• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2011년 춘계학술대회논문집
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• pp.477-482
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• 2011

In the present study, the diffusion process of hydrogen leaking from a FCV (Fuel Cell Vehicle) in an underground parking lot was analyzed by numerical simulations in order to assess the risk of a leakage accident. The temporal and spatial changes of the hydrogen concentration as well as the flammable region in the parking lot were predicted numerically. The effects of the leakage flow rate and an additional ventilation fan were investigated to evaluate the ventilation performance in the parking lot to relieve the accumulation of the leaked hydrogen gas. The present numerical analysis can provide useful information such as the distribution of the leaked hydrogen concentration for safety of various hydrogen applications.

• 한국수소및신에너지학회논문집
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• 제19권1호
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• pp.64-70
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• 2008

This paper briefly discusses the main sources of errors and their solutions for measuring hydrogen uptake from gas phase by the Sieverts technique. Correction of volumetric errors of apparatus, density of hydrogen storage material, estimation of temperature gradient are investigated. Systematic errors and the change of density of the host material according to the pressure have been the subject of much controversy in recent years. We considered the standard ball calibration, temperature gradient distribution, pretreatment of hydrogen storage materials to minimize errors. We could lessen the miscalculations after applying those methods to Equilibrium pressure-composition isotherm data.

• Nuclear Engineering and Technology
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• 제47권4호
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• pp.424-433
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• 2015

The operating characteristics of hydrogen iodide (HI) decomposition for hydrogen production were investigated using the commercial computational fluid dynamics code, and various factors, such as hydrogen production, heat of reaction, and temperature distribution, were studied to compare device performance with that expected for device development. Hydrogen production increased with an increase of the surface-to-volume (STV) ratio. With an increase of hydrogen production, the reaction heat increased. The internal pressure and velocity of the HI decomposer were estimated through pressure drop and reducing velocity from the preheating zone. The mass of $H_2O$ was independent of the STV ratio, whereas that of HI decreased with increasing STV ratio.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제35회 추계학술대회논문집
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• pp.353-358
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• 2010

High pressure gas is a widely used storage mode for hydrogen fuel. A typical hydrogen tank that is charged with hydrogen gas can function as a hydrogen supply source in a large number of applications. The filling process of a high-pressure hydrogen tank should be reasonably short. However, when the fill time is short, the maximum temperature in the tank increases. Therefore the process should be designed in such a way to avoid high temperatures in the tank because of safety reasons. The paper simulates the fast filling process of hydrogen tanks using Computational Fluid Dynamics method. The local temperature distribution in the tank is obtained. Results obtained are compared with available experimental data. Further work is going on to improve the accuracy of the calculations.

• 한국수소및신에너지학회논문집
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• 제20권2호
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• pp.125-132
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• 2009

Cylinder shaped air-breathing PEMFC has been developed to have small volume, low contact resistance and better air accessibility to the open cathode. This cylinder shaped design consists of an anode cylinder with helical flow channel and a cathode current collector with slits. The pressure distribution measurement according to the shapes was performed. The test result indicated that cylinder shaped fuel cell has better pressure distribution compared with the planar shaped fuel cell. The better pressure distribution was connected to the higher performance. The maximum power density of cylinder shaped fuel cell was about 20% higher than the planar shaped fuel cell. The maximum power density of the developed cylinder shaped air-breathing PEMFC with dry hydrogen was $220\;mW/cm^2$ and with humidified hydrogen was $293\;mW/cm^2$.

• 한국수소및신에너지학회논문집
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• 제20권2호
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• pp.87-94
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• 2009

There are several types of compressors which are appropriate for hydrogen gas station. Diaphragm type of compressor is the one of them and it satisfies the requirements for that purpose in terms of maintaining gas purity and making high pressure over 700 bar. The objective of this study is to find an optimal design of oil distribution hole configuration. The number of holes is changed maintaining total cross-sectional area of holes. Five cases(1 hole, 4, 8,16 and 24 holes) were studied through Fluid Structure Interaction(FSI) analysis method. Gas and oil pressure, the deflection and stress of the diaphragm were analysed during compression and suction process respectively. There is no specific difference among the cases during compression. An additional deflection due to the existence of hole was found during suction for all case. But the highest deflection and stress were found in the 1 hole case. It was seen that 60% decrease of stress in magnitude in 24 hole case compare to the 1 hole case.

