• 한국수소및신에너지학회논문집
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• 제25권2호
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• pp.161-172
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• 2014

Hydrogen, which can be produced from abundant and widely distributed renewable energy resources, seems to be a promising candidate for solving the concerns for improving energy security, urban air pollution, and reducing greenhouse gas emissions. The two primary motivating factors for hydrogen economy are fossil fuel supply limitations and concerns about global warming. But the safety issues associated with hydrogen economy need to be investigated and fully understood before being considered as a future energy source. Limited operating experience with hydrogen energy systems in consumer environments is recognised as a significant barrier to the implementation of hydrogen economy. To prevent unnecessary restrictions on emerging codes, standards and local regulations, safety policies based on real hazards should be developed. This article studies briefly the direct impact-distances from hazard events such as hydrogen release and jet fire, and damage levels from hydrogen gas explosion in a confined space. Based on the direct impact-distances indicated in the accident scenarios and consumer environments in Korea, the safety policies, which are related to hydrogen filling station, hydrogen fuel cell car, portable fuel cell, domestic fuel cells, and hydrogen town, are suggested to implement hydrogen economy. To apply the safety policies and overcome the disadvantages of prescriptive risk management, which is setting guidance in great detail to management well known risk but is not covering unidentified risk, hybrid risk management model is also proposed.

• Corrosion Science and Technology
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• 제4권6호
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• pp.236-241
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• 2005

Hydrogen induced cracking (HIC) is one of the hydrogen degradation phenomena of linepipe steels caused by $H_2S$ gas in the crude oil or natural gas. However, NACE TM0284-96 standard HIC test method is hard to satisfy the steel requirements for sour service application since it uses more severe environmental conditions than actual conditions. Therefore, in order to use steels effectively, it is required to evaluate HIC resistance of steels in the practical range of environmental severity. In this study, HIC resistance of two high strength low alloy (HSLA) steels being used as line pipe steels was evaluated in various test solutions with different $H_2S$ pressures and pH values. The results showed that the key parameter affecting crack area ratio (CAR) is $H_2S$ partial pressure of test solution when the pH value of test solution is not over 4. Hydrogen diffusivity was not a constant value, but it was rather affected by the hydrogen ion concentration (pH value) in the solution.

• 한국수소및신에너지학회논문집
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• 제20권1호
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• pp.9-21
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• 2009

As one of the alternative solution for energy and environmental issues such as climate change, energy security, oil price, etc., hydrogen energy has been getting so much attentions these days. This paper analyzed the $CO_2$ emission, costs, and energy consumptions when the hydrogen energy was introduced to transportation, specifically in Sedan sector using the energy system model, MARKAL. As results, 21.5% of $CO_2$ emission in 2040 could be reduced and additional 76 billion dollars will be needed in the high energy price scenario. The amount of energy saving mainly due to the replacement of existing car to hydrogen vehicle was 16% of the final energy consumption in 2040.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.553-557
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• 2013

The stretching vibration of OH of ice Ih is studied by Car-Parrinello molecular dynamics in regarding the effect of mixed H/D contamination while the vibrational spectrum is considered by velocity-velocity autocorrelations of the sampled ensemble. When hydrogen atoms are immersed randomly into the deuterated ice, a typical vibrational frequency of OH stretching mode is observed to be similar to that from the pure $H_2O$ ice. When focusing on the correlation of isolated neighboring OH stretching, a narrower and blue shifted peak is observed at the high frequency range as a result of the screening from the complex many body correlations by $D_2O$ environment. It is also specifically related to the symmetric intermolecular correlations between neighboring OH stretching modes. More enhanced high frequency range can be explained by the expansion of such two body correlations to collective many body correlations among all possible OH stretching modes. This contribution becomes important when it involves in chemical interactions via excitation of such vibrational states.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.152.1-152.1
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• 2011

This study analyzes transitions to a green path in transportation system in South Korea. We develop transportation system model with four new technology options, green cars; Hybrid electric vehicle, plug-in hybrid vehicle, electric vehicle and fuel cell vehicle. Among those technologies fuel cell vehicle is the best option assuming no GHG emissions when driving. We use MESSAGE model to get an optimal solution of pathway for high deployment of fuel cell vehicles under the Korea BAU transportation model. Among hydrogen production sources, off gas hydrogen is most economic since it is hardly used to other chemical sources or emits in South Korea. According to off gas hydrogen projection it can run 1.8 million fuel cell vehicles in 2040 which corresponds to 10% of all passenger cars expected in Korea in 2040. However, there are concerns associated with technology maturity, cost uncertainty which has contradictions. But clean pathway with off gas and renewable sources may provide a strong driving force for energy transition in transportation in South Korea.

