• Title/Summary/Keyword: Hydrochloric acid

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Effect of Hydrochloric Acid, Sulfuric Acid and Enzymes on the Hydrolysis of Marine Products. (1) Effect of hydrochloric acid on the hydrolysis of dried cuttlefish, sardine, shrimp, sea mussel and undaria (水産物의 鹽酸, 黃酸, 酵素에 依한 加水分解에 關한 硏究 (第一報) 鹽酸에 依한 加水分解)

  • Lee, Sang-Tai;Song, Ki-Moo
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.85-87
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    • 1957
  • We have studied on the effect of hydrochloric acid on the hydrolysis of dried cuttlefish, sardine, shrimp, sea mussel and undaria taking various concentration of acid, heating at various periods at constant temperatures and under atmospheric pressure following results were obtained. 1. The addition of HCl increases hydrolysis ratio of marine products rapidly, having maximum point of its ratio at 30% of dried cuttlefish and shrimp, at 25% of sea mussel and undaria, at 15% of sardine. 2. Hydrolysis ratios of cuttlefish and shirmp, sea mussel and undaria, and sardine reach maximum values at 30% of HCl, 25% of HCl and 15% of HCl, respectively.

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Acid Pickling Characteristics of Stainless Steel by the Mixed Solution of Hydrochloric acid, Hydrofluoric acid and Hydrogen Peroxide (염산-불산-과산화수소 혼합용액에 의한 스테인레스강의 산세 특성)

  • Chun, Heedong;Choi, SangGyo
    • Clean Technology
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    • v.11 no.1
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    • pp.21-28
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    • 2005
  • Nitric acid free pickling solution was applied to solve the severe environmental problems attributed to nitric acid during pickling process of stainless steel product. In points of pickling capability and erosion of stainless steel base metal, a solution contains I% of hydrochloric acid and 2% of hydrofluoric acid and hydrogen peroxide was revealed as the best alternative to conventional mixed acid of nitric acid and hydrofluoric acid. To keep the pickling capability, it was necessary to maintain the concentration ratio of hydrogen peroxide to hydrochloric acid above 0.5.

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Dielectric Characteristics of Alumina by Surface Etching Effects (표면에칭효과에 의한 산화알루미늄 유전체의 정전용량 특성)

  • Oh Han-Jun;Park Chi-Sun
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.4 s.33
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    • pp.61-67
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    • 2004
  • The structural, electrical properties of the electrolytic capacitors were examined. By the addition of additives to hydrochloric acid solution increased the dielectric aluminum surface layer. For etch tunnels formed in hydrochloric acid, the away and density of the tunnels was not uniform, while for those formed in hydrochloric acid with additives the distribution presented relative uniformity. When the etched surface formed in hydrochloric acid with $5\%$ ethylene glycol, the enlargement of specific surface area was more effective.

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Development of a Concentration Measurement System for Pickling Line Control (산세라인 자동화를 위한 농도 측정 시스템 개발)

  • Park, Hyoung-Kuk;Lee, Jong-Hyun;Noh, Ill-Hwan
    • Journal of Institute of Control, Robotics and Systems
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    • v.19 no.10
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    • pp.891-895
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    • 2013
  • This paper proposes the development of a new method for online analysis which measured acid concentration in a pickling line. Pickling is the most important step to remove surface scale layers and is strongly depending on the exactly controlled pickling liquor composition. Today, there is no feasible system available for the online control of pickling lines. Within this paper, new methods for online analysis of pickling liquors have been tested and implemented into an overall pickling process control tool. This method measured simultaneously the hydrochloric acid and iron ion concentration in a solution of hydrochloric acid by measuring the ultrasonic speed, the solution temperature, and the electrical conductivity. Experimental results showed excellent precision and the measurement error was ${\pm}2g/l$ compared with the neutralization titration measurement.

Recovery of Silver Using Cyclone Type Electrolytic Cell from Thiourea-hydrochloric Acid Mixed Solutions (티오요소와 염산 혼합 용액에서 사이클론 전해에 의한 은(Ag) 회수)

  • Cho, Yeon-Chul;So, Hong-Il;Lee, Joo-eun;Ahn, Jae-Woo;Ryu, Ho-Jin
    • Resources Recycling
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    • v.26 no.4
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    • pp.62-70
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    • 2017
  • A cyclone type electrolytic method was used to recover silver from thiourea-hydrochloric acid mixed solutions. The electrowinning behavior of silver was investigated in different systems, such as the flow rate, current density, silver concentration, thiourea concentration and hydrochloric acid concentration. As the increase of the flow rate, current density and hydrochloric acid concentration, the recovery rate of silver was increased. Whereas, as the increase of silver concentration, the recovery rate of silver was decreased. The thiourea concentration did not affect the Ag recovery and current efficiency. Above 99% of Ag was recovered at the flow rate of 12 L/min., current density of $0.75A/dm^2$, silver concentration of 1.0 g/L, 0.5 M thiourea and 0.1 M hydrochloric acid. In most experimental conditions, silver was recovered as a powder form.

Studies on the Hydrolysis of ${\alpha}$-Bromophenylacetamide (${\alpha}$-Bromophenylacetamide의 가수분해 반응연구)

  • Kim In Kyu;Yoon Young Jin
    • Journal of the Korean Chemical Society
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    • v.22 no.5
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    • pp.334-339
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    • 1978
  • The hydrolysis of ${\alpha}$-bromophenylacetamide in the acidic media has been studied. The reactions in sulfuric acid and p-toluenesulfonic acid afforded mainly mandelic acid ; on the other hand, in hydrochloric acid ${\alpha}$-chlorophenylacetic acid was the main product. In either case, it was difficult to obtain ${\alpha}$-bromophenylacetic acid without concomittant formation of mandelic acid and ${\alpha}$-chlorophenylacetic acid respectively from the hydrolysis of ${\alpha}$-bromophenylacetamide. Mandelic acid and ${\alpha}$-chlorophenylacetic acid were obtained in good yields (86, 95 %) in sulfuric and hydrochloric acid respectively; the reactions are therefore potentially useful processes for obtaining them.

