• 제목/요약/키워드: Hydrogen transfer

검색결과 544건 처리시간 0.026초

Ionization of Hydrogen in the Solar Atmosphere

  • Chae, Jongchul
    • Journal of Astronomy and Space Sciences
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    • 제38권2호
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    • pp.83-92
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    • 2021
  • The ionization degree of hydrogen is crucial in the physics of the plasma in the solar chromosphere. It specifically limits the range of plasma temperatures that can be determined from the Hα line. Given that the chromosphere greatly deviates from the local thermodynamic equilibrium (LTE) condition, precise determinations of hydrogen ionization require the solving of the full set of non-LTE radiative transfer equations throughout the atmosphere, which is usually a formidable task. In many cases, it is still necessary to obtain a quick estimate of hydrogen ionization without having to solve for the non-LTE radiative transfer. Here, we present a simple method to meet this need. We adopt the assumption that the photoionizing radiation field changes little over time, even if physical conditions change locally. With this assumption, the photoionization rate can be obtained from a published atmosphere model and can be used to determine the degree of hydrogen ionization when the temperature and electron density are specified. The application of our method indicates that in the chromospheric environment, plasma features contain more than 10% neutral hydrogen at temperatures lower than 17,000 K but less than 1% neutral hydrogen at temperatures higher than 23,000 K, implying that the hydrogen temperature determined from the Hα line is physically plausible if it is lower than 20,000 K, but may not be real, if it is higher than 25,000 K. We conclude that our method can be readily exploited to obtain a quick estimate of hydrogen ionization in plasma features in the solar chromosphere.

극저온 액체수소 저장탱크 지지시스템의 열응력 해석 (Thermal Stress Analysis of the Support System in Cryogenic Liquid Hydrogen Storage Tank)

  • 박동훈;윤상국;이정환;조원일;백영순
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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    • pp.239-245
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    • 2005
  • The reduction of heat transfer rate to the stored liquid hydrogen from outside condition is extremely important to keep the liquid hydrogen longer. In this paper the highly efficient support system for the liquid hydrogen storage vessel was newly developed and analysed. The support system was composed of a spherical ball in the center of supporter to reduce the heat transfer area, with its above and below supporting blocks which are the SUS and PTFE blocks inserted in the SUS tube. The heat transfer rate and temperature distribution of the support system were evaluated by FLUENT, and the thermal stress and strain were estimated by ANSYS software. The results showed that the heat transfer rate from outer vessel to inner one was extremely decreased compared with the common method which is simply SUS tubes inserted between inner and outer tanks. The thermal stress and strain were obtained well below the limited values. As a result, it was the most efficient support system of storage vessel for liquid hydrogen and most cryogenic fluids.

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AC Impedance Study of Hydrogen Oxidation and Reduction at Pd/Nafion Interface

  • Song, Seong-Min;Koo, Il-Gyo;Lee, Woong-Moo
    • 한국수소및신에너지학회논문집
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    • 제12권3호
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    • pp.231-238
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    • 2001
  • Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

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금속수소화물 수소저장 용기 내부의 열 및 물질전달 현상에 대한 수치적 연구(I) - $LaNi_5$ 베드를 이용한 수소 흡장반응 해석 모델 개발 (Numerical analysis of the coupled heat and mass transfer phenomena in a metal hydride hydrogen storage reactor(I) - Model development of analyzation for hydrogen absorption reaction using the $LaNi_5$ bed)

  • 남진무;주현철
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.225.1-225.1
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    • 2010
  • Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

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산란 및 투과된 수소 이온의 분자 전산 연구 III. 니켈 (100) 표면 층의 운동에너지 (Molecular Simulation Studies of Scattered and Penetrated Hydrogen Ions III. Kinetic Energies in Ni (100) layers)

  • 서승혁;민웅기
    • 한국수소및신에너지학회논문집
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    • 제12권3호
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    • pp.191-199
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    • 2001
  • In this paper molecular dynamics simulations have been carried out to investigate energy and momentum transfer of hydrogen ions impacted on the Ni (100) surface with $45^{\circ}$ and $90^{\circ}$ incident angles. The initial kinetic energies of the hydrogen ion were ranged from 100 eV to 1,600 eV to study the layer-by-layer energy variation as a dependence of incident energies and angles. At low incident energies, the scattering energy transfer is dominated by the normal motion of surface layers due to thermal vibrations and multiple collision effects. For higher incident energies, the scattering energy transfer in a normal direction is greater than that in a parallel direction. In the case of penetration, the amount of transferred energies do not affect much on Ni layers at low incident energy. It was found channeling effects through Ni layers with increasing incident energies.

