• Title/Summary/Keyword: Hydrogen distribution

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Ultraviolet Microscopic Study on Lignin Distribution in the Fiber Cell Wall of BCTMP

  • Yoon, Seung-Lak;Yasuo Kojina
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.61-66
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    • 2004
  • Bleached chemithermomechanical pulp (BCTMP) was produced from CTMP of Betula maximowicziana Regel by two staged ozone-hydrogen peroxide bleaching in order to improve the optical properties of high yield pulp. This pulp was used for the evaluation of optical properties improvement, chemical characteristics of lignin in fiber and the relationship between lignin and optical properties in fiber cell wall. Hydrogen peroxide treatment improved the brightness, but the post color number (PC No.). There was little improvement on optical properties by ozone treatment, but this could be improved more by using two staged ozone-hydrogen peroxide bleaching. The hydrogen peroxide treatment did not make any change on chemical characteristics of lignin in cell wall, but by ozone treatment, it was found that the non-aromatic conjugated structure was existed in the surface of cell wall, but this could be removed by hydrogen peroxide treatment in two staged ozone-hydrogen peroxide treatment. Therefore, the optical properties was significantly improved, due to the removal of non-aromatic conjugated structure.

수소에너지 정부 정책 동향 및 R&D 역할

  • Seo, Jae-Yeong;Kim, Ji-Hyeon
    • Bulletin of the Korea Photovoltaic Society
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    • v.3 no.2
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    • pp.63-69
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    • 2017
  • New and renewable energy has attracted a significant attention since the Paris Agreement in 2015. Especially hydrogen energy is important for reducing greenhouse gas produced during transportation. The new government suggested that the eco-friendly vehicles, hydrogen infrastructure and the development of new and renewable energy are the major growth engines in the future. Hydrogen energy is also concerned as the main part of our economy in the national affairs. In the policy of Mission Innovation Strategy and the third Eco-Friendly Vehicle Master Plan, government presents the status, future direction, technical road map and distribution road map of hydrogen energy. With this trend, investments in the research and development on hydrogen and fuel cells have expanded and will continue to expand for the implementation of the policy. The cost reduction, technical innovation and the increase in the localization rate are required for the new and renewable energy, including hydrogen energy, to become the future growth engine.

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The design and fabricationt for ion fraction measurement of plasma generator (플라즈마발생기의 이온분율 측정 장치 설계 및 제작)

  • Lee, Chan-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.368-368
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    • 2008
  • Ion implantation has been widely developed during the past decades to become a standard industrial tool. To comply with the growing needs in ion implantation, innovative technology for the control of ion beam parameters is required. Beam current, beam profile, ion fractions are of great interest when uniformity of the implant is an issue. Especially, it is important to measure the spatial distribution of beam power and also the energy distribution of accelerated ions. This energy distribution is influenced by the proportion of mass for ion in the plasma generator(ion source) and by charge exchange and dissociation within the accelerator structure and also by possible collective effects in the neutralizer which may affect the energy and divergence of ions. Hydrogen atom has been the object of a good study to investigate the energy distribution. Hydrogen ion sources typically produce multi-momentum beams consisting of atomic ion ($H^+$) and molecular ion ($H_2^+$ and $H_3^+$). In the beam injector, the molecular ions pass through a charge-exchanges gas cell and break up into atomic with one-half (from $H_2^+$) or one-third (from $H_3^+$) according to their accelerated energy. Burrell et al. have observed the Doppler shifted lines from incident $H^+$, $H_2^+$, and $H_3^+$ using a Doppler shift spectroscopy. Several authors have measured the proportion of mass for hydrogen ion and deuterium using an ion source equipped with a magnetic dipole filter. We developed an ion implanter with 50-KeV and 20-mA ion source and 100-keV accelerator tube, aiming at commercial uses. In order to measure the proportion of mass for ions, we designed a filter system which can be used to measure the ion fraction in any type of ion source. The hydrogen and helium ion species compositions are used a filter system with the two magnets configurations.

