• 한국자동차공학회논문집
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• 제4권4호
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• pp.46-57
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• 1996

The direct injection stratified charge(DISC) engine enhances the fuel tolerance and the antiknock tendency. This enhanc3d antiknock tendency allows use of a higher compression ratio which results in higher thermal efficiency. But its actual utilization is prevented by high emission combustion time and wall quenching will be the main causes of increasing unburned hydrocarbons in DISC system. In order to solve this problem, small aount of hydrogen was added to the charging air or injected fuel. The effects of hydrogen addition were examined experimentally by radial fuel injection using a pancake-type constant volume bomb. In case of the hydrogen addition to the charge of air, the combustion the amount of hydrogen. In case of the hydrogen addition to the fuel, the combustion pressure was significantly increased.

• 한국연소학회지
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• 제22권1호
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• pp.23-31
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• 2017

Large-scale fuel tanks emit massive amount of hardly-combustible VOC mixtures which are light hydrocarbon species in dilution with nitrogen and carbon dioxide. We have developed a lab-scale burner to combust those VOC mixtures by use of a turbulent partially-premixed flame as a pilot flame. For a higher HC treatment ratio, the mixture gases were reformed by a rotating arc plasma device. The results showed that the nitrogen mole fraction and the injecting speed of the VOC mixture influence on the performance of the burner. It was also found that the size of the pilot flame and the power supplied to the plasma device determine the overall HC treatment ratio and the concentrations of CO and NOx in the exhaust gas.

• 에너지공학
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• 제17권4호
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• pp.227-232
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• 2008

이산화탄소는 지구온난화를 일으키는 온실가스의 하나의 주요요인으로 생각되어진다. $CO_2$는 탄화수소를 연료로 사용하는 연소에서 배기가스의 주성분이다. 자동차의 $CO_2$ 배출물에 대한 규제는 최근에 더욱 절박하게 대두되어 왔다. 이러한 심각한 규제는 배기가스를 저감하는 대체연료를 개발할 수 있는 자동차 제품들에게 요구되는 것이다. 본 논문은 가솔린, 디젤, LPG 자동차를 사용하여, FTP-75와 NEDC(ECE15+EUDC) 모두에 따라서 $CO_2$ 배출물과 연료소비율(연비)과의 상관관계를 검토했다. 이 논문을 통해서 탄소중량비가 낮은 연료 일수록 $CO_2$ 발생량의 감소율이 큰 것을 알 수 있다. 사용한 연료에 따라서 $CO_2$ 배출량과 연비와의 관계를 함수로 표현할 수 있었으며, 높은 상관관계를 갖는 것을 알 수 있었다. LPG차량은 휘발유와 디젤차량보다 $CO_2$ 배출량이 적게 배출되는 것을 알 수 있었다.

• 천문학회보
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• 제40권1호
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• pp.60.2-60.2
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• 2015

Since its detection in 1980, the $8-{\mu}m$ north-polar brightening of $CH_4$ on Juptier has not moved from $180^{\circ}$ (SysIII) longitude. The $8-{\mu}m$ $CH_4$ brightening is mostly thermal and very similar to that of $13-{\mu}m$ $C_2H_2$ emissions, but the morphology of these hydrocarbon north-polar brightenings are very different from that of the $3-{\mu}m$ $H_3{^+}$ auroral oval suggesting a significantly different excitation process yet unknown heating mechanism. Recently, Kim et al. (submitted to Icarus, 2015) found that that the center of the $3-{\mu}m$ $CH_4$ northern bright spot is located at ${\sim}200^{\circ}$ (SysIII) longitude, which is ${\sim}20^{\circ}$ west from the center of the $8-{\mu}m$ north-polar bright spot, and it does not coincide with the $3-{\mu}m$ $H_3{^+}$ bright spot. They found significantly high temperatures (500 ~ 850K) from $CH_4$ rotational lines on the $3-{\mu}m$ bright spot above the $1-{\mu}bar$ pressure level, while we find cooler temperatures (<350K) over the the $8-{\mu}m$ spot. They also found that the upper states of the $3-{\mu}m$ $CH_4$ bands are mostly populated by non-thermal excitations, such as auroral particle precipitations and/or Joule heatings in contrast to the $8-{\mu}m$ thermal emission. This finding indicates that the $10-{\mu}m$ hydrocarbon brightening is confined to low altitudes below the $1-{\mu}bar$ level eliminating the long-suggested possibility of direct auroral bombardments while opening a new possibility of dynamical origin for the $10-{\mu}m$ brightening.

• 한국대기환경학회지
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• 제30권6호
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• pp.519-530
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• 2014

Twenty four individual polycyclic aromatic hydrocarbon (PAH) compounds both in gas- and particle-phase were quantified in three tunnels (Namsan Tunnel 3, Jeongneung Tunnel, Bukak Tunnel) to characterize vehiculate emission of PAHs. Gas phase PAHs were dominant in tunnels which consisted of 85% of total PAHs concentrations. Naphthalene and 2-methyl naphthalene were the most abundant gas phase PAH compounds, while the concentrations of fluoranthene and pyrene were highest in the particle phase. Most (96%) of the gas phase PAH compounds consisted of two- and three-aromatic rings whereas most of the particle phase PAHs were in four and five-rings (67%) in tunnels. Average BaP-eq concentrations of PAHs in the particle phase ($20.8{\pm}11.6ngm^{-3}$) was about twenty fold higher than that in the gas phase ($1.6{\pm}0.6ngm^{-3}$). It means that the particle phase PAHs has more adverse health effect than the gas phase PAHs even though the concentrations of the particle phase PAHs were lower than those of the gas phase PAHs. Compared to previous studies reporting diagnostic ratios for specific PAH compounds, the profile of individual PAH compounds measured in this study reflected well for the vehiculate emissions. We reported, for the first time, on the results of the profile of individual PAH compounds measured in tunnels for both gas and particle phases.

