• Title/Summary/Keyword: Hydrogen safe

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Characteristics of Bioflocculant Produced by Achromobacter sp. YJ-66. (Achromobacter sp. YJ-66가 생산하는 생물응집제의 성분 특성)

  • 우정숙;정준영;도대홍;조재민
    • Microbiology and Biotechnology Letters
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    • v.28 no.4
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    • pp.233-238
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    • 2000
  • To develop biodegradable and safe flocculant, Achromobacter sp. HY-66 were isolated from soil. The purified flocculant was composed of fructose and glucose in an approximate molar ratio of 1:24. Molecular weight was approximately 9$\times$105 dalton by Sepharose CL-4B gel filtration chromatography. Elemental analysis revealed that the contents of carbon, hydrogen and oxygen were 37.72%, 5.37% and 56.89%, respectively. The presence of O-H stretching, C-H streching, carboxy ester and C-H bending were confirmed by IR absorption spectrum analysis. We suggest that a bioflocculant produced from Achromobacter sp. YJ-66 is new and different from other bioflocculants.

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Effects of Citrus limon Extract on Oxidative Stress-Induced Nitric Oxide Generation and Bovine Teeth Bleaching

  • Jeong, Soon-Jeong
    • Journal of dental hygiene science
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    • v.21 no.2
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    • pp.96-103
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    • 2021
  • Background: We aimed to investigate the effect of Citrous limon extract (CLE) on oxidative stress-induced cytotoxicity and nitric oxide (NO) generation and the tooth bleaching effect of CLE as a substitute for hydrogen peroxide (H2O2) and determine the feasibility and application of CLE as a safe and effective natural tooth bleaching agent. Methods: The protective effect of CLE on H2O2-induced cytotoxicity in Raw264.7 macrophages was investigated by the MTT assay. The inhibitory effect of CLE on the generation of H2O2-induced NO was confirmed by the NO assay, and the changes in inducible nitric oxide synthase (iNOS) protein expression were confirmed by western blotting. Stained bovine teeth were treated with/without 15% and/or 35% CLE and H2O2, 15% sodium bicarbonate (NaHCO3) for 3 hours, and were irradiated with/without bleaching light (BL) for 15 minutes. The color change of the treated bovine tooth surface was measured using a colorimeter. Results: The viability of Raw264.7 cells treated with each concentration of CLE and 500 μM H2O2 significantly increased as CLE increased, and NO generation and iNOS protein expression were significantly reduced in cells treated with 300 ㎍ CLE+/500 μM H2O2+ and 300 ㎍ CLE+/500 μM H2O2+/150 ㎍ NaHCO3+. The bleaching effect of 35% CLE+ was higher than that of 15% CLE+ and 15% NaHCO3+, and the effect was similar to that of 15% H2O2+. The 35% CLE+/15% NaHCO3+ showed the greatest bleaching effect and was higher than that of the groups irradiated with the BL. The greatest bleaching effect was observed with 35% CLE+/15% NaHCO3+, followed by 35% H2O2+/BL+. Conclusion: CLE inhibited oxidative stress-induced cytotoxicity and NO generation in Raw264.7 cells and, could replace H2O2, which causes side effects and risks in teeth breaching treatment. It showed greatest teeth bleaching effect when combined with NaHCO3. CLE is an effective and safe natural tooth bleaching substitute.

Studies on Adsorption and Desorption of Ammonia Using Covalent Organic Framework COF-10 (Covalent Organic Framework (COF-10)를 이용한 암모니아 흡착 및 탈착에 관한 연구)

  • Yang, Heena;Kim, Iktae;Ko, Youngdon;Kim, Shindong;Kim, Whajung
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.265-269
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    • 2016
  • Ammonia gas as a hydrogen source has received great attention since the importance of hydrogen gas as a clean energy source increased. However, ammonia is toxic and corrosive to metal such that the absorbent that can store and transport ammonia became an important issue. As an effort to solve this, a large pored covalent organic framework, COF-10 was proposed as an adsorbent for storage and safe transportation of ammonia. During the ammonia adsorption process, boron in COF-10 structure can act as a Lewis acid site and bind with ammonia. In this study, COF was synthesized and its structure was identified by BET, XRD and FT-IR. The adsorption characteristics of COF were investigated by TPD and adsorption isotherm. The COF-10 showed an excellent adsorption capacity for ammonia (9.79 mmol/g) which could be utilized as an ammonia adsorbent.

