• Fire Science and Engineering
• /
• v.26 no.5
• /
• pp.35-40
• /
• 2012

Numerical investigation was performed to study on the soot formation characteristics in the WSR according to the CO addition. Ethylene and pure air were used as a fuel and an oxidizer, respectively, and three different equivalence ratios (2.0, 2.5, 3.0) were used in the calculation. The resulted CO mole fraction of 10 % CO addition showed the maximum value in spite of the least CO supply. This means that the conversion of CO to soot and other carbon compounds is weakened under incipient soot formation. The soot volume fraction was decreased with increasing the CO addition because the important species for soot formation such as pyrene and acetylene, were decreased with the addition of CO. When the equivalence ratio was 2.5, the soot volume fraction shows the highest value, which results from the contribution of fuel rich condition and reacting temperature. Furthermore, surface growth rate and species concentrations justified the HACA mechanism for soot formation.

• Journal of Veterinary Clinics
• /
• v.35 no.2
• /
• pp.39-45
• /
• 2018

We evaluated the effects of green tea extract (GTE) supplementation at different dilution steps on boar sperm freezing and in vitro fertilization. Sperm intracellular hydrogen peroxide ($H_2O_2$), motility, viability, acrosome integrity and morphology were determined. In addition, sperm IVF parameters (penetration and monospermy) and glutathione (GSH) levels of presumptive zygotes (PZs) were evaluated. Semen was diluted in lactose egg yolk (LEY) and cooled at $5^{\circ}C$ for 3 h (first dilution step) and then diluted in LEY with 9% glycerol and maintained at $5^{\circ}C$ for 30 min (second dilution step). Four experimental groups were compared: first and second dilution steps without GTE (control), first dilution step with GTE (Step 1), second dilution step with GTE (Step 2) and first and second dilution step with GTE (Step 1+2). The spermatozoa were frozen in nitrogen vapor. Higher sperm motility, viability and acrosome integrity after thawing were observed in Step 1, Step 2 and Step 1+2 groups compared with the control (P < 0.05). Lower $H_2O_2$ level was observed in Step 1+2 compared with control and Step 1 (P < 0.05). For IVF, matured oocytes were co-cultured with spermatozoa frozen according to the experimental groups. GSH levels of PZs were significantly higher in Step 2 and Step 1+2 than in control and Step 1 (P < 0.05) without a significant difference in IVF parameters. In conclusion, supplementation with GTE in both first and second dilution steps during the freezing process resulted in better boar sperm cryopreservation and might be beneficial for further embryo development.

• Journal of the Korean Society of Safety
• /
• v.26 no.2
• /
• pp.42-47
• /
• 2011

Going underwater is supposed to begin with the history of human beings. At first it was confined to relatively shallow level, less than several meters by holding breath. Recently, deep level diving has been necessary for such purpose as construction, maritime salvage, military operations, research and sports by using SCUBA(self-contained underwater breathing apparatus) equipment. As one goes down into water, the pressure on the diver is increased due to water pressure with depth, usually 1 atm for each 10 m water level. In deep water, mixed gas or nitrox(EAN, enriched air nitrox) could be applied for the divers lest they should get disease due to high pressure. Of these, the former is usually composed of oxygen and inert gas like helium or hydrogen, the latter contains higher oxygen content than that in normal air in which the oxygen concentration is designated by the character "EAN" followed by vol. % of oxygen, for example, "EAN 40" contains 40% of oxygen. In this case, a victim was found at the 39 m below the sea surface breathing air and nitrox in cylinder wrongly marked as EAN 36, which was analyzed to contain 63% of oxygen by GC/TCD. The cause of death could not be exactly related with the oxygen content in the nitrox cylinder, because the accurate depth for the victim to dive was not known, even though the victim was just found at the depth of 39 m. However, the wrongly marked nitrox could be believed to be the main cause of the death at the depth unless there happened any other accident except that during diving.