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Preliminary numerical study on hydrogen distribution characteristics in the process that flow regime transits from jet to buoyancy plume in time and space

  • Wang, Di;Tong, Lili;Liu, Luguo;Cao, Xuewu;Zou, Zhiqiang;Wu, Lingjun;Jiang, Xiaowei
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1514-1524
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    • 2019
  • Hydrogen-steam gas mixture may be injected into containment with flow regime varying both spatially and transiently due to wall effect and pressure difference between primary loop and containment in severe accidents induced by loss of coolant accident. Preliminary CFD analysis is conducted to gain information about the helium flow regime transition process from jet to buoyancy plume for forthcoming experimental study. Physical models of impinging jet and wall condensation are validated using separated effect experimental data, firstly. Then helium transportation is analyzed with the effect of jet momentum, buoyancy and wall cooling discussed. Result shows that helium distribution is totally dominated by impinging jet in the beginning, high concentration appears near gas source and wall where jet momentum is strong. With the jet weakening, stable light gas layer without recirculating eddy is established by buoyancy. Transient reversed helium distribution appears due to natural convection resulted from wall cooling, which delays the stratification. It is necessary to concern about hydrogen accumulation in lower space under the containment external cooling strategy. From the perspective of experiment design, measurement point should be set at the height of connecting pipe and near the wall for stratification stability criterion and impinging jet modelling validation.

A Study On the Retention Time Distribution with Plasma Damage Effect

  • Yi Jae Young;Szirmay Laszlo;Yi Cheon Hee
    • Proceedings of the IEEK Conference
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    • 2004.08c
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    • pp.460-462
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    • 2004
  • The control of the data retention time is a main issue for realizing future high density dynamic random access memory. There are several leakage current mechanisms in which the stored data disappears. The mechanisms of data disappear is as follow, 1 )Junction leakage current between the junction, 2) Junction leakage current from the capacitor node contact, 3)Sub-threshold leakage current if the transfer transistor is affected by gate etch damage etc. In this paper we showed the plasma edge damage effect to find out data retention time effectiveness. First we measured the transistor characteristics of forward and reverse bias. And junction leakage characteristics are measured with/without plasma damage by HP4145. Finally, we showed the comparison TRET with etch damage, damage_cure_RTP and hydrogen_treatment. As a result, hydrogen_treatment is superior than any other method in a curing plasma etch damage side.

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CURRENT RESEARCH AND DEVELOPMENT ACTIVITIES ON FISSION PRODUCTS AND HYDROGEN RISK AFTER THE ACCIDENT AT FUKUSHIMA DAIICHI NUCLEAR POWER STATION

  • NISHIMURA, TAKESHI;HOSHI, HARUTAKA;HOTTA, AKITOSHI
    • Nuclear Engineering and Technology
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    • v.47 no.1
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    • pp.1-10
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    • 2015
  • After the Fukushima Daiichi nuclear power plant (NPP) accident, new regulatory requirements were enforced in July 2013 and a backfit was required for all existing nuclear power plants. It is required to take measures to prevent severe accidents and mitigate their radiological consequences. The Regulatory Standard and Research Department, Secretariat of Nuclear Regulation Authority (S/NRA/R) has been conducting numerical studies and experimental studies on relevant severe accident phenomena and countermeasures. This article highlights fission product (FP) release and hydrogen risk as two major areas. Relevant activities in the S/NRA/R are briefly introduced, as follows: 1. For FP release: Identifying the source terms and leak mechanisms is a key issue from the viewpoint of understanding the progression of accident phenomena and planning effective countermeasures that take into account vulnerabilities of containment under severe accident conditions. To resolve these issues, the activities focus on wet well venting, pool scrubbing, iodine chemistry (in-vessel and ex-vessel), containment failure mode, and treatment of radioactive liquid effluent. 2. For hydrogen risk: because of three incidents of hydrogen explosion in reactor buildings, a comprehensive reinforcement of the hydrogen risk management has been a high priority topic. Therefore, the activities in evaluation methods focus on hydrogen generation, hydrogen distribution, and hydrogen combustion.

Development of On-axis Raman Lidar System for Remotely Measuring Hydrogen Gas at Long Distance (원거리 수소 가스 원격 계측을 위한 On-axis 라만 라이다 장치 개발)

  • Choi, In Young;Baik, Sung Hoon;Lim, Jae Young;Cha, Jung Ho;Kim, Jin Ho
    • Korean Journal of Optics and Photonics
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    • v.29 no.3
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    • pp.119-125
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    • 2018
  • Hydrogen gas is an important and promising energy resource that has no emissions of pollutants during power generation. However, hydrogen gas is very dangerous because it is colorless, odorless, highly flammable, and explosive at low concentration. Conventional techniques for hydrogen gas detection are very difficult for measuring the hydrogen gas distribution at long distances, because they sample the gas to measure its concentration. Raman lidar is one of the techniques for remotely detecting hydrogen gas and measuring the range of the hydrogen gas distribution. A Raman lidar system with an on-axis optical receiver was developed to improve the range of hydrogen gas detection at long distance. To verify the accuracy and improvement in the range of detecting the hydrogen gas, experiments measuring the hydrogen gas concentration are carried out using the developed on-axis Raman lidar system and a gas chamber, to prevent explosion of the hydrogen gas. As a result, our developed on-axis Raman lidar system can measure a minimum hydrogen gas concentration of 0.66 volume percent at a distance of 50 m.