A Study on Removal of Organic Matter and Chromaticity from Urine Using Chemical Oxidization Process (화학적 산화공정을 이용하여 소변의 색도 및 유기물 처리를 통한 재이용 기술 연구)

  • Shin, Sung-Hoon;Jung, Jong-Tai;Cho, Yong-Chul
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.109-115
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    • 2018
  • This study was conducted to solve the water shortage problem by reclaiming urine from homes or public places and using it as cleaning water for toilets. The process used in this experiment is a chemical oxidation process combining ozone, hydrogen peroxide, and UV. We set the key substance that is to be removed as chromaticity and conducted the experiment to remove it. If the quantity or concentration of injected ozone, UV, and hydrogen peroxide is insufficient, then the chromaticity will initially increase due to low oxidizing power, and will later decrease. In addition, the efficiency of removing chromaticity appeared to be higher, depending on the quantity of ozone injected, for medium concentrated urine than highly concentrated urine. However, the absolute quantity of removed chromaticity was about 68% higher for highly concentrated urine, when 16 g/hr of ozone was injected. The higher the pH level, the reaction time and efficiency of removing chromaticity were higher, and in normal conditions, in reference to a pH of 8.55, there was a 6% difference in efficiency between a pH level of 5.05 and a pH level of 10.12. Finally, when processing urine through an ozone-only process, COD decreased steadily over time, but DOC did not decrease. This is because ozone reacts selectively with organic matter.

The TANDEM Euratom project: Context, objectives and workplan

  • C. Vaglio-Gaudard;M.T. Dominguez Bautista;M. Frignani;M. Futterer;A. Goicea;E. Hanus;T. Hollands;C. Lombardo;S. Lorenzi;J. Miss;G. Pavel;A. Pucciarelli;M. Ricotti;A. Ruby;C. Schneidesch;S. Sholomitsky;G. Simonini;V. Tulkki;K. Varri;L. Zezula;N. Wessberg
    • Nuclear Engineering and Technology
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    • v.56 no.3
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    • pp.993-1001
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    • 2024
  • The TANDEM project is a European initiative funded under the EURATOM program. The project started on September 2022 and has a duration of 36 months. TANDEM stands for Small Modular ReacTor for a European sAfe aNd Decarbonized Energy Mix. Small Modular Reactors (SMRs) can be hybridized with other energy sources, storage systems and energy conversion applications to provide electricity, heat and hydrogen. Hybrid energy systems have the potential to strongly contribute to the energy decarbonization targeting carbon-neutrality in Europe by 2050. However, the integration of nuclear reactors, particularly SMRs, in hybrid energy systems, is a new R&D topic to be investigated. In this context, the TANDEM project aims to develop assessments and tools to facilitate the safe and efficient integration of SMRs into low-carbon hybrid energy systems. An open-source "TANDEM" model library of hybrid system components will be developed in Modelica language which, by coupling, will extend the capabilities of existing tools implemented in the project. The project proposes to specifically address the safety issues of SMRs related to their integration into hybrid energy systems, involving specific interactions between SMRs and the rest of the hybrid systems; new initiating events may have to be considered in the safety approach. TANDEM will study two hybrid systems covering the main trends of the European energy policy and market evolution at 2035's horizon: a district heating network and power supply in a large urban area, and an energy hub serving energy conversion systems, including hydrogen production; the energy hub is inspired from a harbor-like infrastructure. TANDEM will provide assessments on SMR safety, hybrid system operationality and techno-economics. Societal considerations will also be encased by analyzing European citizen engagement in SMR technology safety.