• 한국자동차공학회논문집
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• 제20권3호
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• pp.88-97
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• 2012

To measure the traffic pollutants with high temporal and spatial resolution under real conditions, a mobile emission laboratory (MEL) was designed. The equipment of the mini-van provides gas phase measurements of CO, NOx, CO2 and THC (Total hydrocarbon), and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and a condensation particle counter (CPC). The inlet sampling port above the bumper enables the chasing of different type of vehicles. This paper introduces the technical details of the MEL and presents data from the experiment in which a MEL chases a city bus fuelled by diesel, DME and Bio-diesel. The dilution ratio was calculated by the ratio of ambient NOx and tail-pipe NOx. Most particles from the bus fuelled by diesel were counted under 300 nm and the peak concentration of the particles was located between 30 and 60 nm. However, most particles in the exhaust of the bus fuelled by DME were nano-particles (diameter: less than 50 nm). The bus fuelled by Bio-diesel shows less particle emissions compare to diesel bus due to the presence of the oxygen in the fuel.

• 신재생에너지
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• 제7권3호
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• pp.67-73
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• 2011

MGT fuelled by landfill gas was tested to asses feasibility of its exhaust gas application for $CO_2$ enrichment. The exhaust gas was analyzed during start-up and normal operation with different MGT load conditions. Due to the changes of air/fuel ratio and combustion mode, $O_2$, $CO_2$, CO and NOx concentration were varied within wide ranges during the MGT start-up. Especially, NOx emissioin level was increased up to 20.01 ppmv. Different tendencies of $O_2$, $CO_2$, CO and NOx concentrations were observed with MGT output changes. $O_2$ and CO concentrations were shown to be decreased and NOx and $CO_2$ concentrations were shown to have opposite trends. NOx emission level (0.8~1.88 ppmv) was very low compared to other types of combustion based power generation equipment. Unburned hydrocarbon emission level was substantially decreased with MGT load increase. Especially, $C_2H_4$ concentration was below the detection limit(0.2 ppmv) around the nominal load condition. The exhaust gas from landfill gas fuelled MGT system was shown to be feasible for $CO_2$ fertilization. Concentrations of major components were within or below the maximum allowable ranges.

• 한국자동차공학회논문집
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• 제22권2호
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• pp.67-75
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• 2014

Biodiesel as alternative fuels has been widely studied due to biodiesel merits such as lower sulfur, lower aromatic hydrocarbon and higher oxygen content. But biodiesels could be easily oxidized by several conditions. In this study, various antioxidants such as propyl gallate, TBHA, TBHQ, DTBHQ, butyl-amin, aniline and pyrogallol were added in the biodiesel produced by the used cooking oil, then the material property test and the vehicle emissions test were conducted in accordance with test method. From the results of material property test, all antioxidants were suitable for the quality standard of density and kinematic viscosity, but Propyl gallate and Pyrogallol, as a type of Gallate additives, showed that the result of TAN increased rapidly according to the increase of the amount of additives. In the oxidation stability test, TBHQ, Butyl-amine and Aniline showed the excellent oxidation stability. Also, when considering the material property test, TBHQ was verified to the most excellent additives. In case of the vehicle emissions test, the testing was conducted by using the biodiesel added by TBHQ and was conducted by using two light duty diesel vehicles suitable for the EURO 4 and EURO 5 emission regulation. The result of testing showed that when the TBHQ was added, the amounts of CO, NOx and NMHC+NOx were decreased but the amount of $CO_2$ was increased.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제1권1호
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• pp.19-33
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• 1997

The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorological processes. In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification process through observation is emphasized.

• 한국안전학회지
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• 제31권3호
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• pp.22-27
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• 2016

The use of electromagnetic wave has been interested in various energy industry because it enhances a flame stability and provides higher safety environments. However it might increase the pollutant emissions such as NOx and soot, and have harmful influence on human and environments. Therefore, it is very important to understand interaction mechanism between flame and electromagnetic wave from environmental point of view. In this study, an experiment was performed with jet diffusion flames induced by electromagnetic wave. Microwave was used as representative electromagnetic wave and a flickering flame was introduced to simulate the more similar combustion condition to industry. The results show that the induced microwave enhances the flame stability and blowout limit. The unstable lifted flickering flames under low fuel/oxidizer velocity is changed to stable attached flames or lift-off flames when microwave applied to the flames, which results from the abundance of radical pool. However, NOx emission was increased monotonically with increasing the microwave power as microwave power increased up to 1.0 kW. The effects might be attributed to the heating of combustion field and thermal NOx mechanism will be prevailed. Soot particle was examined at the post flame region by TEM grid. The morphology of soot particle sampled in the microwave induced flames was similar to the incipient soot that is not agglomerated and contain a lots of liquid phase hydrocarbon such as PAH, which soot particle formed near reaction zone is oxidized on the extended yellow flame region and hence only unburned young particles are emitted on the post flame region.