• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.1
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• pp.65-73
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• 2012

Nowadays, the concern on the environmental load of bleaching process gave rise to the process of ECF(elemental chlorine free) and TCF(total clorine free). These sequences are based on oxygen-derived compounds such as oxygen, ozone, and hydrogen peroxide which is used as a typical eco-friendly bleaching agent. In this study, paper mulberry pulp was bleached with hydrogen peroxide and some bleaching process were accompanied with ultrasonication in order to increase the bleaching efficiency. The best bleaching efficiency of paper mulberry pulp was obtained in the condition of hydrogen peroxide and ultrasonication(20 kHz) bleaching system at $45^{\circ}C$ for 30 min. The brightness and kappa number of paper mulberry pulp were gained to 5.09% and 3.52 respectively. and yield was slightly loosed to 2%. Therefore, the efficiency of hydrogen peroxide and ultrasonication bleaching system of paper mulberry pulp was superior to the conventional hydrogen peroxide bleaching system. Magnesium sulfate acted as a bleaching stabilizer for the increasement of yield. As a result, the yield and viscosity were increased to 2.2% and 12% respectively.

• Corrosion Science and Technology
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• v.23 no.2
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• pp.145-153
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• 2024

In the automotive industry, the hole expanding test is widely used to assess the formability of punched holes in sheets. This test provides a good representation of formability within the framework defined by the ISO 16630 standard. During hole expanding tests on galvanized high strength steels, a negative effect was observed when there was a delay between hole punching and expansion, as compared to performing both operations directly. This effect is believed to be caused by hydrogen aging, which occurs when hydrogen diffuses towards highly-work hardened edges. Therefore, the aim of this study is to demonstrate the migration of hydrogen towards work-hardened edges in high strength Zn-coated steel sheets using a novel Thermal Desorption Analyzer (TDA) designed for small samples. This newly-developed TDA setup allows for the quantification of local diffusible hydrogen near cut edges. With its induction heating and ability to analyze Zn-coated samples while reducing artifacts, this setup offers flexible heat cycles. Through this method, a hydrogen gradient is observed over short distances in shear-cut galvanized steel sheets after a certain period of time following punching.

• Journal of the Korean Society of Industry Convergence
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• v.27 no.1
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• pp.39-46
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• 2024

As the development of hydrogen vehicles has accelerated in recent years, it is necessary to develop a storage tank for hydrogen fueling stations capable of high-pressure charging, and for this purpose, a new system with a compressor-embedded refueling tank is required. In this study, the parametric study of shape design based on strength performance evaluation was carried out to find the optimal shape design of bellows, the core component of compressor-embedded refueling tank for a newly developed hydrogen refueling station capable of high-pressure charging above 1,000 bar. The design factors for parametric study were contour shape and radius of bellows, and the performance factors were the maximum stress and the gap distance in the contact direction. In the shape design of the compressor bellows for hydrogen refueling station considered in this study, it was found that adjusting the contour radius is an appropriate design method to improve the compression performance and structural safety.

• Journal of the Korean Society of Industry Convergence
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• v.26 no.4_2
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• pp.705-713
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• 2023

The phenomenon of abnormal climate conditions resulting from greenhouse gas-induced global warming is increasingly prevalent. To address this challenge, global initiatives are underway to adopt environmentally friendly, zero-emission fuels. In this study, we investigate the hydrogen embrittlement characteristics of materials used for eco-friendly hydrogen storage systems. The effects of hydrogen embrittlement on austenitic stainless steels of the FCC series and structural steel of the BCC series were examined. Initially, test samples of three different steel types were prepared in 2t and 3t sizes, and hydrogen was injected into the specimens using an electrochemical method over a 24-hour period. Subsequently, a universal material testing machine (UTM) was employed to monitor changes in mechanical strength and elongation. The FCC series stainless steels exhibited a tendency for elongation to decrease, indicating low sensitivity to hydrogen. In contrast, the mechanical strength and elongation of the BCC series steel changed significantly upon hydrogen charging, posing challenges for prediction. The results of the present study are expected to serve as a fundamental database for analyzing the impact of hydrogen embrittlement on both FCC and BCC series steel materials.

