• 한국수소및신에너지학회논문집
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• 제28권4호
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• pp.392-400
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• 2017

An experimental study was conducted to investigate behavior of steel surface oxidation with characteristics of the combustion. The excess entalphy combustion in porous media system was applied to implement the direct radiation heating system. The surface oxidation thickness (SOT) of fuel-lean was thicker than the SOT of fuel-rich. Also, the SOT was increased by increasing residence time. Detailed explanations were given by SEM and EDS analysis.

• 연구논문집
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• 통권29호
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• pp.91-99
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• 1999

Fatigue crack growth behaviors of Cr-Mo steels developed recently for thick-wall pressure vessel were investigated. Experiments in accordance with ASTM E647 standard were performed for 1/2 inch CT specimens of $2^(1/4)$Cr-1Mo and 3Cr-IMo steels in gaseous environments, hydrogen gas of 10 atm, 1 atm and argon gas of 1 atm. Fatigue crack growth rates were observed and effects of gaseous hydrogen and argon on the crack growth behavior were discussed.

• 한국수소및신에너지학회논문집
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• 제29권4호
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• pp.378-385
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• 2018

An experimental study was conducted to investigate behavior of surface oxidation with steel type. The excess entalphy combustion in porous media system was applied to implement the direct radiation heating system. The surface oxidation thickness (SOT) in fuel-lean condition was thicker than the SOT in fuel-rich. Also, the SOT was increased by increasing residence time. Detailed explanations were given by SEM and EDS analysis.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.1192-1197
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• 2003

The aim of this study is to investigate the hydride embrittlement when the LBB evaluation is carried out for the integrity of PHWR Pressure Tubes. The transverse tensile and CCT tests were performed at three hydrogen concentrations while the test temperatures were changed (RT to $300^{\circ}C$). The specimens were directly machined from the pressure tube retaining original curvature. Both the transverse tensile and the fracture toughness tests showed the hydrogen embrittlement clearly at RT but this phenomenon was disappeared while the test temperature arrived over $250^{\circ}C$. Using the DHC test results, the CCL and LBB time were calculated and compared. The hydride embrittlement behavior at the LBB evaluation was definitely showed.

• 한국수소및신에너지학회논문집
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• 제29권5호
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• pp.503-511
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• 2018

There have been many studies of combustion in the circulating fluidized bed. However, little study is available for combustion of wood pellet together fed with wood chip. The mixed ratio of two fuels is an useful information when thermal power company would receive the Renewable Energy Portfolio Standard (RPS) from government. In this study, the combustion behavior and kinetics of such biomass fuels are evaluated using fluidized bed reactor and thermogravimetric analyzers. The mixing ratio of wood chip relative to wood pellet was varied at different temperatures. The results show that a combustion reactivity changed significantly at the wood chip mixing ratio of 40%, particularly at low temperature condition.

• 한국수소및신에너지학회논문집
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• 제30권3호
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• pp.260-268
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• 2019

The pyrolysis characteristics of pulverized coal particle was numerically analyzed with the drop tube furnace. Based on the simulated gas flow field in the drop tube furnace, the particle velocity, temperature and volatile evolution were calculated with the fourth order Runge-Kutta method. The effects of changes in reactor wall temperature and particle diameter on the pyrolysis behavior of coal particle were investigated. The particle heating rate was very sensitive to the reactor wall temperature and particle size, that is, the higher wall temperature and the smaller particle size resulted in the higher heating rate and the consequent quicker volatile evolution.

• 전기화학회지
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• 제17권1호
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• pp.18-25
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• 2014

A Pt nanoparticle-decorated multiwall carbon nanotube (Pt-MWNT) electrode was prepared on Nafion by a hot-pressing at relatively low temperature. This electrode exhibited an intricate entangled, nanoporous structure as a result of gathering highly anisotropic Pt-MWNTs. Individual Pt nanoparticles were confirmed to have a polycrystalline face-centered cubic structure with an average crystal size of around 3.5 nm. From the cyclic voltammograms for hydrogen redox reactions, the Pt-MWNT electrode was found to have a similar electrochemical behavior to polycrystalline Pt, and a specific electrochemical surface area of $2170cm^2mg^{-1}$. Upon exposure to hydrogen analyte, the Pt-MWNT/Nafion electrode demon-strated a very high sensitivity of $3.60{\mu}A\;ppm^{-1}$ and an excellent linear response over the concentration range of 100-1000 ppm. Moreover, this electrode was also evaluated in terms of response and recovery times, reproducibility, and long-term stability. Obtained results revealed good sensing performance in hydrogen detection.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2005년도 생물공학의 동향(XVI)
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• pp.287-292
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• 2005

Hybrid시스템의 운전결과 황화수소의 removal efficiency는 황화수소의 inlet load가 $200g/m^{3}/h$에서 removal efficiency가 급격히 감소하여 약 60%의 수준을 유지하였다. 또한 톨루엔에 대한 removal efficiency는 거의 100%를 유지하다가 톨루엔의 inlet load가 $644g/m^{3}/h$로 증가할 때에는 약 60%로 감소하였다. 이와 같은 Hybrid시스템 운전결과로 부터 바이오필터만을 이용하여 황화수소와 톨루엔을 동시처리할 때보다 removal efficiency가 제고되었음이 관찰되었다.

• 한국수소및신에너지학회논문집
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• 제19권6호
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• pp.482-489
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• 2008

Ti-Cr alloys consist of BCC solid solution, C36, C14 and C15 Laves phase at high temperature. Among others, the BCC solid solution phase was reported to have a high hydrogen storage capacity. However, activation, wide range of hysteresis at hydrogenation/dehydrogenation, and degradation of hydrogen capacity due to hydriding/dehydriding cycles must be improved for its application. In this study, to improve such problems, we added a Nb. For attaining target materials, Ti-10Cr-xNb(x=1, 3, 5wt.%) specimens were prepared by arc melting. The arc melting process was carried out under argon atmosphere. As-received specimens were characterized using XRD(X-ray diffraction), SEM(Scanning Electron Microscopy) with EDX(Energy Dispersive X-ray) and TG/DSC(Thermo Gravimetric Analysis/Differential Scanning Calorimetry). In order to examine hydrogenation behavior, the PCI(pressure-Composition-Isotherm) was performed at 293, 323, 373 and 423K.

• 한국수소및신에너지학회논문집
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• 제1권1호
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• pp.1-8
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• 1989

The hydriding kinetic mechanism and the change of the hydriding reaction rate of $MmNi_{4.5}Al_{0.5}$ during the thermally induced hydrogen absorption-desorption cycling are investigated. Comparison of the reaction rate data which are obtained by the pressure sweep method with the theoretical rate equations suggests that the hydriding rate controlling step has changed from the dissociative chemisorption of hydrogen molecules at the surface to the hydrogen diffusion through the hydride phase with the increase of the hydriding fraction. These hydriding kinetic mechanism is not changed during the cycling. However, the intrinsic hydriding reaction rate of $MmNi_{4.5}Al_{0.5}$ after 5500 cycles increases significantly comparing with the activated one. It is suggested that the change of the hydriding kinetic behavior due to intrinsic degradation of $MmNi_{4.5}Al_{0.5}$ can be interpreted as follows ; the formation of nickel cluster at the surface of the sample and the host metal atom exchange in bulk by thermal cycling.