• 제목/요약/키워드: Hydrogen Network

검색결과 181건 처리시간 0.029초

입지배분모형 기반의 서울시 수소충전소 접근성 분석 (An Analysis of Accessibility to Hydrogen Charging Stations in Seoul Based on Location-Allocation Models)

  • 김상균;원종석;편용범;조민경
    • 한국재난정보학회 논문집
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    • 제20권2호
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    • pp.339-350
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    • 2024
  • 연구목적: 이 연구는 서울시 10개 수소충전소의 공간적 접근성 분석을 실시하고, 접근이 어려운 지역을 식별하였다. 입지의 형평성과 안전성 측면에서 신규 입지를 추가하여 접근성을 분석을 다시 수행한 후, 개선 효과 비교를 통해 시사점을 도출하는 것을 목적으로 한다. 연구방법: ArcGIS 프로그램의 네트워크 분석 기반의 입지배분(Location-Allocation) 모형과 이용권역(Service Area) 모형을 적용하여 접근이 취약한 지역을 식별하였다. 입지선정 방분석 기반의 입지배분(Location-Allocation) 모형과 이용권역(Service Area) 모형을 적용하여 접근이 취약한 지역을 식별하였다. 입지선정 방법은 부족한 수소충전소에 신속한 도착이 필요한 점을 고려하여 '최소시설 수로 최대수요를 확보하도록 함(Minimize Facilities)' 방법을 적용하였다. 특정한 시간 내의 도착을 위한 한계 거리는 서울시 2022년 평균 차량통행속도(23.1km/h, 서울시 열린데이터 광장)를 적용하여 10분 이동가능 거리인 3,850m과 5,775m(15분) 그리고 7,700m(20분)의 세 가지로 분하여 분석하였다. 신규 입지는 수소충전소 설치에 대한 갈등을 최소화하기 위하여 산업통상자원부의 특례기준1)을 적용하여 기존의 주유소, LPG/CNG 충전소 중에서 수소충전소 추가 설치가 가능한 후보지를 도출하였다. 연구결과: 분석 결과, 최종적으로 상세 현황 검토를 통해 추가 후보지 5개소가 도출되었다. 기존 10개의 수소충전소에 20분 이내 접근이 취약한 지역을 중심으로 상대적으로 안전한 기존 주유소와 LPG/CNG 충전소에 신규 수소충전소 5개소를 설치하면 접근성이 크게 개선됨을 확인할 수 있었다. 그럼에도 불구하고 여전히 접근이 어려운 지역이 있는 것으로 나타났다. 결론: 입지배분모형을 이용하여 수소충전소 접근이 어려운 지역을 식별하고, 설치의 우선순위를 부여한다면 과학적 근거 기반 수소충전소 입지 선정을 위한 의사결정을 지원할 수 있다.

기술로드맵을 통한 기술기획: 특허인용네트워크의 활용 (Technology Planning through Technology Roadmap: Application of Patent Citation Network)

  • 정유진;윤병운
    • 한국산학기술학회논문지
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    • 제12권11호
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    • pp.5227-5237
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    • 2011
  • 기술로드맵은 기술, 제품, 시장의 관계를 고려하여 기술전략 및 기획을 지원하는 강력한 도구로서 기술 로드맵을 개발하거나 실무에 적용시킨 사례 등과 관련된 연구가 다수 수행되었다. 그러나 대부분의 기술로드맵 연구들은 체계적이고 정량적인 분석보다는 브레인스토밍, 전문가 그룹 활용, 델파이 등과 같은 정성적인 방법에 의존하고 있다. 이러한 한계를 극복하기 위해, 본 연구에서는 대표적인 정량적 분석인 특허분석을 활용하였다. 따라서 본 연구의 목적은 기술수명주기를 고려한 특허인용네트워크를 개발하여 기술로드맵 작성에 적용하고, 이를 통해 유망한 미개발 기술을 기획하는 것이다. 이를 위하여, 우선 특허데이터와 인용정보가 수집되고 이를 바탕으로 특허인용 네트워크가 작성된다. 둘째, 기술수명주기 및 특허출원연도를 고려하여 수명주기에서의 위치를 분석하고, 향후 기술개발기간이 추정된다. 기술진화를 보여주기 위해 하위 세부기술들은 그룹핑되어 상위기술을 설명하고 이는 기술로드맵에 포함되는 노드로서 지칭된다. 마지막으로 기술 층의 각 기술 노드들을 연결 짓고 개발기간을 추정하여 기술로드맵을 작성한다. 이 기술로드맵을 바탕으로 기술기획을 수행하기 위해 텍스트 마이닝을 적용하여 미개발 기술을 제시하고, 향후 개발될 필요가 있는 기술의 특성을 제안한다. 본 연구는 수소저장 기술을 선정하여 앞에서 제시된 방법과 과정을 설명하였다.

