• 제목/요약/키워드: Hydrogen annealing

검색결과 195건 처리시간 0.028초

$(Pb_{0.72}La_{0.28})Ti_{0.94}O_3$ buffer를 사용한 $Pb(Zr_{0.52}Ti_{0.48})O_3$ 박막의 수소 후열처리 효과 (Effect of the hydrogen annealing on the $Pb(Zr_{0.52}Ti_{0.48})O_3$ film using $(Pb_{0.72}La_{0.28})Ti_{0.94}O_3$ buffers)

  • 이은선;이동화;정현우;임성훈;이상렬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.191-194
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    • 2004
  • Ferroelectric $Pb(Zr_{0.52}Ti_{0.48})O_3$ (PZT) 박막을 $Pt(111)/Ti/SiO_2/Si$ 기판위에 증착되었고, 수소 후열처리 후의 특성변화를 연구하였다. 동시에 10 nm의 $(Pb_{0.72}La_{0.28})Ti_{0.94}O_3$ (PLT) buffer를 사용한 PZT 박막의 수소 후열처리 효과를 관찰하였다. PZT 박막의 경우, 수소 후열처리 전과 후에 강유전 특성이 현저하게 감소한 반면, PLT buffer가 사용된 PZT 박막의 경우, 강유전 특성에 거의 변화가 없었다. 이는 PLT buffer를 사용함으로써 PZT 박막의 배향성이 향상되고, 이에 따라 forming gas에 의한 수소원자가 박막 내로의 침투가 어렵게 된다. 따라서 수소원자에 대한 PZT 박막의 열화되는 현상이 buffer를 사용하는 경우, 거의 나타나지 않게 된다.

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프리 패턴한 비정질 실리콘 박막의 two-step RTA 효과 (THE TWO-STEP RAPID THERMAL ANNEALING EFFECT OF THE PREPATTERNED A-SI FILMS)

  • 이민철;박기찬;최권영;한민구
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1333-1336
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    • 1998
  • Hydrogenated amorphous silicon(a-Si:H) films which were deposited by plasma enhanced chemical deposition(PECVD) have been recrystallized by the two-step rapid thermal annealing(RTA) employing the halogen lamp. The a-Si:H films evolve hydrogen explosively during the high temperature crystallzation step. In result, the recrystallized polycrystalline silicon(poly-Si) films have poor surface morphology. In order to avoid the hydrogen evolution, the films have undergone the dehydrogenation step prior to the crystallization step Before the RTA process, the active area of thin film transistors (TFT's) was patterned. The prepatterning of the a-Si:H active islands may reduce thermal damage to the glass substrate during the recrystallization. The computer generated simulation shows the heat propagation from the a-Si:H islands into the glass substrate. We have fabricated the poly-Si TFT's on the silicon wafers. The maximun ON/OFF current ratio of the device was over $10^5$.

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산소 분위기 열처리에 따른 ZnO 나노선의 상온 영역에서의 수소가스 검출 특성 향상 (Enhanced Hydrogen Gas Sensing Properties of ZnO Nanowires Gas Sensor by Heat Treatment under Oxygen Atmosphere)

  • 강우승
    • 한국표면공학회지
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    • 제50권2호
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    • pp.125-130
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    • 2017
  • ZnO nanowires were synthesized and annealed at various temperatures of $500-800^{\circ}C$ in oxygen atmosphere to investigate hydrogen gas sensing properties. The diameter and length of the synthesized ZnO nanowires were approximately 50-100 nm and a few $10s\;{\mu}m$, respectively. $H_2$ gas sensing performance of the ZnO nanowires sensor was measured with electrical resistance changes caused by $H_2$ gas with a concentration of 0.1-2.0%. The response of ZnO nanowires at room temperature to 2.0% $H_2$ gas is found to be two times enhanced by annealing process in $O_2$ atmosphere at $800^{\circ}C$. In the current study, the effect of heat treatment in $O_2$ atmosphere on the gas sensing performance of ZnO nanowires was studied. And the underlying mechanism for the sensing improvement of the ZnO nanowires was also discussed.

유전 알고리즘 및 담금질 기법을 활용한 Type 4 복합재료 압력용기 최적화 프로세스 (Optimization Process of Type 4 Composite Pressure Vessels Using Genetic and Simulated Annealing Algorithm)

  • 송귀남;김한상
    • 한국수소및신에너지학회논문집
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    • 제32권4호
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    • pp.212-218
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    • 2021
  • In this study, we conducted a design optimization of the Type 4 composite pressure vessels to enhance the pressure-resistant performance of the vessels while keeping the thickness of the composite layer. The design variables for the optimization were the stacking angles of the helical layers of the vessels to improve the performance. Since the carbon fibers are expensive material, it is desirable to reduce the use of the carbon fibers by applying an optimal design of the composite pressure vessel. The structural analysis and optimization process for the design of Type 4 composite pressure vessels were carried out using a commercial finite element analysis software, Abaqus and a plug-in for automated simulation, Isight, respectively. The optimization results confirmed the performance and safety of the optimized Type 4 composite pressure vessels was enhanced by 12.84% compared to the initial design.