The Evaluation of the atomic composition and the surface roughness of Titanium Implants following Various Laser treatment with air-powder abrasive (레이저 처리후 임프란트 표면 변화에 관한 연구)

  • Kim, Tae-Jung;Lim, Sung-Bin;Chung, Chin-Hyung
    • Journal of Periodontal and Implant Science
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    • v.32 no.3
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    • pp.615-630
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    • 2002
  • Various long-term studies have shown that titanium implants as abutments for different types of prostheses have become a predictable adjunct in the treatment of partially or fully edentulous patients. The continuous exposure of dental implants to the oral cavity with all its possible contaminants creates a problem. A lack of attachment, together with or caused by bacterial insult, may lead to peri-implantitis and eventual implant failure. Removal of plaque and calculus deposits from dental titanium implants with procedures and instruments originally made for cleaning natural teeth or roots may cause major alterations of the delicate titanium oxide layer. Therefore, the ultimate goal of a cleaning procedure should be to remove the contaminants and restore the elemental composition of the surface oxide without changing the surface topography and harming the surrounding tissues. Among many chemical and mechanical procedure, air-powder abrasive have been known to be most effective for cleaning and detoxification of implant surface. Most of published studies show that the dental laser may be useful in the treatment of pen-implantitis. $CO_2$ laser and Soft Diode laser were reported to kill bacteria of implant surface. The purpose of this study was to obtain clinical guide by application these laser to implant surface by means of Non-contact Surface profilometer and X-ray photoelectron spectroscopy(XPS) with respect to surface roughness and atomic composition. Experimental rough pure titanium cylinder models were fabricated. All of them was air-powder abraded for 1 minute and they were named control group. And then, the $CO_2$ laser treatment under dry, hydrogen peroxide and wet condition or the Soft Diode laser treatment under Toluidine blue O solution condition was performed on the each of the control models. The results were as follows: 1. Mean Surface roughness(Ra) of all experimental group was decreased than that of control group. But it wasn't statistically significant. 2. XPS analysis showed that in the all experimental group, titanium level were decreased, when compared with control group. 3. XPS analysis showed that the level of oxygen in the experimental group 1, 3($CO_2$ laser treatment under dry and wet condition) and 4(Soft Diode laser was used under toluidine blue O solution) were decreased, when compared with control group. 4. XPS analysis showed that the atomic composition of experimental group 2($CO_2$ laser treatment under hydrogen peroxide) was to be closest to that of control group than the other experimental group. From the result of this study, this may be concluded. Following air-powder abrasive treatment, the $CO_2$ laser in safe d-pulse mode and the Soft Diode laser used with photosensitizer would not change rough titanium surface roughness. Especially, $CO_2$ laser treatment under hydrogen peroxide gave the best results from elemental points of view, and can be used safely to treat peri-implantitis.

Biochemical changes and drug residues in ascidian Halocynthia roretzi after formalin-hydrogen peroxide treatment regimen designed against soft tunic syndrome

  • Lee, Ji-Hoon;Kim, Ju-Wan;Shin, Yun-Kyung;Park, Kyung-Il;Park, Kwan Ha
    • Fisheries and Aquatic Sciences
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    • v.20 no.7
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    • pp.12.1-12.7
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    • 2017
  • Soft tunic syndrome (STS) is a protozoal disease caused by Azumiobodo hoyamushi in the edible ascidian Halocynthia roretzi. Previous studies have proven that combined formalin-hydrogen peroxide ($H_2O_2$) bath is effective in reducing STS progress and mortality. To secure target animal safety for field applications, toxicity of the treatment needs to be evaluated. Healthy ascidians were bathed for 1 week, 1 h a day at various bathing concentrations. Bathing with 5- and 10-fold optimum concentration caused 100% mortality of ascidians, whereas mortality by 0.5- to 2.0-fold solutions was not different from that of control. Of the oxidative damage parameters, MDA levels did not change after 0.5- and 1.0-fold bathing. However, free radical scavenging ability and reducing power were significantly decreased even with the lower-than-optimal 0.5-fold concentration. Glycogen content tended to increase with 1-fold bathing without statistical significance. All changes induced by the 2-fold bathing were completely or partially restored to control levels 48 h post-bathing. Free amino acid analysis revealed a concentration-dependent decline in aspartic acid and cysteine levels. In contrast, alanine and valine levels increased after the 2-fold bath treatment. These data indicate that the currently established effective disinfectant regimen against the parasitic pathogen is generally safe, and the biochemical changes observed are transient, lasting approximately 48 h at most. Low levels of formalin and $H_2O_2$ were detectable 1 h post-bathing; however, the compounds were completely undetectable after 48 h of bathing. Formalin-$H_2O_2$ bathing is effective against STS; however, reasonable care is required in the treatment to avoid unwanted toxicity. Drug residues do not present a concern for consumer safety.

Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

  • Cho, Hyunjin;Lee, Changhyup;Oh, In Seoup;Park, Sungchan;Kim, Hwan Chul;Kim, Myung Jong
    • Carbon letters
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    • v.13 no.4
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    • pp.205-211
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    • 2012
  • Methanol as a carbon source in chemical vapor deposition (CVD) graphene has an advantage over methane and hydrogen in that we can avoid optimizing an etching reagent condition. Since methanol itself can easily decompose into hydrocarbon and water (an etching reagent) at high temperatures [1], the pressure and the temperature of methanol are the only parameters we have to handle. In this study, synthetic conditions for highly crystalline and large area graphene have been optimized by adjusting pressure and temperature; the effect of each parameter was analyzed systematically by Raman, scanning electron microscope, transmission electron microscope, atomic force microscope, four-point-probe measurement, and UV-Vis. Defect density of graphene, represented by D/G ratio in Raman, decreased with increasing temperature and decreasing pressure; it negatively affected electrical conductivity. From our process and various analyses, methanol CVD growth for graphene has been found to be a safe, cheap, easy, and simple method to produce high quality, large area, and continuous graphene films.

Development Status of Accident-tolerant Fuel for Light Water Reactors in Korea

  • Kim, Hyun-Gil;Yang, Jae-Ho;Kim, Weon-Ju;Koo, Yang-Hyun
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.1-15
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    • 2016
  • For a long time, a top priority in the nuclear industry was the safe, reliable, and economic operation of light water reactors. However, the development of accident-tolerant fuel (ATF) became a hot topic in the nuclear research field after the March 2011 events at Fukushima, Japan. In Korea, innovative concepts of ATF have been developing to increase fuel safety and reliability during normal operations, operational transients, and also accident events. The microcell $UO_2$ and high-density composite pellet concepts are being developed as ATF pellets. A microcell $UO_2$ pellet is envisaged to have the enhanced retention capabilities of highly radioactive and corrosive fission products. High-density pellets are expected to be used in combination with the particular ATF cladding concepts. Two concepts-surface-modified Zr-based alloy and SiC composite material-are being developed as ATF cladding, as these innovative concepts can effectively suppress hydrogen explosions and the release of radionuclides into the environment.

Microbial Reduction of Fresh Vegetables by Treatment of Sanitizing Reagents (살균제의 처리에 의한 신선엽채류의 미생물 감소)

  • Park Heon-Kuk;Kim Sang-Bum
    • The Korean Journal of Food And Nutrition
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    • v.17 no.4
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    • pp.436-441
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    • 2004
  • As the production of agricultural products showing high quality and environmental safety is required increasingly these days, it is really necessary to study on technology for producing agricultural products which are safe microbiologically. Among several sanitizing reagents contacted easily, we investigated the most effective and useful method for reducing microorganisms by sanitizer treatment. From this study, it was showed that treatment of 3% hydrogen peroxide solution over 1 minute, which decreased microbiological level less than one tenth of natural state(no sanitizer treatment) in all microorganisms tested, was the most effective sanitizing method to green vegetables, especially raw lettuce used in this study, for reducing microorganisms. By utilizing this sanitizing method in farming step, the improvement of safety and added value of agricultural products, especially raw green vegetables, is expected.