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분산형 소형 연료전지용 1KW급 열교환기 설계 (Heat Exchanger Design For The Individually Allocated Fuel Cell For 1kw Power generation)

  • 이택홍;박태성;김태완;노재현;강영진
    • 한국수소및신에너지학회논문집
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    • 제25권1호
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    • pp.39-46
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    • 2014
  • Our lab designs a heat exchangers for hydrogen gas. Coolant is water, thus it is very difficult to determine heat transfer parameters in this gas-liquid system. Repeated experiments gives overdesign value 6.06%, overall heat transfer coefficient 36.32 ($kcal/m^2-hr-^{\circ}C$) for Hydrogen. Theoretically determined overall heat transfer coefficient is 38.44 ($kcal/m^2-hr-^{\circ}C$). Our lab simulated this system and overdesign 30.4% shows good match with this experiment by HTRI. These parameters are in same range with literature.

소형 수소저장물질 유효열전도도 측정장치의 신뢰성 평가 (Reliability Evaluation of Miniaturized Measurement Cell of Effective Thermal Conductivity for Hydrogen Storage Materials)

  • 이영효;임연호
    • 한국수소및신에너지학회논문집
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    • 제26권5호
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    • pp.431-437
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    • 2015
  • Recently, a miniaturized measurement cell of effective thermal conductivity was developed to evaulate the heat transfer characteristics of hydrogen stroage material in the initial step of its development. In this work, the realiablity issues which can occur from this miniaturization of measurement cell were studied in detail by both experiments and numerical simulation of heat transfer. $LaNi_5$ as a reference was used for the reliability evaluation of the miniaturized measurement cell. Numerical simulations of heat transfer for this measurement system were verified through comparison with the experimental data. Under these reliablity studies, we discuss how to overcome the inherent drawbacks of this miniaturized system in order to achieve the high reliability.

극저온 고압액체수소 공급을 위한 실험실 규모 인쇄기판 열교환기의 복합열전달 해석을 통한 방빙설계에 관한 연구 (A Study on Anti-Icing Design by Conjugate Heat Transfer Analysis in a Lab-Scale Printed Circuit Heat Exchanger for Supply of Cryogenic High Pressure Liquid Hydrogen)

  • 손상호;김우경
    • 한국수소및신에너지학회논문집
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    • 제33권5호
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    • pp.541-549
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    • 2022
  • This study investigates anti-icing design by conjugate heat transfer analysis in lab-scale printed circuit heat exchanger (PCHE) for supply of cryogenic high pressure liquid hydrogen. The conjugate heat transfer analysis by using computational dynamics (CFD) provided various temperature distributions at important locations in PCHE heat exchanger and predicted the possibility of freezing in hot channel. And, the effect of inlet temperature of glycol water was analyzed in order to resolve the freezing problem in PCHE.

광합성 박테리아를 이용한 고성능 수소 생산 고정화 생물반응기의 개발(I) 고정화 연속 교반탱크 반응기에서의 수소 생산성 및 효율인자 평가 (Development of Bioreactors for Hydrogen-Producing Immobilized Photosynthetic Bacteria(I) : Evaluation of lmmobilized CSTR for Hydrogen Productivity and Effectiveness Factor)

  • 선용호;한정우
    • KSBB Journal
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    • 제8권3호
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    • pp.243-255
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    • 1993
  • In this study, it was observed that hydrogen Productivity varied with stirrer speed, bead radius, input glucose concentration and dilution rate in a continuous stirred tank reactor in which immobilized R. rubrum KS-301 was used as a hydrogen-producing bacterium The mass transfer resistance due to cell immobilization was also studied. In order to estimate an effectiveness factor, Des of glucose was first obtained, which was subsequently represented by the correlation equation between Dos and Xb, As a result external mass transfer resistance could be neglected for stirrer speeds greater than 400rpn With bead radius increasing, the hydrogen productivity and internal effectiveness factor decreased. With input 91ucose concentration increasing, the hydrogen productivity and interval and external effectiveness factor increased. Although an Internal effectiveness factor was not affected, hydrogen productivity Increased with dilution rate increasing. An overall effectiveness factor remained nearly constant for the dilution rates investigate4 but increased with input 91ucose concentration increasing.

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Radiative Transfer in Highly Thick Media through Rayleigh and Raman Scattering with Atomic Hydrogen

  • Chang, Seok-Jun
    • 천문학회보
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    • 제46권2호
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    • pp.40.1-40.1
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    • 2021
  • Hydrogen is the most abundant element in the universe, which is, in the cosmological context, attributed to its simplest structure consisting of a proton and an electron. Hydrogen interacts with an electromagnetic wave in astrophysical environments. Rayleigh scattering refers to elastic scattering, where the frequencies of the incident and scattered photons are the same. Rayleigh and resonance scattering is a critical role study Lyman Alpha objects in the early universe. The scattering causes the frequency and spatial diffusion of Lyα. In the case of Raman scattering, the energies of the incident and scattered photons are different. The photons near Lyβ convert to the optical photons near Hα through Raman scattering. The photon scattered by atomic hydrogen can carry both of the properties of the H I region and the emission region. I adopt a Monte Carlo approach to investigate the formation of the various spectral line features through Rayleigh and Raman scattering in highly thick media of atomic hydrogen. In this thesis, I present my works on radiative transfer involving the scattering processes between far UV photon and atomic hydrogen. I introduce scattering processes with atomic hydrogen and the spectral, spatial, and polarized information originating from the scattering.

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