• Title/Summary/Keyword: Hydrogen CFD

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A Numerical Study of Cathode Block and Air Flow Rate Effect on PEMFC Performance (고분자전해질 연료전지의 환원극 블록과 공기 유량 영향에 대한 전산 해석 연구)

  • Jo, Seonghun;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.96-102
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    • 2022
  • Reactants of PEMFC are hydrogen and oxygen in gas phases and fuel cell overpotential could be reduced when reactants are smoothly transported. Numerous studies to modify cathode flow field design have been conducted because oxygen mass transfer in high current density region is dominant voltage loss factor. Among those cathode flow field designs, a block in flow field is used to forced supply reactant gas to porous gas diffusion layer. In this study, the block was installed on a simple fuel cell model. Using computational fluid dynamics (CFD), effects of forced convection due to blocks on a polarization curve and local current density contour were studied when different air flow rates were supplied. The high current density could be achieved even with low air supply rate due to forced convection to a gas diffusion layer and also with multiple blocks in series compared to a single block due to an increase of forced convection effect.

A Numerical Study on Mass Transfer and Methanol Conversion Efficiency According to Porosity and Temperature Change of Curved Channel Methanol-Steam Reformer (곡유로 메탄올-수증기 개질기 공극률 및 온도 변화에 따른 물질 전달 및 메탄올 전환율에 대한 수치해석적 연구)

  • Seong, Hong Seok;Lee, Chung Ho;Suh, Jeong Se
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.11
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    • pp.745-753
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    • 2016
  • Micro methanol-steam reformer for fuel cell can effectively produce hydrogen as reforming response to steam takes place in low temperature (less than $250^{\circ}C$). This study conducted numerical research on this reformer. First, study set wall temperature of the reformer at 100, 140, 180 and $220^{\circ}C$ while methanol conversion efficiency was set in 0, 0.072, 3.83 and 46.51% respectively. Then, porosity of catalyst was set in 0.1, 0.35, 0.6 and 0.85 and although there was no significant difference in methanol conversion efficiency, values of pressure drop were 4645.97, 59.50, 5.12 and 0.45 kPa respectively. This study verified that methanol-steam reformer rarely responds under the temperature of $180^{\circ}C$ and porosity does not have much effect on methanol conversion efficiency if the fluid flowing through reformer lowers activation energy by sufficiently contacting reformer.

Preliminary Study on Factor Technology of Selective Catalytic Reduction System in Marine Diesel Engine (선박용 디젤엔진 SCR 시스템 요소 기술에 관한 기초 연구)

  • Park, Yoon-Yong;Song, Ha-Cheol;Ahn, Gi-Ju;Shim, Chun-Sik
    • Journal of Navigation and Port Research
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    • v.40 no.4
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    • pp.173-181
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    • 2016
  • From 2016, controls on reduction of NOx and SOx emissions from the vessels that are operated in the emission control area were tightened. The selectivity catalytic reduction system of the denitrification equipment which NOx among the above controlled materials is very effective and used commercially very much. But it has the disadvantage that CSR is activated at high temperatures. Therefore, the SCR and SCR activation instrument that can react even at low temperatures by using micro-nano bubbles so that the above problems can be minimized were developed. And the computational fluid dynamics technique was used by ANSYS-CFX package to prepare the plan that improves the SCR system's efficiency. Simulation for the viscous flow analysis of the SCR system was executed by applying the Navier-Stokes equation to it as a governing equation. For the SCR system's shape, 3D modeling was done by using CATIA V5. SCR jet nozzle's position was checked by changing it to the intervals of 1/3, 1/2, and 2/3 from the inlet of the vent pipe to compare the SCR system's efficiency. And the number of nozzles was compared and analyzed by simulating 4, 6, and 8 holes to check an effect of the number on the SCR system's efficiency. The simulation result has found that the closer nozzles are to the inlet of the vent pipe and the more nozzles are, the more efficiency is improved.

Numerical simulation of gasification of coal-water slurry for production of synthesis gas in a two stage entrained gasifier (2단 분류층 가스화기에서 합성가스 생성을 위한 석탄 슬러리 가스화에 대한 수치 해석적 연구)

  • Seo, Dong-Kyun;Lee, Sun-Ki;Song, Soon-Ho;Hwang, Jung-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.417-423
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    • 2007
  • Oxy-gasification or oxygen-blown gasification, enables a clean and efficient use of coal and opens a promising way to CO2 capture. The coal gasification process of a slurry feed type, entrained-flow coal gasifier was numerically predicted in this paper. The purposes of this study are to develop an evaluation technique for design and performance optimization of coal gasifiers using a numerical simulation technique, and to confirm the validity of the model. By dividing the complicated coal gasification process into several simplified stages such as slurry evaporation, coal devolatilization, mixture fraction model and two-phase reactions coupled with turbulent flow and two-phase heat transfer, a comprehensive numerical model was constructed to simulate the coal gasification process. The influence of turbulence on the gas properties was taken into account by the PDF (Probability Density Function) model. A numerical simulation with the coal gasification model is performed on the Conoco-Philips type gasifier for IGCC plant. Gas temperature distribution and product gas composition are also presented. Numerical computations were performed to assess the effect of variation in oxygen to coal ratio and steam to coal ratio on reactive flow field. The concentration of major products, CO and H2 were calculated with varying oxygen to coal ratio (0.2-1.5) and steam to coal ratio(0.3-0.7). To verify the validity of predictions, predicted values of CO and H2 concentrations at the exit of the gasifier were compared with previous work of the same geometry and operating points. Predictions showed that the CO and H2 concentration increased gradually to its maximum value with increasing oxygen-coal and hydrogen-coal ratio and decreased. When the oxygen-coal ratio was between 0.8 and 1.2, and the steam-coal ratio was between 0.4 and 0.5, high values of CO and H2 were obtained. This study also deals with the comparison of CFD (Computational Flow Dynamics) and STATNJAN results which consider the objective gasifier as chemical equilibrium to know the effect of flow on objective gasifier compared to equilibrium. This study makes objective gasifier divided into a few ranges to study the evolution of the gasification locally. By this method, we can find that there are characteristics in the each scope divided.

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Study on Methanol Conversion Efficiency of Steam-Methanol Reforming on Pipe Shape and Flow Rate Variation in Curved Channel (수증기-메탄올 개질기의 곡유로 채널형 관 형태 변화에 따른 메탄올 전환율 및 유동 특성에 관한 수치해석적 연구)

  • Seong, Hong Seok;Lee, Chung Ho;Suh, Jeong Se
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.3
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    • pp.173-179
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    • 2016
  • This is a numerical study on the curved channel type of hydrogen reformer using the commercial code of fluid dynamics. We numerically compared the numerical model in a previous study model and the modelling of a tube type curved channel. In the result of numerical analysis on 4 types of curved channel reformers, the methanol conversion efficiency of type 1~4 were 45.0%, 45.3%, 45.6%, 45.6% respectively, and there was hardly any difference by ${\pm}0.6%$. In light of flow characteristics, the rectangle type tube and the type 2 with $45^{\circ}$ turn showed most uniform flow characteristics and concentration distribution of methanol, and the circular type tube and the type 3 with $90^{\circ}$ turn had most un-uniform flow characteristics and concentration distribution of methanol. We concluded that the design for curved channel reformer has to have rectangle type tube with curve of almost $45^{\circ}$ as in the type of curved pipe with $45^{\circ}$ turn.