Carbon and Energy Balances of Glucose Fermentation with Hydrogen-producing Bacterium Citrobacter amalonaticus Y19

  • Oh, You-Kwan;Park, Sung-Hoon;Seol, Eun-Hee;Kim, Seo-Hyoung;Kim, Mi-Sun;Hwang, Jae-Woong;Ryu, Dewey D.Y.
    • Journal of Microbiology and Biotechnology
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    • 제18권3호
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    • pp.532-538
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    • 2008
  • For the newly isolated $H_2$-producing chemoheterotrophic bacterium Citrobacter amalonaticus Y19, anaerobic glucose metabolism was studied in batch cultivation at varying initial glucose concentrations (3.5-9.5 g/l). The carbon-mass and energy balances were determined and utilized to analyze the carbon metabolic-pathways network. The analyses revealed (a) variable production of major metabolites ($H_2$, ethanol, acetate, lactate, $CO_2$, and cell mass) depending on initial glucose levels; (b) influence of NADH regeneration on the production of acetate, lactate, and ethanol; and (c) influence of the molar production of ATP on the production of biomass. The results reported in this paper suggest how the carbon metabolic pathway(s) should be designed for optimal Hz production, especially at high glucose concentrations, such as by blocking the carbon flux via lactate dehydrogenase from the pyruvate node.

Thermocontrol of Solute Permeation across Polymer Memberane Composed of Poly(N, N-dimethylaminoethyl methacrylate) and Its Copolymers

  • Yuk, Soon-Hon;Cho, Sun-Hang
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제6권4호
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    • pp.274-278
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    • 2001
  • Polymer membranes composed of N, N-dimethylaminoethyl methaccrylate(DMAEMA) and acrylamide(AAm)(or ethyl acrylamide(EAAm) were prepared to demonstrated the thermo-control of solute permeation. Poly DMEMA has a lower critical solution temperature(LCST) at around 50$\^{C}$ in water, With the copolymerization of DMAEMA with AAm (or EAAm) a shift in the LCST to a lowere temperature was observed, probably due to the formation of hydrogen bonds between the amide and N-N-dimethylamino groups. However, the temperature-induced phase transition of poly(DMAEMA-co-EAAm) did not show a similar trend to that of poly(DMAEMA- co-AAm) in the gel state. The hydrogen bonds in poly(DMAEMA-co-EAAm) were significantly disrupted with the formation a gel network, which led to a difference in the swilling behavior of polymer gels in response to temperature. To apply these polymers to temperature-sensitive sol-ute permeation, polymer membranes were prepared. The permeation pattern of hydrocortisone, used as the model solute, was explained based on the temperature-sensitive swelling behavior of the polymer membranes.

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Microwave-assisted Preparation, Structures, and Photoluminescent Properties of [Ln(NO3)2(H2O)3(L)2](NO3)(H2O) {Ln=Tb, Eu;L=2-(4-pyridylium)ethanesulfonate, (4-pyH)+-CH2CH2-SO3-}

  • Zheng, Zhen Nu;Lee, Soon-W.
    • Bulletin of the Korean Chemical Society
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    • 제32권6호
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    • pp.1859-1864
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    • 2011
  • Two lanthanide complexes, $[Ln(NO_3)_2(H_2O)_3(L)_2](NO_3)(H_2O)$ {Ln = Eu (1), Tb (2); L = 2-(4-pyridylium)-ethanesulfonate, $(4-pyH)^+-CH_2CH_2-SO_3^-)$}, were prepared from lanthanide nitrate and 4-pyridineethanesulfonic acid in $H_2O$ under microwave-heating conditions. Complexes 1 and 2 are isostructural, and the lanthanide metal in both complexes is coordinated to nine oxygen atoms. The pyridyl nitrogen in the ligand is protonated to give a zwitter ion that possesses an $NH^+$ (pyridyl) positive end and an $SO_3^-$ negative end. All O-H and N-H hydrogen atoms participate in hydrogen bonds to generate a two-dimensional (complex 1) or a three-dimensional network (complex 2). Complex 1 exhibits an intense red emission, whereas complex 2 exhibits an intense green emission in the solid state at room temperature.

Self-assembly and Mechanism of L-Alanine-based Dihydrazide Derivative as Excellent Gelator of Organic Solvents

  • Wang, Chuan-Sheng;Wang, Xiao-Hong;Li, Zhi-Yuan;Wei, Wei;Shi, Zhong-Liang;Sui, Zhi-Tong
    • Bulletin of the Korean Chemical Society
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    • 제32권4호
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    • pp.1258-1262
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    • 2011
  • A new organogelator, L-Alanine dihydrazide derivative can self-assemble in various organic solvents and turned them into thermally reversible physical supramolecular organogels at extremely low concentrations (< 2 wt %). The gel-sol phase transition temperatures ($T_{GS}$) were determined as a function of gelator concentration and the corresponding enthalpies (${\Delta}H_g$) were extracted. Scanning electron microscopy (SEM) measurements revealed that the interspaces of fiber-like network structures were diminished with the increasing of the LMOG concentration. FT-IR spectroscopy studies revealed that hydrogen-bonding and hydrophobic interaction were the driving forces for the formation of the gels. Based on the data of XRD and molecular modeling, the possible packing modes for the formation of organogelator aggregates were proposed.