• 한국수소및신에너지학회논문집
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• 제29권5호
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• pp.497-502
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• 2018

In Korea, passenger car and van using LPG fuel including taxi constantly increased due to the high cost of fuel. Recently, the emission standard has continuously tightened in the world. In this investigation was conducted the greenhouse gas emission characteristics of LPG vehicles according to the displacement and weight. Exhaust emission characteristics of 13 test LPG vehicles from about 1.0 L to 3.0 L displacements were measured and analyzed by using chassis dynamometer and emission analyzer. It is revealed that the greenhouse gas emission was showed the increasing tendency as the displacement and curb weight increased. Also, greenhouse gas emission of SC03 driving cycle has highest value and that of HWFET driving cycle shows the lowest value.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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• pp.245-246
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• 2012

The possibility that self-ignition can be generated near an obstacle is high in practical applications such as a hydrogen car. In this paper, experimental investigations were suggested to understand the effects of a wall on self-ignition phenomena through high-speed images. The results showed that the existence of a wall could not change the ignition phenomena itself irrespective of wall height and burst pressure. However, when a strong flame was induced in the tube, a wall could promote the flame stabilization.

• 한국가스학회지
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• 제25권6호
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• pp.85-91
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• 2021

정부는 2019년 1월 세계 최고 수준의 수소경제 선도국가로 도약하기 위해 「수소경제 활성화 로드맵」을 발표했으며, 우리나라가 강점이 있는 수소자동차와 연료전지를 양대 축으로 수소경제를 선도할 수 있는 산업생태계 구축 전략을 세웠다. 그 일환으로 2022년 310개소, 2040년 1,200개소의 수소충전소 보급목표를 수립하였다. 이에 발맞춰 2021년 2월 한국가스안전공사는 속도감 있는 수소충전소 구축을 위해 시공단계에서 안전기준에 따른 다양한 현장 문제 발생으로 인한 시공지연을 사전해소하기 위한 수소충전소 사전컨설팅 제도를 운영하게 된다. 본 논문은 사전컨설팅 제도에 대해 알아보고 그 효과를 분석하고자 한다.

• 한국수소및신에너지학회논문집
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• 제27권4호
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• pp.357-364
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• 2016

Recently, the world faces the environmental problem such as air pollution due to harmful gas discharged from car and abnormal climate due to the green-house gases increased by the discharge of $CO_2$. Compressed Natural Gas (CNG), one of alternative for this problem, is less harmful, compared to the existing fossil fuel, as gaseous fuel, and less carbon in fuel ingredients and carbon dioxide generation rate relatively favorable more than the existing fuel. However, CNG fuel has the weakness of slow flame propagation speed and difficult fast burn. On the other hand, hydrogen does not include carbon in fuel ingredients, and does not discharge harmful gas such as CO and HC. Moreover, it has strength of quick burning velocity and ignition is possible with small ignition energy source and it's has wide Lean Flammability Limit. If using this hydrogen with CNG fuel, the characteristics of output and discharge gas is improved by the mixer's burning velocity improved, and, at the same time, is possible to have stable lean combustion with the reduction of $CO_2$ expected. Therefore, this research tries to identify the characteristics of engine and emission gas when mixing CNG fuel and hydrogen in each portion and burning them in spark igniting engine, and grasp the combustion stability and emission gas characteristics according and use it as the basic data of hydrogen-CNG premixed engine.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.174-180
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• 2017

Recently, the world faces the environmental problem such as air pollution due to harmful gas discharged from car and abnormal climate due to the green-house gases increased by the discharge of $CO_2$. Compressed Natural Gas (CNG), one of alternative for this problem, is less harmful, compared to the existing fossil fuel, as gaseous fuel, and less carbon in fuel ingredients and carbon dioxide generation rate relatively favorable more than the existing fuel. However, CNG fuel has the weakness of slow flame propagation speed and difficult fast burn. On the other hand, hydrogen does not include carbon in fuel ingredients, and does not discharge harmful gas such as CO and HC. Moreover, it has strength of quick burning velocity and ignition is possible with small ignition energy source and it's has wide Lean Flammability Limit. If using this hydrogen with CNG fuel, the characteristics of output and discharge gas is improved by the mixer's burning velocity improved, and, at the same time, is possible to have stable lean combustion with the reduction of $CO_2$ expected. Therefore, this research tries to identify the characteristics of engine and emission gas when mixing CNG fuel and hydrogen in each portion and burning them in spark igniting engine, and grasp the lean combustion limit and emission gas characteristics according and use it as the basic data of hydrogen-CNG premixed engine.