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Crystal Structure of Three-Dimensional Nickel(II) Tetraaza Macrocyclic Complex Linked by Hydrogen-Bonds  

Park, Ki-Young (Department of Cultural Heritage Conservation Science, Kongju National University, Kongju 314-701)
Choo, Geum-Hong (Department of Physics, Chungnam National University, Taejon 305-764)
Suh, Il-Hwan (Department of Physics, Chungnam National University, Taejon 305-764)
Publication Information
Korean Journal of Crystallography / v.13, no.1, 2002 , pp. 12-16 More about this Journal
Abstract
The complex [Ni(L)](BDC)·4H₂O (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[16,4,O/sup 1.18/,O/sup 7.12/] docosane; BDC = 1,3-benzenedicarboxylate) has been synthesized and characterized by X-ray crystallography. Compound 1 crystallizes in the orthorhombic space group Pcnb, with a = 8.764(2) , b = 17.687(2) , c = 19.475(1) , V = 3018.7(8) ³, Z = 4, R₁, (wR₂) for 2148 observed reflections of [1>2σ(I) was 0.0822 (0.2236). Compound 1 is interconnected to give a three-dimensional network through weak hydrogen-bonding interactions.
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