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Characterization of Liquefied Pine Bark Prepared from Phenol-Organic Sulfonic Acids Liquefaction. (소나무 수피 페놀-유기설폰산 액화에 의하여 제조된 액화물의 특성)

  • 문성필;로경란;이종문
    • Journal of Korea Foresty Energy
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    • v.21 no.3
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    • pp.18-27
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    • 2002
  • Pine bark was liquefied in the presence of phenol using organic sulfonic acids as catalysts, and the liquefied barks were characterized. It was found that the organic sulfonic acids were more effective catalysts than hydrochloric acid for complete liquefaction of pine bark. The liquefied barks prepared from phenol-organic sulfonic acid liquefaction were highly phenolated, and the amounts of combined phenol were 2-3 times greater than that of the liquefied bark obtained from phenol-hydrochloric acid liquefaction. The glass transition points (Tg) were lower than that of the liquefied barks prepared from phenol-hydrochloric acid. It can be concluded that by using the organic sulfonic acids, the phenol used as a liquefying reagent is highly introduced into the bark, resulting in the phenolated bark preventing further condensation reactions, which may occur during the liquefaction. The carbohydrates such as cellulose and hemicellulose in the liquefied barks were almost decomposed during the liquefaction, from the results of IR spectra and neutral sugar analyses. Energy dispersive X-ray spectromery (EDS) results from the residues and the liquefied barks showed that the organic sulfonic acid catalysts did not lead to serious corrosion of the reactor compared with the hydrochloric acid catalyst.

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Effects of γ-aminobutyric acid and hydrochloric acid on growth performance, nutrient digestibility and fecal score of growing pigs

  • Ding, Zhenyu;Kim, Inho
    • Korean Journal of Agricultural Science
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    • v.46 no.3
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    • pp.489-496
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    • 2019
  • A study was conducted to determine the effects of feeding ${\gamma}$-aminobutyric acid (GABA) and hydrochloric acid (HCl) on the growth performance, nutrient digestibility and fecal score in growing pigs. Ninety Duroc ${\times}$ (Landrace ${\times}$ Large Yorkshire) growing pigs with an average initial body weight (BW) of $25.51{\pm}1.63kg$ were randomly allotted to three treatment groups with 6 replications of 5 pigs per replicate pen for each treatment in a 6-week trial period. The treatments were as follows: 1) basal diet (CON); 2) basal diet with 0.05% GABA and 3) basal diet with 1% of a 10% HCl solution. The results showed that GABA supplementation significantly increased the average daily gain (ADG) (p < 0.05) compared with the control during week 4 and the overall experiment period (0 to 6 weeks). However, HCl supplementation had a numerical increase in the ADG compared with the control. The total tract digestibility of dry matter (DM) was greater in GABA group than the CON (p < 0.05). The supplementation of GABA and HCl in the diet of growing pigs had no significant effect on the fecal scores compared with the CON. Experimental results show that supplementation of 0.05% GABA in the diet of growing pigs had a positive effect on the ADG and DM digestibility in growing pigs.

Investigating the Efficiency of Formic Acid and Hydrochloric Acid in Weak Acid Hydrolysis for Myoglobin

  • Jihyun Paek;Hyojin Hwang;Yeoseon Kim;Dabin Lee;Jeongkwon Kim
    • Mass Spectrometry Letters
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    • v.14 no.2
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    • pp.48-55
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    • 2023
  • This study compares the efficiency of weak acid hydrolysis (WAH) using formic acid (FA) and hydrochloric acid (HCl) in the analysis of myoglobin peptides. WAH using 2% and 5% formic acid resulted in the identification of 32 peptides, with varying degrees of cleavage at the C-terminus of aspartic acid residues. HCl WAH with different concentrations demonstrated an increase in the total number of identified peptides but a decrease in fully cleaved peptides as the HCl concentration increased. Notably, deamidation was observed during HCl WAH but not in FA WAH. The addition of HCl WAH after FA WAH provided a similar pattern to HCl WAH, with slightly higher levels of hydrolysis. These findings highlight distinct cleavage patterns and deamidation effects between FA and HCl in the context of WAH.

A Case of Serious Caustic Injury after Ingestion of Hydrochloric Acid (염산으로 인한 중대한 부식성 손상 1례)

  • Park Hyun-Joo;Yi Hyeon-Gyu;Kim Pum-Soo;Roh Hyung-Keun
    • Journal of The Korean Society of Clinical Toxicology
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    • v.2 no.1
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    • pp.58-62
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    • 2004
  • Acid ingestion can cause not only caustic injury on esophagus and stomach but also fatal outcome through systemic complications. We report the case of a patient who died early after severe caustic injury with strong acid. A 38-year-old man who ingested about 400ml of hydrochloric acid of unknown concentration was transferred to our hospital from a private clinic, in which he was managed with gastric irrigation through a nasogastric tube. He was complaining dyspnea and abdominal pain. Physical examination demonstrated tenderness and rebound tenderness on epigastric region. Severe metabolic acidosis and leukocytosis were noted. Radiological findings suggested perforation of gastrointestinal tract, although the physical signs were not typical. Endoscopy revealed caustic injuries of grade I on esophagus and of grade Ⅲ on stomach, which indicate more severe injury on the stomach than on the esophagus. Exploratory surgery was recommended but unfortunately not permitted by his family. Despite intensive measures, his vital signs deteriorated rapidly and he died 50 hours after the ingestion.

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