• 센서학회지
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• 제19권2호
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• pp.67-86
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• 2010

Hydrogen is emerging as clean fuel and important industrial raw materials. The hydrogen gas is not sensed by the human olfactory system, But the combustion characteristics of hydrogen is that the ignition is very easy, the propagation speed of the flame is very fast and explosion limits is a wide range of 4 %~75 %. Therefore it is extremely in danger, and the need for its leakage detection technologies is especially important in places such as a production, transportation, storage and usage. The hydrogen sensors are classified with ceramic type, semiconductor type, optical type, electrochemical type and so on. Hydrogen sensors and their technologies are reviewed in detail for materials, fabrication process, sensing characteristics, good point and faults, and production and utilization of sensors be discussed.

• 한국수소및신에너지학회논문집
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• 제2권1호
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• pp.69-75
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• 1990

The effect of thermal cycling on the hydrogenation characteristics of the $Mg_2Cu-H$ system was investigated in order to study of intrinsic degradation of the system. The hydrogen storage capacity decreased with thermal cycling from $573^{\circ}K$ to $663^{\circ}K$. By the thermal analysis it is found that stable $MgH_2$ hydride is formed during thermal cycling. With a heat treatment at $693^{\circ}K$ at a hydrogen pressure of 16 atm, the hydrogenation rate drastically decreased. From these observation, it suggested that the intrinsic degradation of $Mg_2Cu$ system results from mainly the formation of stable $MgH_2$ hydride phase.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.634-640
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• 2011

The effect of cycling on the absorption and desorption characteristics of the 80 wt% $AB_2$-15 wt% Mg-5 wt% Mm system was investigated. The material was made by Hydrogen Combustion Synthesis. The cycling experiment was performed at 298 K, 30 atm for 15 min. During the reaction time, the amount of absorption was fully desorbed. After the full activation, the hydrogen storage capacity was 1.57 wt% and the capacity was maintained until 50 cycles. And the reaction rate does not change with an increase in the number of cycles. This material has good durability and reversible feature.

• 한국초전도ㆍ저온공학회논문지
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• 제24권2호
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• pp.27-38
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• 2022

Urban air mobility (UAM) has recently attracted lots of attention as a solution to urban centralization and global warming. Electric vertical take-off and landing (eVTOL) is a concept that emerges as one of the promising and clean technologies for UAM. There are two difficult challenges for eVTOL aircraft to solve. One is how to improve the weight efficiency of aircraft, and the other is how to complete long-range missions for UAM's flight scenarios. To approach these challenges, we propose a consolidated concept design of battery-fuel cell hybrid tiltrotor aircraft with a liquid hydrogen (LH₂) fuel tank. The efficiency of a battery-fuel cell hybrid powertrain system on the designed eVTOL aircraft is compared to that of a battery-only powertrain system. This paper shows how much payload can increase and the flight scenario can be improved by hybridizing the battery and fuel cell and presenting a detailed concept of a cryogenic storage tank for LH₂.

• 한국수소및신에너지학회논문집
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• 제31권1호
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• pp.33-40
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• 2020

As hydrogen utilization becomes more active recently, a large amount of hydrogen should be supplied safely. Among the three supply methods, liquefied hydrogen, which is an optimal method of storage and transportation convenience and high safety, has a low temperature of -253℃, which is complicated by the liquefaction process and consumes a lot of electricity, resulting in high operating costs. In order to reduce the electrical energy required for liquefaction and to raise the efficiency, hydrogen is cooled by using a mixed refrigerant in a precooling step. The electricity required for the precooling process of the mixed refrigerant can be reduced by using the cold energy of LNG. Actually, LNG cold energy is used in refrigeration warehouse and air liquefaction separation process, and a lot of power reduction is achieved. The purpose of this study is to replace the electric power by using LNG cold energy instead of the electric air-cooler to lower the temperature of the hydrogen and refrigerant that are increased due to the compression in the hydrogen liquefaction process. The required energy was obtained by simulating mixed refrigerant (MR) hydrogen liquefaction system with LNG cold heat and electric system. In addition, the power replacement rate of the electric process were obtained with the pressure, the temperature of LNG, the rate of latent heat utilization, and the hydrogen liquefaction capacity, Therefore, optimization of the hydrogen liquefaction system using LNG cold energy was carried out.

