of chemical treatment for 2 sewage treatment plants with different technical methods. As the result, SUVA value of the second treated water (supernatant of the second settling pond after biological treatment) was increased and DOC was reduced in comparison with supplied raw water. And, SUVA value and DOC were reduced by coagulation after coagulation treatment of the second treated water. Properties of dissolved organic matter for 2 sewage treatment plants's DOC were divided. As the result, there was lots of hydrophilic component with hydrophilicity in case of plant A. In case of the second treated water, Plant A showed fulvic acid with little molecular weight was reduced among the hydrophobic component with hydrophobicity, but numic acide with lots of molecular weight was increased. However, in case of plant B, both fulvic acid with little molecular weight and humic acid with lots of molecular weight were increased among the hydrophobic components with hydrophilicity. Before the operation of phosphorus facility, properties of dissolved organic matter after biodegradation with effluent water showed hydrophilic components were reduced and hydrophobic components were increased. However, after coagulation treatment of the second treated water, hydrophilic components and hydrophobic components were outstandingly decreased or increased. During the biodegradation after coagulation treatment, hydrophilic components were significantly decreased and hydrophobic components were increased.

Hydrophilic Effect of the Polyimide by Atmospheric Low-temperature Plasma Treatment (대기압 저온 플라즈마 처리에 의한 폴리이미드의 친수화 효과)

  • Cho, J.H.;Kang, B.K.;Kim, K.S.;Choi, B.K.;Kim, S.H.;Choi, W.Y.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.2
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    • pp.148-152
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    • 2005
  • Atmospheric low-temperature plasma was produced using dielectric barrier discharge (DBD) plate-type plasma reactor and high frequency of 13.56 Hz. The surfaces of polyimide films for insulating and packaging materials were treated by the atmospheric low-temperature plasma. The contact angle of 67$^{\circ}$ was observed before the plasma treatment. The contact angle was decreased with deceasing the velocity of plasma treatment. In case of oxygen content of 0.2 %, electrode gap of 2 mm, the velocity of plasma treatment of 20 mm/sec, and input power of 400 W, the minimum contact angle of 13$^{\circ}$ was observed. The chemical characteristics of polyimide film after the plama treatment were investigated using X-ray photoelectron spectroscopy (XPS), and new carboxyl group bond was observed. The surfaces of polyimide films were changed into hydrophilic by the atmospheric low-temperature plasma. The polyimide films having hydrophilic surface will be very useful as a packaging and insulating materials in electronic devices.

Estimation of energy self-sufficiency in municipal wastewater treatment plant using photovoltaic power simulated by azimuth and hydrophilic coating (방위각과 초친수코팅에 따른 태양광발전량 시뮬레이션과 하수처리장 에너지자립율 산정)

  • An, Young-Sub;Kim, Sung-Tae;Kang, Ji-Hoon;Chae, Kyu-Jung;Yoon, Jong-Ho
    • KIEAE Journal
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    • v.11 no.6
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    • pp.133-138
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    • 2011
  • This paper presents energy self-sufficiency simulated in municipal wastewater treatment plants (WWTPs) by adopting solar energy production systems that were simulated by varying azimuth and super-hydrophilic coating on the surface of photovoltaic (PV). Relative to the national average energy consumption in WWTPs, the employment of 100 kW PV system was simulated to achieve 2.75% of energy self-sufficiency. The simulated results suggested that the installation of PVs toward South or Southwest would produce the highest energy self-sufficiency in WWTPs. When super-hydrophilic coating was employed in the conventional PV, 5% of additional solar energy production was achievable as compared to uncoated conventional PV. When 100 kW of PV system was installed in a future test-bed site, Kihyeung Respia WWTP located in Yongin, South Korea, the energy self-sufficiency by solar power was simulated to be 1.77%. The simulated solar power production by azimuth and super-hydrophilic coating will be useful reference for practitioners in designing the solar PV systems in the WWTPs.