• 한국환경보건학회지
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• 제39권4호
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• pp.346-353
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• 2013

Objectives: The goal of this study is to identify the distribution of the foliar fluorine content of vegetation surrounding the area where hydrofluoric acid was accidently released in Gumi, Gyeongsangbuk-do on September 27, 2012. In addition, it also aims to estimate the concentration of hydrogen fluoride in the air on the day of the accident. Methods: Samples of plant leaves were collected on October 7, 2012 within 1 km from the site where the accident occurred. These samples were analyzed for soluble fluorine ion with an ion selective electrode. The ambient concentration of hydrogen fluoride was calculated using the fluoride content in the plant via the dose-rate equation (${\Delta}F$=KCT). Results: The arithmetic and geometric means of the concentrations were 2158.2 and 1183.7mg F $kg^{-1}$ for leaves and, 2.4 and 1.1 ppm HF for the air, respectively. The highest concentration of hydrogen fluoride in the air was 14.7 ppm, which is higher than the maximum concentration reported by the government (1 ppm) and the exposure limit (ceiling, 3 ppm). The concentrations of both fluorine and hydrogen fluoride decreased with increasing distance from the accident site and showed a significant decrease outside of a 500m radius from the site (p <0.05). Conclusions: The area around the accident site was highly polluted with hydrogen fluoride according to the results of this study. Considering the persistency of hydrogen fluoride in the environment, long-term monitoring and environmental impact assessment should be pursued.

• 한국수소및신에너지학회논문집
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• 제14권3호
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• pp.207-216
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• 2003

By using the electrochemical method, the relation between the deformation and the geometrical shape, and the effect of cold work on hydrogen absorption-desorption cycling in palladium were investigated, In order to study this problem, four kinds of the Pd specimens used were plates and bars as cold worked and annealed states. As results, it is found that the deformation of thickness direction in the palladium plates increased whereas other lateral directions decreased. But the palladium bars showed the same deformation ratio in all directions because of uniform distribution of the $\beta$ phase. Grains in the plate specimens were greatly deformed after hydrogenation cycling whereas grains in the bar specimens were pulverized. Also, deterioration of the hydrogen absorption rate of the bar specimen was larger than the plate specimen. And the effect of cold work on hydrogen absorption capacity was relatively small.

• 한국수소및신에너지학회논문집
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• 제33권2호
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• pp.142-147
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• 2022

Along with the global discussion on climate change prevention, regulations on hazardous substances emitted from ships were also carried out. Batteries have been regularly proposed as a solution for transportation, but lack of energy density has presented hydrogen as a final alternative. This study conducted legal issues regarding the method of providing hydrogen fuel on land and providing hydrogen fuel at sea. It is necessary to study how to institutionalize hydrogen bunkering in the legal system of the licensing system and distribution system.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2009년 춘계학술대회논문집
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• pp.176-182
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• 2009

In the present study, a numerical simulation for the diffusion of hydrogen jet in a enclosure was performed to aid the leakage test of the hydrogen for the safety of the hydrogen vehicle. The temporal and spatial distributions of the hydrogen concentration in the test chamber are predicted from the present numerical analyses. Flammable region of 4-74% and explosive region of 18-59% hydrogen by volume was identified from the present results. Factors influencing the diffusion of the hydrogen jet were examined to evaluate the effectiveness of forced ventilation for relieving the accumulation of the leaked hydrogen gas in the chamber, which include location of open windows, size of leakage nozzle, and leakage rate among others. The distribution of the concentration of the leaked hydrogen for various cases can be used as a database in various applications for the hydrogen safety.