• Journal of Hydrogen and New Energy
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• v.33 no.6
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• pp.795-802
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• 2022

Korea is showing its appearance as a leading country in the hydrogen economy by establishing policies for revitalizing the hydrogen economy and enacting the 「Hydrogen Economy Promotion and Hydrogen Safety Management Act」 for the first time in the world. In addition, domestic hydrogen facilities are using hydrogen energy safely through world-class safety management compared to overseas advanced countries. However, in order to enhance the safety of the rapidly diversifying hydrogen industry and rapid technology development, such as the introduction of liquefied hydrogen, some institutional improvements are needed. In this regard, this paper intends to analyze the results of safety inspections on 13 representative facilities and prepare safety improvement plans to establish preemptive safety measures.

• Journal of the Korean Institute of Gas
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• v.25 no.6
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• pp.74-79
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• 2021

This study analyzed the current status of the global hydrogen economy and the safety of energy sources currently in use due to the activation of the hydrogen economy. Understanding the hydrogen economy, identifying government policy trends, comparing and analyzing characteristics with existing energy sources such as gasoline, propane, and methane, and evaluating damage impact for each energy source using PHAST, a quantitative damage impact assessment program. Using the analysis results, this study analyzes the safety of hydrogen energy to revitalize the hydrogen economy and suggests ways to improve safety.

• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.48-53
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• 2017

Since the number and the amount of toxic substances handled by domestic companies have been increased, the possibility of serious chemical accidents has become severe. According to Chemistry Safety Clearing-house (CSC), the number of chemical accidents for the last five years has been rapidly raised. A representative example which shows the serious impact of a chemical accident is HF (Hydrogen Fluoride) accident generated in Gumi in 2012. In order to make effective responses for mitigating losses of accidents, the most suitable consequence model has to be selected and implemented throughout the considerations of chemical properties and environments. Even if each consequence model has been verified by the results of experiments, it is necessary to analyze and compare the usability of them according to various scenarios. In this study, the Gumi HF accident is simulated by HGSYSTEM, which is the most specialized model for the release and dispersion of HF. It is found that the ending point of ERPG-2 is about 1 km from the accident point. In order to investigate the usability of the most representative consequence models (ALOHA and CARIS), the results of them are compared with one of HGSYSTEM.

• Journal of the Korean Institute of Gas
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• v.26 no.6
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• pp.59-64
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• 2022

Currently, 787 hydrogen tube trailer are in operation as of the end of October 2022, and a maximum of 340 kg is transported in a Type 1 seamless container at a pressure of up to 200 bar. The current safety management system and facility management are in good condition, but the system and facility structure improvement are needed to strengthen safety. Accordingly, this paper simulated and analyzed an accident case that occurred on the Daejeon-Dangjin highway on December 28, 2021 during the process of expanding the supply and operation of hydrogen tube trailer according to the hydrogen energy activation policy. Based on the results, suggestions were made on how to improve the safety of hydrogen tube trailer.

• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.13-21
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• 2021

Because of the recent expansion of hydrogen vehicle supply, the installation of hydrogen filling station is expected to gradually expand. This study attempts to predict the damage scale and propose a safer design form based on the scenario that assumes the worst case of a hydrogen station. A Flacs solver using computational fluid dynamics (CFD) was used to predict the damage scale, and the accuracy was verified by comparing it with the experimental results of previous researchers. The damage scale prediction was conducted for hydrogen leakage and explosion, and the prediction target was the KR model based on the measured values. And as a comparative review model, a roofless model was selected without a ceiling. As a result of analyzing the two models, it was possible to confirm the accumulation and retention of hydrogen gas up to 60 vol% or more in the KR model, whereas in the case of the Roofless model, the phenomenon of discharge and diffusion to the outside of the charging station by riding the wall after leakage. I was able to check. In conclusion, it was reviewed that the type of hydrogen charging station without ceiling is more advantageous for safety than the hydrogen filling station model.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.116-122
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• 2023

In addition to analyzing the hydrogen economy trends of the international community (Korea, the United States, Europe, Japan, etc.), which is being promoted to realize a carbon-neutral society, this study compared and analyzed the differences between the gaseous hydrogen refueling station, which is a key hydrogen-using facility close to the people, and a liquefied hydrogen refueling station that is scheduled to be built in the future. In addition, SAFETI, a quantitative risk assessment program, was used to analyze the safety of liquefied hydrogen refueling stations and In consideration of the individual and societal risks and the ranking of risks by facility, which are conditional allowable areas, a plan to improve safety such as facility layout was proposed

• Journal of Hydrogen and New Energy
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• v.35 no.1
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• pp.66-74
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• 2024