An Experimental Study of the Surface Treatment Effect on the Frosting/Defrosting Behavior of a Fin-Tube Heat Exchanger (휜-관 열교환기의 착.제상 거동에 대한 표면처리의 영향에 관한 실험적 연구)

  • Jhee, Sung;Lee, Kwan-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.8
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    • pp.1062-1068
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    • 2000
  • The effect of heat exchanger surface treatment on the frosting/defrosting behavior in a fin-tube heat exchanger is investigated experimentally. It is found that the hydrophilic surface mainly influences on the frosting behavior, however, the hydrophobic surface gives some influence on the defrosting behavior. In view of frosting performance, surface-treated heat exchanger with either hydrophilic or hydrophobic characteristic shows a little improvement in the thermal performance than the aluminium heat exchanger with no surface treatment. The result reveals that the heat exchanger with hydrophobic surface treatment is more effective in view of the defrosting efficiency and time. The amounts of residual water on the surface-treated heat exchangers are shown to be smaller than those of the bare heat exchanger, therefore further improvements on the performance of re-operations are expected.

Growth Responses of Eggplant (Solanum melongena) to Hydrophilic Polymer Mixture Ratio in Growing Medium for Lower Maintenance Urban Agriculture via Green Roofs (옥상 내 저관리 도시농업에서 친수성 중합체 배합비에 따른 가지(Solanum melongena)의 생육반응)

  • Ju, Jin-Hee;Kim, Won-Tae;Xu, Hui;Yoon, Young-Han;Choi, Eun-Young
    • Journal of Environmental Science International
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    • v.25 no.5
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    • pp.625-633
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    • 2016
  • This study was conducted to investigate the influence of hydrophilic polymer (HP) mixture ratio (Control, 1.0%, 2.5%, 5.0%, and 10.0%) on growth of eggplant (Solanum melongena) for lower maintenance urban agriculture via green roofs. Although it was not statistically significant (p > 0.05), substrate temperature was decreased as hydrophilic polymer mixture ratio were increased. High substrate water content (95%) was found consistently in growing media under elevated hydrophilic polymer mixture ratio at over 5% during the entire growing period. Substrate electronic conductivity was increased as hydrophilic polymer mixture ratio were increased. Growth index was decreased as hydrophilic polymer mixture ratio was increased. It was reduced about 1/3 and 1/5 compared to that of Control in HP5.0 and HP10.0 treatment plants, respectively. Number of leaves, leaf length, and leaf width were decreased in following order: Control> HP1.0> HP2.5> HP5.0> HP10.0 treatments. There numbers were significantly lower in HP5.0 and HP10.0 treatment plants. Dry weight of shoot and root were decreased as hydrophilic polymer mixture ratio was increased. They were reduced by 1/4 compared to those of Control treatment plants. In addition, visual value was decreased as hydrophilic polymer mixture ratio was increased. Plants grown in HP1.0, HP2.5, and HP5.0 treatments all survived. However, plants grown in the HP10.0 treatment had the lowest survival rate (56%) after 3 months of growing. These results indicate that the advantage of adding hydrophilic polymer to green roof growing media may greater during dry periods. However, the proper mixture proportion of hydrophilic polymer should be determined according to different characteristics of growing media and plant species.

Recovery Process for the Recycling of Waste Carbon Black

  • Lee, Sungoh;Nampyo Kook;Tam Tran;Bangsup Shin;Kim, Myongjun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.215-219
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    • 2001
  • Impurities removal from waste carbon black was carried out to produce high-grade carbon black. A lot of hydrophilic carbon black is produced as a byproduct of the hydrogen production process by flame decomposition of water. Due to its impurity content such as sulphur, iron, ash and etc., it can only be used as low-grade carbon or burnt out. High-grade hydrophilic carbon black is 3-5 times more expensive than oil-based carbon black because of its process difficulties and requires pollutant treatment. Hydrophilic carbon is normally used far conductive materials for batteries, pigment for plastics, electric wire covering, additives for rubber, etc.. In these applications, hydrophilic carbon must maintain its high purity. In this study magnetic separation, froth flotation and ultrasonic treatment were employed to remove impurities from the low-grade hydrophilic carbon black. As results, the ash, iron and sulphur content of product decreased to less than 0.01wt.%, 0.0lwt.% and 0.3wt.% respectively, and the surface area of product was about 930 $m^2$/g.

