• Clean Technology
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• v.28 no.3
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• pp.218-226
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• 2022

As a result of the recent social transformation towards a hydrogen economy and carbon-neutrality, the demands for hydrogen energy have been increasing rapidly worldwide. As such, eco-friendly hydrogen production technologies that do not produce carbon dioxide (CO₂) emissions are being focused on. Among them, ammonia (NH₃) is an economical hydrogen carrier that can easily produce hydrogen (H₂). In this study, Ru/Al₂O₃ catalyst coated onmetallic monolith for hydrogen production from ammonia was prepared by a dip-coating method using a catalyst slurry mixture composed of Ru/Al₂O₃ catalyst, inorganic binder (alumina sol) and organic binder (methyl cellulose). At the optimized 1:1:0.1 weight ratio of catalyst/inorganic binder/organic binder, the amount of catalyst coated on the metallic monolith after one cycle coating was about 61.6 g L^-1. The uniform thickness (about 42 ㎛) and crystal structure of the catalyst coated on the metallic monolith surface were confirmed through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Also, a numerical optimization regression equation for NH3 conversion according to the independent variables of reaction temperature (400-600 ℃) and gas hourly space velocity (1,000-5,000 h^-1) was calculated by response surface methodology (RSM). This model indicated a determination coefficient (R²) of 0.991 and had statistically significant predictors. This regression model could contribute to the commercial process design of hydrogen production by ammonia decomposition.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.1
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• pp.22-30
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• 2009

Energy environment has been changing rapidly such as the fluctuation of oil prices and the effect on UNFCCC. Oil price change affects Korea's economy heavily due to her poor natural resources and large dependence of consumed energy resources. Korea takes the 4th place of importing the crude oil and 9th place in $CO_2$ emissions with the 1st place of $CO_2$ emissions increasing rate. Considering the current statue of Korea including oil price change and UNFCCC, Korea will be expected to be the Annex I nation due to Korean energy environments and the quantity of $CO_2$ emission. Energy technology development is a crucial key to cope with Korea's national energy security and environments. In this study, we establish the framework, which allocates the relative weights of assessment criteria and sub-criteria, for assessing and selecting R&D programs of energy technologies strategically. We integrated fuzzy theory and analytic hierarchy process (AHP) approach since the fuzzy AHP approach reflects the vagueness of human thoughts and perception effectively as making pairwise comparisons of criteria and alternatives. The fundamental data of this research results will support R&D planning phase for policy-makers and the production of well focused R&D outcomes.

• Journal of the Korean Institute of Gas
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• v.21 no.2
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• pp.20-25
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• 2017

For the HCNG bus using fuel which is the mixture gas of hydrogen and natural gas, the fuel efficiency and $CO_2$ emission characteristics were analyzed based on the WHVC test results and compared with that of the CNG and diesel buses. $CO_2$ emission characteristics were also analyzed by contribution effects such as carbon emission factor and fuel consumption. As a result, the fuel economy of HCNG bus was evaluated to be 11.5% improvement compared to CNG bus, and it was also showed equivalent to diesel bus. In addition, the $CO_2$ emission of HCNG bus was reduced 20.4% and 34.5% compared to CNG bus and diesel bus respectively. It was concluded that the $CO_2$ emission characteristics were influenced by the carbon emission factor depending on fuel composition and the fuel consumption according to the engine performance.

• Journal of the Korean Institute of Gas
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• v.25 no.5
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• pp.19-29
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• 2021

Due to the climate changing, the world's countries are tightening regulations on CO2 and air pollutants emission to solve them. In addition, eco friendly vehicles is increasing to replace automobiles in internal combustion engine. Recently, the government is supporting the expansion of hydrogen refueling infrastructure and localization of core equipment in refueling facilities according to the hydrogen economy road map. In this study, design of the Excess flow limiting device in FCEV cylinder valve using by finite element analysis and performed performance tests on prototype. Major test results as hydrostatic strength, continued operation, operation, pressure impulse, leakage showed that the excess flow limiting device meets the performance requirements according to ISO 12619-2 and ISO 12619-11.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.125-132
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• 2011

A unitized regenerative fuel cell (URFC) as a next-generation fuel cell technology was considered in the study. URFC is a mandatory technology for the completion of the hybrid system with the fuel cell and the renewable energy sources, and it can be expected as a new technology for the realization of hydrogen economy society in the $21^{st}$ century. Specifically, the recent research data and results concerning the polymer electrolyte membrane for the URFC technology were summarized in the study. The prime requirements of polymer electrolyte membrane for the URFC applications are high proton conductivity, dimensional stability, mechanical strength, and interfacial stability with the electrode binder. Based on the performance of the polymer electrolyte membrane, the URFC technology combining the systems for the production, storage, utilization of hydrogen can be a new research area in the development of an advanced technology concerning with renewable energy such as fuel cell, solar cell, and wind power.

• Journal of Power Electronics
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• v.5 no.4
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• pp.305-311
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• 2005

Throughout the world, studies on the water energization are currently under way. Of those, Brown gas, which is generated through the electrolyzation of water and is a mixed gas of the constant volume of 2 parts hydrogen to 1 part oxygen, has better characteristics in terms of economy, energy efficiency, and environmental affinity than those of acetylene gas and LPG (Liquefied Petroleum Gas) used for existing welding machines. This paper analyzes the characteristics of Brown gas and presents methods for increasing the generating efficiency of Brown gas by designing a power supply to deliver power to a water-electrolytic cell and designing a cylindrical electrode to improve the efficiency of the electrolyzer needed for water electrolyzation. Based on the above the methods, a welding machine using Brown gas is developed. And the generation efficiency of Brown gas is measured tinder different conditions (duty ratio, frequency and amplitude) of supplied power.

