• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.909-913
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• 2018

A hydrocarbon trap (HT) plays an important role of controlling vehicle emissions in the so-called cold emission period by holding hydrocarbons until three way catalysts (TWCs) are thermally activated. In this study, we have investigated the adsorption characteristics of cation (H, La, K, and Ag)-exchanged ZSM-5 zeolites for hydrocarbons (propylene, n-butane, and toluene) by DFT (density functional theory)-based computational chemistry. Cation exchange is to improve the hydrothermal stability of zeolites and their adsorption capacity, thereby rendering cation-exchanged zeolites promising materials for HT. The idea of cluster approximation makes the calculation of adsorption energies superbly efficient in computation. The results showed that Ag-exchanged ZSM-5 would be the best for the adsorption of all three adsorbates, without often encountered Ag oxidation in experiments. Besides, the hydrothermal stability of La-exchanged ZSM-5 was confirmed from the change of geometrical parameters by cation exchange, and it showed good adsorption capacity for propylene and toluene. Hydrogen-exchanged ZSM-5 was also good for hydrogen adsorption, but had poor hydrothermal stability.

• Proceedings of the KSME Conference
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• 2000.11b
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• pp.150-155
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• 2000

Exhaust emissions from vehicles are the main source of air pollution. Many researchers are trying to find the way of reducing vehicle emissions, especially in the cold transient period of the FTP-75 test. In this study, UEGI (Unburned Exhaust Gas Ignition) technology, warming up the close-coupled catalytic converter (CCC) by igniting the unburned exhaust mixture using two glow plugs installed in the upstream of the catalyst, was developed. It was applied to an exhaust system with a hydrocarbon adsorber to ensure an effective reduction of HC emission during the cold start period. Results showed that the CCC reaches the light-off temperature (LOT) in a shorter time compared with the baseline exhaust system, and HC and CO emissions are reduced significantly during the cold start.

• Microbiology and Biotechnology Letters
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• v.48 no.2
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• pp.99-112
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• 2020

Rhizoremediation, based on the ecological synergism between plant and rhizosphere microorganisms, is an environmentally friendly method for the remediation of petroleum hydrocarbon-contaminated soils. In order to mitigate global climate change, it is necessary to minimize greenhouse gas emissions while cleaning-up contaminated soils. In rhizoremediation, the main factors affecting pollutant remediation efficiency and greenhouse gas emissions include not only pollutant and soil physicochemical properties, but also plant-microbe interactions, microbial activity, and addition of amendments. This review summarizes the development in rhizoremediation technology for purifying oil-contaminated soils. In addition, the key parameters and strategies required for rhizoremediation to mitigate climate change mediation are discussed.

• Membrane Journal
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• v.30 no.6
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• pp.395-408
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• 2020

Polymer electrolyte membrane fuel cells (PEMFCs) have gained much attention as eco-friendly energy conversion devices without emission of environmental pollutant. Polymer electrolyte membrane (PEM) that can transfer proton from anode to cathode and also prevent fuel cross-over has been regarded as a key component of PEMFCs. Although perfluorinated polymer membranes such as Nafion® were already commercialized in PEMFCs, their high cost and toxic byproduct generated by degradation have still limited the wide spread of PEMFCs. To overcome these issues, development of hydrocarbon based PEMs have been studied. Incorporation of cross-linked structure into the hydrocarbon based PEM system has been reported to fabricate the PEMs showing both high proton conductivity and outstanding physicochemical stability. This study focused on the various cross-linking strategies to the preparation of cross-linked PEMs based on hydrocarbon polymers with ion conducting groups for application in PEMFCs.

• International Journal of Advanced Culture Technology
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• v.4 no.1
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• pp.10-18
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• 2016

In the present study, a single cylinder four stroke dual fuel diesel engine was tested to investigate the performance and emission characteristics of various test fuels. The engine was tested in dual fuel mode using diesel and Karanja biodiesel blends as pilot fuel along with Natural gas as primary fuel with a constant gas flow rate under different loading conditions. From the experimentation it was found that smoke opacity and oxides of nitrogen (NOx) are at low level for all the prepared test fuels in dual fuel mode but the emissions of carbon monoxide (CO), carbon dioxide ($CO_2$) and hydrocarbon (HC) were found higher. In comparison to diesel fuel, by increasing the blend percentage different emission parameters are found to be reduced. At different loading conditions all the test fuels show poor performance in dual fuel mode of operation when compared with single mode of operation with diesel and biodiesel. With increase in gas flow rates, except (NOx) and smoke emissions, the other emission parameters like CO, HC and $CO_2$ values increased for all test fuels. Again, all blended fuels showed lower performance compared to diesel. The maximum pilot fuel savings for diesel was found decreasing with the increase in karanja biodiesel. From the present work it may be concluded that Karanja biodiesel with Natural gas in dual mode can be can used as promising alternative for diesel with some required engine modifications and further research must be carried out to minimize the emissions of CO, HC and $CO_2$.