• Journal of the Korean Society of Industry Convergence
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• v.26 no.5
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• pp.875-884
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• 2023

Hydrogen infiltration into metals has been reported to induce alterations in their mechanical properties under load. In this study, we conducted CTOD (Crack Tip Opening Displacement) tests on steel specimens designed for use in liquid hydrogen storage systems. Electrochemical hydrogen charging was performed using both FCC series austenitic stainless steel and BCC series structural steel specimens, while CTOD testing was carried out using a 500kN-class material testing machine. Results indicate a notable divergence in behavior: SS400 test samples exhibited a higher susceptibility to failure compared to austenitic stainless steel counterparts, whereas SUS 316L test samples displayed minimal changes in displacement and maximum load due to hydrogen charging. However, SEM (Scanning Electron Microscopy) analysis results presented challenges in clearly explaining the mechanical degradation phenomenon in the tested materials. This study's resultant database holds significant promise for enhancing the safety design of liquid hydrogen storage systems, providing invaluable insights into the performance of various steel alloys under the influence of hydrogen embrittlement.

• Journal of Hydrogen and New Energy
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• v.17 no.1
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• pp.90-97
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• 2006

Hydrogen is used as a chemical feedstock in several important industrial processes, including oil refineries and petro-chemical production. But, nowadays hydrogen is focused as energy carrier on the rising of problems such as exhaustion of fossil fuel and environmental pollution. Thermochemical hydrogen production by nuclear energy has potential to efficiently produce large quantities of hydrogen without producing greenhouse gases, and research of nuclear hydrogen, therefore, has been worked with goal to demonstrate commercial production in 2020. The oil refineries and petro-chemical plant are very large, centralized producers and users of industrial hydrogen, and high-potential early market for hydrogen produced by nuclear energy. Therefore, it is essential to investigate and analyze for state of domestic hydrogen market focused on industrial users. Hydrogen market of petro-chemical industry as demand site was investigated and worked for demand forecast of hydrogen in 2020. Also we suggested possible supply plans of nuclear hydrogen considered regional characteristics and then it can be provided basis for determination of optimal capacity of nuclear hydrogen plant in 2020.

• Journal of the Korean institute of surface engineering
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• v.46 no.3
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• pp.120-125
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• 2013

This investigation was to identify the electrochemical corrosion protection conditions to minimize the cavitation damage by generating hydrogen gas with the means of hydrogen overvoltage before the impact pressure of the cavity is transferred to the surface. The hybrid potentiostatic test method is designed to evaluate a complexed cavitation and electrochemical characteristic for ALBC3 alloy that is diverse and its broad applications fields in marine industry. The surface observation showed that neither the cavitation damage nor the electrochemical damage by the hydrogen gas generation occurred in the potential of -2.6 V under the cavitation environment. In the potentiostatic experiments under the cavitation environment, the cavities were reflected or cancelled out by the collision of the cavities with the hydrogen gas generated by the hydrogen overvoltage.

• Journal of Hydrogen and New Energy
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• v.25 no.3
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• pp.264-270
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• 2014

Fuel cell technology is the most representative area of alternative energy field on vehicle industry according to the limitation of petroleum resources. In recent years, the technology of fuel cell vehicles has made rapid progress, Hyundai Motor Company (HMC) reached to mass production of the Tucson ix hydrogen fuel cell vehicles first in the world. In addition, HMC is accelerating the development of hydrogen fuel cell buses, which have a number of advantages for hydrogen infrastructure and mass transport personnel. In this study, we examined potential of the commercialization through the demonstration of hydrogen fuel cell buses. As a result, we identified that the mass-production possibility of FCB has high potential and HMC's technology will lead to fuel cell bus industry.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.45 no.1
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• pp.6-12
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• 2013

TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 1999.04b
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• pp.375-380
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• 1999

In order to improve the optical properties of high yield pulp, bleached chemi-thermo-mechanical pulp (BCTMP) was produced from CTMP of Betula maximowicziana Regel by two staged ozone-hydrogen peroxide bleaching. This pulp was used for the evaluation of the improvement of optical properties, chemical characteristics of lignin in fiber, and the relationship between lignin and optical properties in fiber cell wall. By hydrogen peroxide treatment, the brightness was improved, but the post color number (PC No.) was not. There was little improvement on optical properties by ozone treatment, but his could be solved by using two staged ozone-hydrogen peroxide bleaching. The hydrogen peroxide treatment did not make nay change on chemical characteristics of lignin in cell wall, but by ozone treatment, it was found that the non-aromatic conjugated structure was existed in the surface of cell wall, but this could be removed by hydrogen peroxide treatment in two staged ozone-hydrogen peroxide treatment. Therefore, the optical properties was significantly improved due to the removal of non-aromatic conjugated structure.