• Journal of the Korean Institute of Gas
• /
• v.17 no.4
• /
• pp.9-17
• /
• 2013

Butanethiol is known as a typical odorant with hydrogen sulfide, methyl mercaptan, methyl sulfide, but on the physical and chemical properties and biological hazard assessment, including inhalation toxicity data are very scarce. Butanethiol as a colorless transparent liquid, and has physic-chemical characteristics with flash point as $-23^{\circ}C$ and strong fire risk, boiling point $84-85^{\circ}C$, vapor pressure 80.71 mmHg ($25^{\circ}C$), freezing point $-140.14^{\circ}C$. From whole body exposure with SD rats, the $LC_{50}$ is above 2,500 ppm (9.22mg/L), and then it is classified as the acute toxic chemical (inhalation) category 4 according to the governmental notification No. 2012-14.

• Korean Journal of Environmental Agriculture
• /
• v.38 no.1
• /
• pp.10-16
• /
• 2019

BACKGROUND: Coal ashes generated from thermal power plants have been known as beneficial materials for agricultural use because of their nutrient elements. However, there is limitation to recycle them due to their alkalinity. The objective of this study was to evaluate the effectiveness or safety of the coal ashes for their heavy metals on agricultural recycling when adjusted to pH of 5 with sulfuric acid. METHODS AND RESULTS: Concentration of hydrogen which is needed to adjust pH of coal ash was estimated by using a buffering curve and then the amount of sulfuric acid was changed by the estimation before incubation. Each of fly ash (FA) and bottom ash (BA) was collected from both thermal plants of Yeongdong (YD) and Yeongheung (YH). The pH values of coal ashes increased to 4.76 (from 4.34) after incubation with sulfuric acid for 56 days, closer to the targeted pH. Coal ashes also increased the contents of available phosphorus by 2-fold (165 mg/kg) and 11-fold (1,137 mg/kg) for YDBA and YDFA, respectively, compared to the control. CONCLUSION: The utilization of coal ash with its acidity regulation would be very beneficial to agriculture sector and further suggest promising environmental safety against heavy metals.

• Korean Chemical Engineering Research
• /
• v.60 no.4
• /
• pp.506-511
• /
• 2022

In the Chemicals Control Act, a system was implemented to unify off-site risk assessment and risk management plan into the prevention and management system for chemical accidents. Among the hazardous chemicals which have been covered in system, the accident preparation substances are designated as chemical substances that are likely to occur and of which damage scale are likely to be large in the event of chemical accidents. In this study, risks were compared by selecting accident preparation substances with similar regulated quantities. In addition, risk assessment studies were conducted applying the accident scenarios. Four types of materials such as ammonia, hydrogen chloride, carbon disulfide and benzene were selected for the study, and risks were finally analyzed using Safeti 8.0, a quantitative risk assessment program by DNV. As a result, some materials are identified to have high risks comparing to other substances having similar regulated quantities.

• Nuclear Engineering and Technology
• /
• v.53 no.12
• /
• pp.3990-4002
• /
• 2021

CSPACE (Core meltdown, Safety and Performance Analysis CodE for nuclear power plants) for a simulation of severe accident progression in a Pressurized Water Reactor (PWR) is developed by coupling of verified system thermal hydraulic code of SPACE (Safety and Performance Analysis CodE for nuclear power plants) and core damage progression code of COMPASS (Core Meltdown Progression Accident Simulation Software). SPACE is responsible for the description of fluid state in nuclear system nodes, while COMPASS is responsible for the prediction of thermal and mechanical responses of core fuels and reactor vessel heat structures. New heat transfer models to each phase of the fluid, flow blockage, corium behavior in the lower head are added to COMPASS. Then, an interface module for the data transfer between two codes was developed to enable coupling. An implicit coupling scheme of wall heat transfer was applied to prevent fluid temperature oscillation. To validate the performance of newly developed code CSPACE, we analyzed typical severe accident scenarios for OPR1000 (Optimized Power Reactor 1000), which were initiated from large break loss of coolant accident, small break loss of coolant accident, and station black out accident. The results including thermal hydraulic behavior of RCS, core damage progression, hydrogen generation, corium behavior in the lower head, reactor vessel failure were reasonable and consistent. We demonstrate that CSPACE provides a good platform for the prediction of severe accident progression by detailed review of analysis results and a qualitative comparison with the results of previous MELCOR analysis.