Investment Benefit Analysis of Safety Assessment and Inspection Technologies of Hydrogen Bus Fuel System Using Contingent Valuation Methods (조건부가치측정법을 이용한 수소버스 연료장치 안전성 평가 및 검사기술에 대한 투자 편익 분석)

  • Seohyun, Lim;Jeong Ah, Jang
    • Journal of Auto-vehicle Safety Association
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    • v.14 no.4
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    • pp.43-52
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    • 2022
  • Recently, the government has been expanding the supply of hydrogen vehicles according to the roadmap for vitalizing the hydrogen economy, but is developing safety assessment and inspection technology for the relevant vehicles. This study analyzed the prevention of hydrogen bus accidents' economic effect that arises from the application and development of large-capacity CHSS oil pressure repetition-test assessment technology, hydrogen bus internal chamber pressure transmission and emission volume inspection technology, among various technologies capable of assessing the safety of a hydrogen bus fuel system. To this end, the contingent valuation method (CVM), one of the value evaluation methods of non-market goods, was applied to investigate users' willingness to pay for each inspection technology. The survey for users' willingness to pay was conducted by attaching posters to promote surveys on the internet and within buses to the entire public. As a result of the analysis, the average WTP of the hydrogen bus internal chamber pressure transmission volume inspection technology was 25.3 KRW, the average WTP of the hydrogen bus internal chamber pressure emission volume inspection technology was 18.6 KRW, and the average WTP of the large-capacity CHSS oil pressure repetition-test assessment technology was measured at 16.7 KRW. In addition, the costs and benefits of the introduction of the relevant inspection technology were defined through the interviewing of experts at related research institutions and businesses. As a result of conducting an economic analysis (4.5% discount rate) according to the development of each inspection technology, economic feasibility was seen in all assessment and inspection technologies. As much as the technology is indispensable for the safe use of hydrogen buses, it shows that investment in related technology is very necessary in the future. However, because it was decided that the relevant analysis will differ according to the distribution rate of hydrogen buses, further analysis following this future distribution rate of hydrogen buses is needed, and future users should be made clearly aware of the safety and environmental nature of the technology.

Computational Fluid Dynamics Analysis of Plate Type Reformer for MCFC (용융탄산염 연료전지용 평판형 개질기 열유동 전산유체역학 해석)

  • Shin, Dong-Hoon;Seo, Hye-Gyung;Lim, Hee-Chun;Lee, Sang-Duk
    • Journal of Hydrogen and New Energy
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    • v.17 no.4
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    • pp.403-408
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    • 2006
  • The plate reformer consisting of combustion chamber and reforming chamber for 25 kW MCFC stack has been operated and computational fluid dynamics was applied to estimate reactions and thermal fluid behavior in the reformer. The methane air 2-stage reaction was assumed in the combustion chamber, and three step steam reforming reactions were included in the calculation. Flow uniformity, reaction rate and species distribution, and temperature distribution were analyzed. In particular, temperature distribution was compared with the measurements to show good agreement in the combustion chamber, however, inappropriate agreement in the reformer chamber.

Humidity Distribution and Performance Variation of a PEMFC Multi Stack System According to the Direction of Anodic Supply (고분자 전해질 연료전지 멀티 스택 시스템의 수소극 흐름방향에 따른 습도분포 및 성능변화)

  • Lee, Yongtaek
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.30 no.3
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    • pp.143-148
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    • 2018
  • In this study the performance and humidity variation for 2 unit cells connected in series were experimentally measured. The relative flow direction of hydrogen and air was changed from parallel flow to counter flow. Internal humidity distribution was then measured by 5 embedded sensors on each channel. In all experimental conditions, the former unit cell showed a better performance and the gap is noted to be higher when counter flow is applied. The performance was noted to be higher at high humidification case in the parallel flow. However, in the counter flow, the difference of performance according to the humidification is negligible. Hydrogen and air are discharged from the PEMFC unsaturated with water vapor at parallel flow/low humidification condition, which explains lower performance of the PEMFC than other conditions. The humidities in hydrogen and air streams of counter flow were noted to increase rapidly even at low humidification condition and the consequential even hydration of membrane is the reason of higher performance.