78K에서 수소 혹은 중수소 흡착으로 인한 W(123)면의 일함수 변화 (Work Function Change of W(123) Plane Due to Hydrogen and Deuterium Adsorption at 78K)

  • 박노길;김기석;김성수;정광호;황정남;최대선
    • 한국진공학회지
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    • 제1권1호
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    • pp.78-82
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    • 1992
  • W(123) 표면위에 수소와 중소수가 흡착될 때 일함수의 변화를 장방출(Field Fmission) 방법으로 측정하였다. 78K에서 이 분자들이 흡착될 때 일함수의 변화는 처음에 는 증가하다가 최대치에 이른 후 감소하였고, 덮임율(coverage)이 증가함에 따라 포화되었 다. 텅스텐 tip의 온도를 200K까지 올렸을 경우에, 일함수의 변화가 최대가 되었을 때의 덮 임율은 78K일 때의 비해 낮은 덮임율 쪽으로 이동하였고, [011] 방향을 갖는 step 혹은 terrace에 의한 일함수의 효과도 동시에 관측되었다.

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수소기처리에 의한 수소화된 비정질규소의 안정성에 관한 연구 (The Stability of Hydrogenated Amorphous Silicon by Hydrogen Radical Annealing)

  • 이재희;이원식
    • 한국진공학회지
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    • 제5권1호
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    • pp.73-76
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    • 1996
  • We have prepared hydrogenated amophous silicon (a-si : H) films with superlattice structure by hydrogen radical anneling(HRA) technique. We have studied the preparation of a-Si :H films by HRA and the optical & electronic characteristics. Optical band gap and the hydrogen contents in the a Si : H film is decreased as HRA time increased. We first report a -Si : H film prepared by periodicdeposition of a-Si : H layer and HRA have the superlattice structure using TEM . After 1 hour light soaking on the a-Si :H film prepared by HRA, there are no difference in the temperatre dependence of dark conductivity and the conductivity activation energy. An excellent stability for light in a-Si :H films by HRA can be explained using the long-range structural relaxation of the amorphous network and the propertiesof light -induced defects(LID) proposed by Fritzsche.

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어닐링 온도 변화에 따른 다결정 MOSFET의 Subthreshold 특성 (Subthreshold characteristics of polysilicon MOSFETs depending on Annealing Temperature)

  • 홍찬희;백동수;홍재일;유주현;박창엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1990년도 추계학술대회 논문집
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    • pp.55-59
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    • 1990
  • N-Channel polysilicon MOSFETs (W/L=20/1.5, 3, 5.10$\mu\textrm{m}$) were fabricated using RTP(Rapid Thermal Processor) and hydrogen passivation. The N+ Source, drain and gate were annealed and recrystallized using RTP at temperature of 1000$^{\circ}C$-1100$^{\circ}C$. But the active areas were now specially crystallized before growing the gate oxide. Without the hydrogen passivation, excellent transistor characteristics (ON/OFF=5${\times}$10$\^$6/, s=85mv/dec, I$\_$L/=51pA/$\mu\textrm{m}$) were obtained for 1.5$\mu\textrm{m}$ MOSFET. Also the transistor characteristics were improved by hydrogen passivation.

광검출기용 다결정 실리콘 박막의 전도특성 분석을 통한 결정립계의 모형화 (Modelling of Grain Boundary in Polysilicon Film for Photodetector Through Current-Voltage Analysis)

  • 이재성
    • 한국전기전자재료학회논문지
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    • 제33권4호
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    • pp.255-262
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    • 2020
  • Grain boundaries play a major role in determining device performance, particularly of polysilicon-based photodetectors. Through the post-annealing of as-deposited polysilicon and then, the analysis of electric behavior for a metal-polysilicon-metal (MSM) photodetector, we were able to identify the influence of grain boundaries. A modified model of polysilicon grain boundaries in the MSM structure is presented, which uses a crystalline-interfacial layer-SiOx layer- interfacial layer-crystalline system that is similar to the Si-SiO2 system in MOS device. Hydrogen passivation was achieved through a hydrogen ion implantation process and was used to passivate the defects at both interfacial layers. The thin SiOx layer at the grain boundary can enhance the photosensitivity of an MSM photodetector by decreasing the dark current and increasing the light absorption.

고압의 수소 및 중수소 분위기에서 열처리된 실리콘 산화막의 전기적 특성 관찰 (Electrical Characteristics of Ultra-thin $SiO_2$ Films experienced Hydrogen or Deuterium High-pressure Annealing)

  • 이재성;백종무;도승우;장철영;이용현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.29-30
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    • 2005
  • Experimental results are presented for the degradation of 3 nm-thick gate oxide ($SiO_2$) under both Negative-bias Temperature Instability(NBTI) and Hot-carrier-induced(HCI) stresses using P and NMOSFETs that are annealed with hydrogen or deuterium gas at high-pressure (1~5 atm.). Statistical parameter variations depend on the stress conditions. We suggest that deuterium bonds in $SiO_2$ film is effective in suppressing the generation of traps related to the energetic hot electrons.

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STM Study on c(4$\times$4) Reconstruction of Si(100)

  • Maeng, Jae-Yeol;Kim, Sehun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.151-151
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    • 2000
  • We have studied the atomic structure of Si(100)-c(4$\times$4) reconstruction using scanning tunneling microscopy(STM). The c(4$\times$4) reconstruction can be formed by annealing the hydrogen exposured surface at temperatures between 850 and 960 K. At this temperature ranges, adsorbed hydrogen atoms are all desorbed. Therefore, the c(4$\times$4) reconstruction is due to the Si dimers on surface. The filled and empty state images of the STM were interpreted in terms of Si dimers in c(4$\times$4) primitive cell forming the reconstruction. Based on the STM images and hydrogen adsorption experiment on c(4$\times$40 surface, we suggest that Si dimers in c(4$\times$40 unit cell are perpendicular ad-dimer to the underlying Si dimer rows.

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