• Journal of Energy Engineering
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• v.18 no.1
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• pp.69-73
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• 2009

The regulations for exhaust emission from vehicles have become much more stringent in recent years. These more stringent regulations require vehicle manufacturers to develop alternative fuels that reduce exhaust emission. This research is to analyze the characteristics of exhaust gas emission of same level vehicles that use gasoline, diesel, and LPG fuels. As for the test mode, we used the CVS-75 mode, which is the driving mode of the current domestic and North American emissions. The characteristics of the exhaust gas emitted under this driving condition was studied. We examined the emissions of THC, CO, and NOx of vehicles that use gasoline, diesel, and LPG fuels. As a result, vehicle exhaust gas emissions increased 9.8 % for vehicles using gasoline and it decreased 12.2 % for diesel-powered vehicles compared to vehicles using LPG fuel. Using gasoline and LPG fuel in the CVS-mode, over 80 % of THC and CO emission was produced for the cold start Phase 1.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.5
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• pp.92-99
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• 2011

To measure the traffic pollutants with high temporal and spatial resolution under real conditions, a mobile emission laboratory (MEL) was designed. The equipment of the mini-van provides gas phase measurements of CO, NOx, $CO_2$, THC (Total hydrocarbon) and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and a condensation particle counter (CPC). The inlet sampling port above the bumper enables the chasing of different type of vehicles. This paper introduces the technical details of the MEL and presents data from the car chasing experiment of diesel bus equipped with aftertreatment system. The dilution ratio was calculated by the ratio of ambient NOx and tail-pipe NOx. Most particles from the diesel bus were counted under 300 nm and the peak concentration of the particles was located between 30 and 60 nm. The total PM number emission from diesel bus equipped with DPF was 10 orders of magnitude lower compared to those emitted from base diesel bus. And the total PM number emission from diesel bus equipped with SCR was comparable to the particle emission from base diesel bus.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.1
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• pp.82-88
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• 2011

Lean combustion and exhaust emission characteristics in a ethanol fueled spark-ignited engine according to ethanol-gasoline fuel blending ratio were investigated. The test engine was $1591cm^3$ and 10.5 of compression ratio SI engine with 4 cylinders. In addition, lambda sensor system was connected with universal ECU to control the lambda value which is varied from 1.0 to 1.5. The engine performance and lean combustion characteristics such as brake torque, cylinder pressure and rate of heat release were investigated according to ethanol-gasoline fuel blending ratio. Furthermore, the exhaust emissions such as carbon monoxide (CO), unburned hydrocarbon (HC), nitrogen oxides ($NO_x$) and carbon dioxide ($CO_2$) were measured by emission analyzers. The results showed that the brake torque, cylinder pressure and the stability of engine operation were increased as ethanol blending ratio is increased. Brake specific fuel consumption (BSFC) was increased in higher ethanol blending ratio while brake specific energy consumption (BSEC) was decreased in higher ethanol blending ratio. The exhaust emissions were decreased as ethanol blending ratio is increased under overall experimental conditions, however, some specific exhaust emission characteristics were mainly influenced by lambda value and ethanol-gasoline fuel blending ratio.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.2
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• pp.250-260
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• 2007

It was investigated that the emission characteristics of volatile organic compounds (VOCs) from small and medium companies located on industrial complexes in Metropolitan area. The emission characteristics are intermittent sources in which VOCs emissions are highly depends on the working condition. Optimized ventilation system to improve air quality in working area for the three typical companies were installed. Adsorption characteristics of major VOCs such as MEK, IPA, and toluene emitted front the companies were investigated for design of the activated carbon vessel as a VOCs control facility in each company. Concentration of total hydrocarbon and gas amounts needed to ventilation were also used as a design parameter. Mixed adsorbent to improve adsorption characteristics of problematic solvents like IPA and the design guideline of the activated carbon vessel have been suggested.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.2
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• pp.137-143
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• 2012

Currently, in order to meet the reinforced emissions regulations for harmful exhaust gas including carbon dioxide ($CO_2$) as a greenhouse gas, technologies for reducing $CO_2$ emission and fuel consumption are being developed. Gasoline direct injection (GDI) systems have the advantage of improved fuel economy and higher power output than port fuel injection gasoline engine systems. The aim of this study is to examine the performance and emission characteristics of a lean burn GDI engine equipped with spray-guided-type combustion system. Stable lean combustion was achieved with a late fuel injection strategy under a constant operating condition. Further improvement in specific fuel consumption is possible with the introduction of multiple fuel injection strategies, which also increases hydrocarbon (HC) and nitrogen oxide ($NO_x$) emissions and decreases carbon monoxide (CO) emission.