• 한국수소및신에너지학회논문집
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• 제31권4호
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• pp.337-344
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• 2020

Worldwide, there is a significant surge in the efforts for addressing the issue of global warming; the use of renewable energy is one of the solutions proposed to mitigate global warming. However, severe volatility is a critical disadvantage, and thus, power-to-gas technology is considered one of best solutions for energy storage. Hydrogen is a popular candidate from the perspective of both environment and economics. Accordingly, a hydrogen production system based on renewable energy sources is developed, and the economics of the system are assessed. The result of the base case shows that the unit cost of hydrogen production would be 6,415 won/kg H₂, with a hydrogen production plant based on a 100 MW akaline electrolyzer and 25% operation rate, considering renewable energy sources with no electricity cost payment. Sensitivity study results show that the range of hydrogen unit cost efficiency can be 2,293 to 6,984 Won/kg H₂, depending on the efficiency and unit cost of the electrolyzer. In case of electrolyzer operation rate and electricity unit cost, sensitivity study results show that hydrogen unit cost is in the range 934-26,180 won/kg H₂.

• 한국수소및신에너지학회논문집
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• 제26권2호
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• pp.114-119
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• 2015

Nowdays, fossil fuels have been used as an important resource in development of industry. But it is limited and caused climate change such as pollution and global warming. So nuclear fusion research is being issued with tritium to develop eco-friendly and sustainable energy. Republic of Korea is in charge of Storage and Delivery System (SDS) in the International Thermonuclear Experimental Reactor (ITER), weld present in the SDS bottles are easily exposed to the hydrogen embrittlement of special characteristics of the hydrogen in hydrogen atmosphere, When the hydrogen embrittlement is rapidly progresses, the cracking is generated in the weld zone. Due to this cracking, the risk of leakage of tritium into the atmosphere occurs. In this study, hydrogen heat treatment was processed through the Pressure-Composition-Temperature (PCT) device according to the time variation. Also mechanical properties such as rupture strength test, three point bend test and hardness test in accordance with the respective time have been conducted and the fracture was observed by scanning electron microscopy(SEM) after the mechanical properties evaluation.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.845-855
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• 2022

In response to climate change, the world is continuing efforts to reduce fossil fuels, expand renewable energy, and improve energy efficiency with the goal of achieving carbon neutrality. In particular, R&D is being made on the value chain covering the entire cycle of hydrogen production, storage, transportation, and utilization in order to shift the energy supply system to focus on hydrogen energy. Hydrogen-based energy sources can produce heat and electricity at the same time, so it is possible to utilize heat energy, which can increase overall efficiency. In this study, calculation of the optimal scale for hydrogen-based cogeneration and the composition of heat sources were reviewed. It refers to a method of the optimal heat source size according to the external heat supply and heat storage to be considered. The results of this study can be used as basic data for establishing a hydrogen-based energy supply model in the future.

• Bulletin of the Korean Chemical Society
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• 제32권6호
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• pp.1879-1883
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• 2011

The electronic structure and bonding in $Ti_2Pd$ and $Pd_2Ti$ alloys with and without hydrogen as an interstitial atom were studied by performing extended Huckel tight-binding band calculations. The hydrogen absorption near an octahedral site is found to be a favorable process in $Ti_2Pd$ rather than in $Pd_2Ti$. In metal hydrides, the metal-hydrogen bonding contribution is crucial to the stability of the system. The stronger interaction of hydrogen with Ti atoms in $Ti_2PdH_2$ than with Pd atoms in $Pd_2TiH_2$ is analyzed by perturbation theory.

• 한국수소및신에너지학회논문집
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• 제29권1호
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• pp.25-31
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• 2018

To apply Sievert's type apparatus to thermal analysis of hydrogen absorption materials, the dehydrogenation of $LaNi_5$ system was investigated. As the initial wt% of hydrogen was increased from 0.44 to 1.24 wt%, the peak temperature of evolution rate shifted to higher temperature. However, with the initial wt% of hydrogen higher than 0.95 wt%, the peak temperature of evolution rate did not change. As the heating rate was increased, the peak temperature increased; the peak temperatures for heating rates 0.5, 1.0 and 1.5 K/min were 262.2, 264.1, and 265.9 K respectively. The Sievert's type automatic apparatus can be successively applied to the thermal analysis of $LaNi_5$ hydride.