• Korean Journal of Materials Research
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• v.32 no.5
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• pp.237-242
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• 2022

Designing and producing a low-cost, high-current-density electrode with good electrocatalytic activity for the oxygen evolution reaction (OER) is still a major challenge for the industrial hydrogen energy economy. In this study, nanostructured Fe-doped CuCo(OH)₂ was discovered to be a precedent electrocatalyst for OER with low overpotential, low Tafel slope, good durability, and high electrochemically active surface sites at reduced mass loadings. Fe-doped CuCo(OH)₂ nanosheets are made using a hydrothermal synthesis process. These nanosheets are clumped together to form a highly open hierarchical structure. When used as an electrocatalyst, the Fe-doped CuCo(OH)₂ nanosheets required an overpotential of 260 mV to reach a current density of 50 mA cm^-2. Also, it showed a small Tafel slope of 72.9 mV dec^-1, and superior stability while catalyzing the generation of O₂ continuously for 20 hours. The Fe-doped CuCo(OH)₂ was found to have a large number of active sites which provide hierarchical and stable transfer routes for both electrolyte ions and electrons, resulting in exceptional OER performance.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.41-51
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• 2023

As abnormal climatic event occur frequently due to global warming, many nations have proclaimed their commitment to achieving carbon neutrality and are actively pursuing a transition toward a hydrogen economy. At this time, ammonia has garnered significant attention not only as a high-capacity hydrogen carrier but also as a promising candidate as a carbon-free fuel. In particular, anion exchange membrane fuel cells offer the advantage of directly supplying ammonia to the fuel cell, eliminating the necessity for separate ammonia decomposition or hydrogen purification. Therefore, in this study, the operation principle and research trend of the anion exchange membrane fuel cell are reviewed, and several research using ammonia as a fuel in anion exchange membrane fuel cell are also investigated.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.417-417
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• 2016

Global environmental deterioration has become more serious year by year and thus scientific interests in the renewable energy as environmental technology and replacement of fossil fuels have grown exponentially. Photoelectrochemical (PEC) cell consisting of semiconductor photoelectrodes that can harvest light and use this energy directly to split water, also known as photoelectrolysis or solar water splitting, is a promising renewable energy technology to produce hydrogen for uses in the future hydrogen economy. A major advantage of PEC systems is that they involve relatively simple processes steps as compared to many other H2 production systems. Until now, a number of materials including TiO2, WO3, Fe2O3, and BiVO4 were exploited as the photoelectrode. However, the PEC performance of these single absorber materials is limited due to their large charge recombinations in bulk, interface and surface, leading low charge separation/transport efficiencies. Recently, coupling of two materials, e.g., BiVO4/WO3, Fe2O3/WO3 and CuWO4/WO3, to form a type II heterojunction has been demonstrated to be a viable means to improve the PEC performance by enhancing the charge separation and transport efficiencies. In this study, we have prepared a triple-layer heterojunction BiVO4/WO3/SnO2 photoelectrode that shows a comparable PEC performance with previously reported best-performing nanostructured BiVO4/WO3 heterojunction photoelectrode via a facile solution method. Interestingly, we found that the incorporation of SnO2 nanoparticles layer in between WO3 and FTO largely promotes electron transport and thus minimizes interfacial recombination. The impact of the SnO2 interfacial layer was investigated in detail by TEM, hall measurement and electrochemical impedance spectroscopy (EIS) techniques. In addition, our planar-structured triple-layer photoelectrode shows a relatively high transmittance due to its low thickness (~300 nm), which benefits to couple with a solar cell to form a tandem PEC device. The overall PEC performance, especially the photocurrent onset potential (Vonset), were further improved by a reactive-ion etching (RIE) surface etching and electrocatalyst (CoOx) deposition.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.22 no.5
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• pp.29-35
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• 2022

This paper proposes a fuel cell education framework installed on a Metaverse environment, which is to reduce the burden of education costs and improve the effect of education or learning. This Meta-Fuel cell platform utilizes the Unity 3D Web and enables not only theoretical education but also hands-on training. The platform was designed and developed to accommodate a variety of unit education contents, such as ppt documents, videos, etc. The platform, therdore, integrates ppt and video demonstrations for theoretical education, as well as software content "STACK-Up" for hands-on training. Theoretical education section provides specialized liberal arts knowledge on hydrogen, including renewable energy, hydrogen economy, and fuel cells. The software "STACK-Up" provides a hands-on practice on assembling the stack parts. Stack is the very core component of fuel cells. The Meta-Fuelcell platform improves the limitations of face-to-face education. It provides educators with the opportunities of non-face-to-face education without restrictions such as educational place, time, and occupancy. On the other hand, learners can choose educational themes, order, etc. It provides educators and learners with interesting experiences to be active in the metaverse space. This platform is being applied experimentally to a education project which is to develop advanced manpower in the fuel cell industry. Its improvement is in progress.