• 제목/요약/키워드: Hydrofluoric Acid

검색결과 200건 처리시간 0.026초

Acid Texturing에 의한 태양전지용 다결정 실리콘 기판의 표면 반사율 감소 (Surface Reflectance Reduction of Multicrystalline Silicon Wafers for Solar Cells by Acid Texturing)

  • 김지선;김범호;이수홍
    • 한국전기전자재료학회논문지
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    • 제21권2호
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    • pp.99-103
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    • 2008
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controlling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400 nm to 1000 nm) reflectance with acid texturing is 4.64 % less than alkali texturing.

Acid Texturing에 의한 다결정 실리콘 태양전지의 표면 반사율 감소에 대한 연구 (Investigation of Surface Reflectance Reduction for Multicrystalline Silicon Solar Cells with Acid Texturing)

  • 김지선;김범호;이은주;이수홍
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.16-17
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    • 2007
  • To improve efficiency of solar cells, it is important to make a light trapping structure to reduce surface reflectance for increasing absorption of sun light within the solar cells. One of the promising methods that can reduce surface reflectance is isotropic texturing with acid solution based on hydrofluoric acid(HF), nitric acid($HNO_3$), and organic additives. Anisotropic texturing with alkali solution is not suitable for multicrystalline silicon wafers because of its different grain orientation. Isotropic texturing with acid solution can uniformly etch multicrystalline silicon wafers unrelated with grain orientation, so we can get low surface reflectance. In this paper, the acid texturing solution is made up of only HF and $HNO_3$ for easy controling the concentration and low cost compared to acid solution with organic additives. $HNO_3$ concentration and dipping time were varied to find the condition of minimum surface reflectance. Textured surfaces were observed Scanning Electron Microscope(SEM) and surface reflectance were measured. The best result of arithmetic mean(wavelength from 400nm to 1000nm) reflectance with acid texturing is 4.64% less than alkali texturing.

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Effect of Pre-treatments on the Content of Heavy Metals in Packaging Paper

  • Jo, Byoung-Muk;Jeong, Myung-Joon
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.465-469
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    • 2006
  • Pre-treatment methods to determine various heavy metal contents in packaging papers were investigated by ICP-ES (Inductively Coupled Plasma Emission Spectrometry) analysis. Pre-treatment methods utilized in this study include dry ashing and decomposition methods ($HNO_{3-}HClO_{4-}HF,\;HNO_{3},\;and\;H_{2}SO_{4-}HNO_{3}$). They were compared with the conventional extraction (water) and migration (3% acetic acid) methods. The five representative heavy metals (Cd, As, Pb, Cr and Hg) were analyzed. For Cd, Hg, and As, the results were below detection limit of the instrument. In case of Cr and Pb, the migration test is considered to be a better method compared to the extraction test, but all pretreated methods showed much higher detection efficiency than the extraction or migration test. However, the detection ratio between the migration test and decomposition methods was different. Among all decomposition methods, the nitric acid - perchloric acid - hydrofluoric acid treatment brought a slightly higher detection value than others, but there was no significant difference among them except sulfuric acid - nitric acid method. Concerning Pb, the sulfuric acid - nitric acid method showed a low detection efficiency compared to other decomposition methods. The sulfuric acid - nitric acid method is, thus, not considered to be a suitable analysis method for Pb in packaging papers.

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다공질 실리콘의 형성과 특성에 관한 연구 (A Study on the Formation and Properties of Porous Silicon)

  • 성영권;최복길;김상영
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 전기.전자공학 학술대회 논문집
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    • pp.781-784
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    • 1988
  • The formation and properties of porous silicon layer(PSL) formed by anodic reaction in hydrofluoric acid solution have been studied. Many micropores are formed randomly inside of PSL and the anodization is achieved uniformly-toward the thickness direction. Current density, resistivity and HF concentration in P-type PSL formation are found to play important roles in determining the formation and properties of PSL.

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Study on Thickness of Porous Silicon Layer According to the Various Anodization Times

  • 장승현
    • 통합자연과학논문집
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    • 제3권4호
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    • pp.206-209
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    • 2010
  • As the etching time is varied, the change of thickness of the porous silicon layers was successfully investigated. The thickness of the PSi layer as a function of anodization time for a p-type substrate that is etched at a constant current density of 50 $mA/cm^2$ in a 35% hydrofluoric acid solution shows a linear relationship between the etching time and the thickness of the PSi layer.

Acid solution을 이용한 다결정 실리콘 기판의 등방성 에칭에 관한 연구 (Investigation of Isotropic Etching of Multicrystalline Silicon Wafers with Acid solution)

  • 김지선;김범호;이수홍
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.70-71
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    • 2007
  • Multicrystalline silicon(mc-Si) solar cells are steadily increasing their share of the PV market due to the lower material costs. However, commercial mc-Si solar cells have lower efficiency than singlecrystalline silicon solar cells. To improve efficiency of mc-Si solar cells, it is important to reduce optical losses from front surface reflection. Isotropic etching with acid solution based on hydrofluoric acid(HF) and nitric acid$(HNO_3)$ is one of the promising methods that can reduce surface reflectance for mc-Si solar cells. Anisotropic etching is not suitable for mc-Si because of its various grain orientations. In this paper, we isotropically etched mc-Si using acid solution. After that, etched surface was observed by Scanning Electron Microscope(SEM) and surface reflectance was measured. We obtained 29.29% surface reflectance by isotropic etching with acid solution in wavelength from 400nm to 1000nm for fabrication of mc-Si solar cells.