Molecular Design for the Formation of Two-dimensional Molecular Networks: STM Study of ${\gamma}$-phenylalanine on Au(111)

  • Jeon, A-Ram;Youn, Young-Sang;Lee, Hee-Seung;Kim, Se-Hun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.205-205
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    • 2011
  • The self-assembly of ${\gamma}$-phenylalanine on Au(111) at 150 K was investigated using scanning tunneling microscopy (STM). Phenylalanine can potentially form two-dimensional (2D) molecular networks through hydrogen bonding (through the carboxyl and amino groups) and ${\pi}-{\pi}$ stacking interactions (via aromatic rings). We found that ${\gamma}$-phenylalanine molecules self-assembled on Au(111) surfaces into well-ordered structures such as ring-shaped clusters (at low and intermediate coverages) and 2D molecular domains (intermediate and monolayer coverages), whereas ${\alpha}$-phenylalanine molecules formed less-ordered structure on Au(111). The self-assembly of ${\gamma}$- but not ${\alpha}$-phenylalanine may be related to the flexibility of the carboxyl and amino groups in the molecule. Moreover, as expected, the 2D molecular network of ${\gamma}$-phenylalanine on Au(111) was mediated by a combination of hydrogen bonding and ${\pi}-{\pi}$ stacking interactions.

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수소 결합에 의한 사차원의 Copper(II) 거대고리 착물의 결정구조 (Crystal Structure of Three-Dimensional Copper(II) Macrocyclic Complex Linked by Hydrogen-Bonds)

  • Park, Ki-Young;Hong, Choon-Pyo;Lee, Hye-Ok;Choo, Geum-Hong;Suh, Il-Hwan;Kim, Jin-Gyu;Park, Young-Soo
    • 한국결정학회지
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    • 제11권2호
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    • pp.75-79
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    • 2000
  • The complex [Cu(L)(H2O)2] (PDC)(1)(L=2,5,9,12-tetramethyl-1,4,8,11- tetraazacyclotetradecane;PDC=1,4-pyridinedicarboxylate) has been synthesized and characterized by X-ray crys-tallography. The compound 1 crystallizes in the triclinic space group P1, with a=7.553(1)Å, b=9.619(2)Å, c=10.692(2)Å, α=74.22(1)°, β=73.32(1)°, γ=78.70(1)°, V=710.1(2)Å3, Z=1,R1(wR2) for 2634 observed reflections of [I>2σ(I)] was 0.0854(0.2242). The compound 1 is interconnected to give a three-dimensional network through weak hydrogen-bonding interactions.

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Sol-Gel Transition in Di-(2-ethylhexyl) phthalate-Plasticized Poly(vinyl chloride)

  • Lee, Chang-Hyung;Nah, Jae-Woon;Cho, Kil-Won;Kim, Seong-Hun;Hahn, Ai-Ran
    • Bulletin of the Korean Chemical Society
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    • 제24권10호
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    • pp.1485-1489
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    • 2003
  • The gelation for di-(2-ethylhexyl) phthalate (DEHP)-plasticized poly(vinyl chloride) was studied by measuring time-resolved small-angle X-ray scattering (SAXS) and a flow of the solutions in test tube. It was found that for the gelation there were three regimes. At Regime I, the solution rapidly changed to a gel, and the SAXS intensity showed a peak and the peak intensity increased, keeping the peak angle constant. Applying the SAXS intensity to the kinetic analysis of the liquid-liquid phase separation, it was revealed that the spinodal decomposition proceeded to develop a periodic length of 29.9 nanometer in size, a hydrogen-bonding-type association in polymer rich phase followed, and then it induced fast gelation rate. At Regime II, the gelation slowly occurred and the SAXS intensity was not observed, suggesting that a homogeneous gel network was formed by a hydrogen-bonding. At regime III, the solution was a homogeneous sol.

수소 결합에 의한 이차원의 Nickel(II) Tetraaza 거대 고리 착물 결합구조 (Crystal Structure of Three-Dimensional Nickel(II) Tetraaza Macrocyclic Complex Linked by Hydrogen-Bonds)

  • Park, Ki-Young;Choo, Geum-Hong;Suh, Il-Hwan
    • 한국결정학회지
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    • 제13권1호
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    • pp.12-16
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    • 2002
  • [Ni(L)](BDC)·4H₂O (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[16,4,O/sup 1.18/,O/sup 7.12/]docosane;BDC = 1,3-benzenedicarboxylate) 착물을 합성하고 구조를 규명하였다. 이 착물은 사방정계, 공간군 Pcnb, a = 8.764(2) , b = 17.687(2) , c = 19.475(1) , V = 3018.7(8) ³, Z = 4로 결정화 되었다. 이 착물의 구조는 최소자승법으로 정밀화하였으며, 최종 신뢰도 R₁(wR₂)값은 2148개의 회절반점에 대하여 0.0822 및 0.2236이었다. 화합물 1은 수소결합들로 연결된 삼차원의 그물 구조를 갖는다.