• Restorative Dentistry and Endodontics
• /
• v.34 no.2
• /
• pp.154-161
• /
• 2009

This clinical study evaluated the whitening effect and safety of polymer based-pen type BlancTis Forte (NIBEC) containing 8.3% carbamide peroxide. Twenty volunteers used the BlancTis Forte whitening agent for 2 hours twice a day for 4 weeks. As a control. Whitening Effect Pen (LG) containing 3% hydrogen peroxide was used by 20 volunteers using the same protocol. The change in shade (${\Delta}E^*$, color difference) was measured using $Shadepilot^{TM}$ (DeguDent) before, during, and after bleaching (2 weeks, 4 weeks, and post-bleaching 4 weeks). A clinical examination for any side effects (tooth hypersensitivity or soft tissue complications) was also performed at each check-up. The following results were obtained. 1. Both the experimental and control groups displayed a noticeable change in shade (${\Delta}E$) of over 2. No significant differences were found between the two groups (p > 0.05), implying that the two agents have a similar whitening effect.2. The whitening effect was mainly due to changes in a and b values rather than in L value (brightness). The experimental group showed a significantly higher change in b value, thus yellow shade, than the control (p < 0.05). 3. None of the participants complained of tooth hypersensitivity or soft tissue complications, confirming the safety of both whitening agents.

• Journal of the Korean Institute of Gas
• /
• v.20 no.6
• /
• pp.1-8
• /
• 2016

Gu-mi hydrogen fluoride leak accident in 2012 was amplified social anxiety for chemical accidents. To relieve these anxieties Off-site Risk Assessment was introduced in 2015. Off-site Risk Assessment is targeted at most chemicals, and most of the high-pressure-toxic gases which are mainly used in high-tech industries such as semi conductor, display, Photovoltaic panels industry are included in the substance of the Off-site Risk Assessment. Since Korean companies occupy a high market share in high-tech industries, high pressure-toxic domestic gas consumption is constantly increasing. Accordingly, it is expected to increase the possibility of accidents. In accordance with the circumstances, this study was to conducted Consequence Analysis(CA) about high pressure-toxic gases those are high demand in domestic. CA was used for ALOHA developed by US EPA & US NOAA and the CA result of Arsine was the largest at 4,700 m. CA results are expected to be utilized for determining the effective Safety distances when high pressure-toxic gas leak.

• Journal of the Korean Academy of Esthetic Dentistry
• /
• v.7 no.1
• /
• pp.6-17
• /
• 1998

Tooth bleaching was being done more than 100 years ago, but the standard for vital tooth bleaching for the last quarter century has been the use of hydrogen peroxide with heat or with a combination of heat and light. The major disadvantages of this process are high cost, unpredictability of results, and patient discomfort. In March, 1989, the dental world was introduced to a new vital tooth bleaching process by Haywood and Heymann in their article "Nightguard vital bleaching(NGVB)." Interestingly enough, this simple technique could have been developed years ago if we had known about the chemical effects of carbamide peroxide on tooth structure. NGVB has created a resurgence in the area of bleaching, primarily because of its relative ease of application, the safety of the materials used, low cost, and the high percentage of successful treatments. This article was to explain simply about all around NGVB(etiology of stains, bleaching chemicals and mechanisms, bleaching effectiveness, side effect, documentation, indications, treatment therapy, laboratory procedure, case reports)