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Quantitative Analysis of Heavy Metals in Packaging Papers

  • Jo, Byoung-Muk;Jeong, Myung-Joon
    • 펄프종이기술
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    • 제39권5호
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    • pp.45-51
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    • 2007
  • This study was carried out to investigate various heavy metal contents in packaging papers by pre-treatments for ICP-ES (Inductively Coupled Plasma Emission Spectrometry) analysis. Pre-treatment methods of heavy metals in this study include extraction, migration and decomposition methods (dry ashing, $HNO_3-HClO_4-HF,\;HNO_3,\;and\;H_2SO_4-HNO_3$). Test results were compared with conventional extraction (water) and migration (3% acetic acid) methods. The five representative heavy metals (Cd, As, Pb, Cr and Hg) were analyzed. For Cd, Hg, and As, the results were below detection limit of the instrumental technique. It was considered that the migration test was a better method compared to extraction test, but all the decomposition methods showed much higher detection values than the extraction or migration test. In case of recycled corrugated containers, 3% acetic acid solution extracted about 25% of chromium and 30% of lead compared to the content by decomposition methods. Among all decomposition methods, the nitric acid - perchloric acid - hydrofluoric acid treatment brought a slightly higher detection value than others, but there was no significant difference among them except sulfuric acid - nitric acid method.

지르코니아 강화 리튬 실리케이트 세라믹의 특성과 임상적용 (Material properties and clinical application of zirconia-reinforced lithium silicate ceramics)

  • 김종은;김지환;심준성;박영범
    • 대한치과의사협회지
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    • 제56권3호
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    • pp.159-166
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    • 2018
  • 지르코니아 강화 리튬 실리케이트 세라믹 재료는, 현재 널리 사용되고 있는 e.max(리튬디실리케이트 세라믹) 재료에 비하여 더 개선된 강도를 지니고 있다. 단일 크라운의 수복에 사용될 수 있으며, 1.5mm 의 두께를 확보하는 것이 예지성 있는 치료를 위해 매우 중요하다. Celtra Duo의 경우 열처리를 수행하는 것이 강도나 마모 저항성 측면에서 도움이 될 것이다. 접착을 위해서는 불산의 처리가 도움이 되며, 너무 짧은 시간의 불산은 접착 강도의 개선에 도움을 주지 못할 수 있으므로 충분한 시간의 불산 처리가 필요하다. 지르코니아 강화 리튬 실리케이트 세라믹 재료는 실험실 연구가 지속적으로 수행되고 출판되고 있지만, 아직 신뢰할만한 임상연구는 매우 부족한 실정이다. 추가적인 임상연구를 통해 과학적인 근거를 마련하는 것이 매우 중요한 부분이 될 것이다.

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화학사고 피해영향 범위의 합리적 산정방안에 대한 연구 (A Study on the Reasonable Estimation of Consequence of Chemical Release)

  • 조규선;임준택;한정우;백은성;유원종;박교식
    • 한국가스학회지
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    • 제24권5호
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    • pp.20-28
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    • 2020
  • 불산 누출사고 발생 시 피해영향범위 예측을 수계산, 영향평가 시뮬레이션, CFD 시뮬레이션을 활용하여서 예측하고 실제 환경영향보고서와 비교·분석하였다. 수계산은 누출원모델과 확산모델을 활용하여서 계산하였으며 영향평가 시뮬레이션은 우리나라 환경부에서 제공하는 KORA, 미국 환경부의 ALOHA, 상용화 프로그램 중 비교적 널리 사용 중인 PHAST를 사용하였고, CFD 시뮬레이션은 STAR-CMM+ 프로그램을 활용하였다. 사용자 입장에서 편리성, 신속성, 수용성, 경제성 등을 고려할 때 불산 누출사고 영향예측에 가장 적절하게 사용할 수 있는 프로그램은 ALOHA와 KORA 이었다. 아울러, 본 연구결과는 정부의 정책개발과 기업의 안전부서에서 피해영향범위 프레임워크를 선정하고 불필요한 규제, 불필요한 안전투자를 최적화하여 정부 또는 기업의 제한된 자원을 효율적으로 활용하는 데 도움이 될 것으로 기대된다.

Surface treatment of feldspathic porcelain: scanning electron microscopy analysis

  • Valian, Azam;Moravej-Salehi, Elham
    • The Journal of Advanced Prosthodontics
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    • 제6권5호
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    • pp.387-394
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    • 2014
  • PURPOSE. Topographic analysis of treated ceramics provides qualitative information regarding the surface texture affecting the micromechanical retention and locking of resin-ceramics. This study aims to compare the surface microstructure following different surface treatments of feldspathic porcelain. MATERIALS AND METHODS. This in-vitro study was conducted on 72 porcelain discs randomly divided into 12 groups (n=6). In 9 groups, feldspathic surfaces were subjected to sandblasting at 2, 3 or 4 bar pressure for 5, 10 or 15 seconds with $50{\mu}m$ alumina particles at a 5 mm distance. In group 10, 9.5% hydrofluoric acid (HF) gel was applied for 120 seconds. In group 11, specimens were sandblasted at 3 bar pressure for 10 seconds and then conditioned with HF. In group 12, specimens were first treated with HF and then sandblasted at 3 bar pressure for 10 seconds. All specimens were then evaluated under scanning electron microscopy (SEM) at different magnifications. RESULTS. SEM images of HF treated specimens revealed deep porosities of variable sizes; whereas, the sandblasted surfaces were more homogenous and had sharper peaks. Increasing the pressure and duration of sandblasting increased the surface roughness. SEM images of the two combined techniques showed that in group 11 (sandblasted first), HF caused deeper porosities; whereas in group 12 (treated with HF first) sandblasting caused irregularities with less homogeneity. CONCLUSION. All surface treatments increased the surface area and caused porous surfaces. In groups subjected to HF, the porosities were deeper than those in sandblasted only groups.