This study addresses the escalating issue of worldwide hydrogen gas accidents, which has seen a significant increase in occurrences. To comprehensively evaluate the risks associated with hydrogen, a two approach was employed in this study. Firstly, a qualitative risk assessment was conducted using the bow-tie method. Secondly, a quantitative consequence analysis was carried out utilizing the areal locations of hazardous atmospheres (ALOHA) model. The study applied this method to two incidents, the hydrogen explosion accident occurred at the Muskingum River power plant in Ohio, USA, 2007 and the hydrogen storage tank explosion accident occurred at the K Technopark water electrolysis system in Korea, 2019. The results of the risk assessments revealed critical issues such as deterioration of gas pipe, human errors in incident response and the omission of important gas cleaning facility. By analyzing the cause of accidents and assessing risks quantitatively, the effective accident response plans are proposed and the effectiveness is evaluated by comparing the effective distance obtained by ALOHA simulation. Notably, the implementation of these measures led to a significant 54.5% reduction in the risk degree of potential explosions compared to the existing risk levels.

• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.750-754
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• 2014

Quantitative risk analysis has been performed for a pervaporation process for production of high test peroxide. Potential main accidents are explosion and fire caused by a decomposition reaction. As the target process has a laboratory scale, the consequence is considered to belong to Category 3. An event tree has been developed as a model for occurrence of a decomposition reaction in the target process. The probability functions of the accident causes have been established based on the frequency data of similar events. Using the constructed model, the failure rate has been calculated. The result indicates that additional safety devices are required in order to achieve an acceptable risk level, i.e. an accident frequency less than $10^{-4}/yr$. Therefore, a layer of protection analysis has been applied. As a result, it is suggested to introduce inherently safer design to avoid catalytic reaction, a safety instrumented function to prevent overheating, and a relief system that prevents explosion even if a decomposition reaction occurs. The proposed method is expected to contribute to developing safety management systems for various chemical processes including concentration of hydrogen peroxide.

• Fire Science and Engineering
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• v.25 no.6
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• pp.32-38
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• 2011

As the using rate of an explosive gas has been increased in the industrial site, the regional residents adjacent to the site as well as the site workers have frequently fallen into a dangerous situation. Damage caused by accident in the process using hydrogen gas is not confined only to the relevant process, but also is linked to a large scale of fire or explosion and it bring about heavy casualties. Therefore, personnel in charge should investigate the kinds and causes of the accident, forecast the scale of damage and also, shall establish and manage safety countermeasures. We, in Anti-Calamity Research Center, forecasted the scope of danger if break out a fire or/and explosion in hydrogen gas facilities of MLCC firing process. We selected piping leak accident, which is the most frequent accident case based on an actual analysis of accident data occurred. We select and apply piping leak accident which is the most frequent case based on an actual accident data as a model of damage forecasting scenario caused by accident. A jet fire breaks out if hydrogen gas leaks through pipe size of 10 mm ${\Phi}$ under pressure of 120 bar, and in case of $4kw/m^2$ of radiation level, the radiation heat can produce an effect on up to distance of maximum 12.45 meter. Herein, we are going to recommend safety security and countermeasures for improvement through forecasting of accident damages.

• Journal of the Society of Disaster Information
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• v.9 no.4
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• pp.449-461
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• 2013

As the hydrofluoric acid leak in Gumi-si, Gyeongsangbuk-do or hydrochloric acid leak in Ulsan, Gyeongsangnam-do demonstrated, chemical related accidents are mostly caused by large amounts of volatile toxic substances leaking due to the damages of storage tank or pipe lines of transporter. Safety assessment is the most important concern because such toxic material accidents cause human and material damages to the environment and atmosphere of the surrounding area. Therefore, in this study, a hydrofluoric acid leaked from a storage tank was selected as the study example to simulate the leaked substance diffusing into the atmosphere and result analysis was performed through the numerical Analysis and diffusion simulation of ALOHA(Areal Location of Hazardous Atmospheres). the results of a qualitative evaluation of HAZOP (Hazard Operability)was looked at to find that the flange leak, operation delay due to leakage of the valve and the hose, and toxic gas leak were danger factors. Possibility of fire from temperature, pressure and corrosion, nitrogen supply overpressure and toxic leak from internal corrosion of tank or pipe joints were also found to be high. ALOHA resulting effects were a little different depending on the input data of Dense Gas Model, however, the wind direction and speed, rather than atmospheric stability, played bigger role. Higher wind speed affected the diffusion of contaminant. In term of the diffusion concentration, both liquid and gas leaks resulted in almost the same $LC_{50}$ and ALOHA AEGL-3(Acute Exposure Guidline Level) values. Each scenarios showed almost identical results in ALOHA model. Therefore, a buffer distance of toxic gas can be determined by comparing the numerical analysis and the diffusion concentration to the IDLH(Immediately Dangerous to Life and Health). Such study will help perform the risk assessment of toxic leak more efficiently and be utilized in establishing community emergency response system properly.