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Experimental study on the hydrophilic performance of pre-coated aluminum foil (알루미늄 호일의 친수코팅 성능 개선에 관한 실험적 연구)

  • 김영생;길용현;박환영;윤백;김자수소;김병열
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.6
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    • pp.725-732
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    • 1999
  • It is usual to use hydrophilic-coated aluminum foil for evaporator fin of air-conditioners to reduce air flow resistance caused by the water droplets condensed on the fin surface. The major effect of a hydrophilic coating is to reduce the contact angle of the condensate and prevent bridging of the condensate between the adjacent fins. The performance of hydrophilic coating generally tends to be degraded as it is used since the coating material is washed down by the condensate. In the present work, several types of hydrophilic coatings were evaluated in terms of durability of hydrophilicity, corrosion resistance and heat resistance. Results showed that an improved hydrophilic coating of resin type presented superb qualify in terms of durability and corrosion resistance while having almost the same level of qualify in heat resistance compared with the others.

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An Experimental Study on the Effects of Contact Angle on a Falling Liquid Film (접촉각이 유하액막 특성에 미치는 영향에 관한 실험적 연구)

  • Kim, Kyung-Hee;Kang, Byung-Ha;Lee, Dae-Young
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.11
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    • pp.867-873
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    • 2006
  • Vertical falling liquid film is extensively used in heat and mass transfer processes of many applications, such as evaporative coolers, cooling towers, and absorption chillers. In such cases, it is required that the falling film spreads widely in the surface forming thin liquid film to enlarge contact surface. An addition of surface active agent to a falling liquid film or hydrophilic surface treatment affects the fluid physical properties of the film. Surfactant addition not only decreases contact angle between the liquid and solid surface but also changes the surface from hydrophobicity to hydrophilicity. In this study, the effects of contact angle on falling film characteristics over a vertical surface have been investigated experimentally. The contact angle is varied either by an addition of surfactant to the liquid or by hydrophilic surface treatment. It is found that the wetted area is increased and film thickness is decreased by the hydrophilic treatment as compared with those of other surfaces. With this hydrophilic treatment, the falling liquid film spreads out widely in the surface. As surfactant concentration is increased, wetted area is also increased and the film thickness is substantially decreased.

Formation and Removal of Trihalomethanes based on Characterization of Hydrophobic and Hydrophilic Precursors (전구물질의 소수성 및 친수성 특성에 따른 트리할로메탄의 생성과 제거에 관한 연구)

  • Jeon, Heekyung;Kim, Junsung;Choi, Yoonchan;Choi, Haeyeon;Chung, Yong
    • Journal of Korean Society on Water Environment
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    • v.24 no.1
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    • pp.123-128
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    • 2008
  • The Dissolved Organic Carbon (DOC) existing in a water includes both hydrophobic and hydrophilic substances however, most of the discussion focuses on hydrophobic substances. The hydrophobic fraction was easily removed by absorption or coagulation more than hydrophilic fraction. Therefore, control of the hydrophilic fraction is very important in water treatment process. This study is to determine the variation of DOC, the removal efficiency of DOC, and Trihalomethane formation potential (THMFP) after each stage of water treatment process by fractionating Natural Organic Matters (NOM) into hydrophobic and hydrophilic substance. DOC from raw water was fractionated at acidic pH (pH<2) using XAD 8 resin column, into two fraction : hydrophobic substance (i.e. humic substance) adsorbed on XAD 8 and hydrophilic substance which represent the organics contained in the final effluent. THMFP was carried out according to the following set condition: Cl2/DOC=4 mg/mg, incubation at $25^{\circ}C$ in darkness, pH 7 adjust with HCl or NaOH as necessary, and 72hour-contact time. THMs analyzed in this study were chloroform, bromodichloromethane, dibromochloromethan, and bromoform. Sewage was almost evenly split between the hydrophobic (56%) and hydrophilic fraction (44%). But, Aldrich humic substance (AHS) was found to contain less hydrophilics (14%) than hydrophobics (86%). The formation of THMs may depend on the source which is characterized by the composition of organic matters such as AHS and sewage. The THMFP yield of sewage and AHS were assessed as follows. The value of the THMFP reaction yield, AHS $172.65{\mu}g/mg$, is much higher than that of sewage $41.68{\mu}g/mg$. This illustrates possible significant difference in THMFP according to the component type and the proportion of organic matter existing in water source. Apparently AHS react with chlorine to produce more THMFP than do the smaller molecules found in sewage. Water treatment process may reduce THMFP, nevertheless residual DOC (the more hydrophilic substance) has significant THMFP. Further reduction in organic halide precursors requires application of alternative treatment techniques.