• Title/Summary/Keyword: Hydrocarbon

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Generation of Model Diesel Particles by Spark Discharge and Hydrocarbon Condensation

  • Kim, Hak-Joon;Kim, Jin-Ho;Choi, Young-Joo;Oh, Hyen-Chul;Chu, Jung-Bum;Kim, Sang-Soo
    • Journal of Mechanical Science and Technology
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    • v.20 no.11
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    • pp.1972-1979
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    • 2006
  • This study was conducted in order to generate model particles which were similar to particles in diesel emission. Spark discharge was used for carbon agglomerates and hydrocarbon condensation for particles that consist of carbon agglomerates and hydrocarbon. The size of the carbon agglomerates, whose mean size were 30 and 70 nm, ranged between 15 and 200 nm, and the total number concentration of the particles ranged from 3 to $5{\times}10^7#/cm^3$ as the controllable variables in spark discharge generator changed. The result of the hydrocarbon condensation experiment showed that the final sizes of the particles enlarged by condensation did not depend on the initial sizes, but the maximum condensational growth of carbon agglomerates by dodecane ($C_{12}H_{26}$) condensation was 112 times the initial size of 40 nm, while the size of the agglomerates by benzene ($C_6H_6$) was 3.25 times its initial size.

COMPARISON OF HYDROCARBON REDUCTION IN A Sl ENGINE BETWEEN CONTINUOUS AND SYNCHRONIZED SECONDARY AIR INJECTIONS

  • Chung, S.-H.;Sim, H.-S.
    • International Journal of Automotive Technology
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    • v.3 no.1
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    • pp.41-46
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    • 2002
  • Effect of secondary air injection (SAI) on hydrocarbon reduction has been investigated in a single cylinder Sl engine operating at cold-steady/cold-start conditions. The hydrocarbon emission and exhaust gas temperature with and without catalytic converter were compared with continuous and synchronized SAIs, which injected secondary air intermittently into exhaust port. Effects of SAI location, SAI pressure, SAI timing, and location of catalytic converter have been investigated and the results are compared for both SAls with base condition. At cold-steady condition, the rate of HC reduction increased as the location of SAI was closer to the exhaust valve for both synchronized and continuous SAls. The emission of HC decreased with increasing exhaust-A/F when it was rich, and was relatively insensitive when it was lean. The timing of SAI in synchronized SAI had significant effect on HC reduction and exhaust gas temperature and the synchronized SAI was found to be more effective in HC reduction and exhaust gas temperature compared to the continuous SAI . At cold-start condition, when the catalytic converter was located 20 cm downstream from the exhaust port exit, the catalytic converter warm-up period for both SAls decreased by about 50%, and the accumulated hydrocarbon emission during the first 120 s decreased about by 56% and 22% with the synchronized and continuous SAIs, respectively, compared to that of the base condition.

Numerical Study of the Effects of Hydrocarbon Addition and Corresponding Chemical Kinetics on the Promotion of NO Oxidation in Nonthermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에서의 탄화수소 첨가 효과와 그 반응역학에 대한 수치적 연구)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • Journal of the Korean Society of Combustion
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    • v.5 no.2
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    • pp.37-50
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propylene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_2$ etc.) successively are produced by hydrocarbon decomposition form the primary path of $NO-NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propylene to have higher affinity with O radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_2$ oxidation. It was also shown that propylene is superior to ethylene in the aspect of NOx removal.

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Log-based petrophysical analysis of Khatatba Formation in Shoushan Basin, North Western Desert, Egypt

  • Osli, Liyana Nadiah;Yakub, Nur Yusrina;Shalaby, Mohamed Ragab;Islam, Md. Aminul
    • Geosciences Journal
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    • v.22 no.6
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    • pp.1015-1026
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    • 2018
  • This paper aims to investigate the good reservoir quality and hydrocarbon potentiality of the Khatatba Formation, Qasr Field in the Shoushan Basin of the North Western Desert, Egypt by combining results from log-based petrophysical analysis, petrographic description and images from scanning electron microscope (SEM). Promising reservoir units are initially identified and evaluated through well log analysis of three wells in the field of study. Petrophysical results are then compared with petrographic and SEM images from rock samples to identify features that characterize the reservoir quality. Well log results show that Khatatba Formation in the study area has good sandstone reservoir intervals from depths ranging from 12848 ft to 13900 ft, with good effective porosity records of 13-15% and hydrocarbon saturations of greater than 83%. Petrographic analysis of these sandstone reservoir units indicate high concentrations of vacant pore spaces with good permeability that can be easily occupied by hydrocarbon. The availability of these pore spaces are attributed to pore-enhancing diagenetic features, mainly in the form of good primary porosity and dissolution. SEM images and EDX analysis confirmed the presence of hydrocarbon, therefore indicating a good hydrocarbon-storing potential for the Khatatba Formation sandstones.

Electrokinetic remediation of diesel-contaminated silty sand under continuous and periodic voltage application

  • Asadollahfardi, Gholamreza;Rezaee, Milad
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.456-462
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    • 2019
  • Hydrocarbon contamination is among the most challenging problems in soil remediation. Electrokinetic method can be a promising method to remediate hydrocarbon-contaminated soils. Electrokinetic method consists of different transport phenomena including electro-migration, electrophoresis, and electroosmotic flow. Electroosmotic flow is the main transport phenomenon for hydrocarbon removal in soil porous media. However, the main component of hydrocarbons is the hydrophobic organic which indicates low water solubility; therefore, it makes the electroosmotic flow less effective. The objective of the present study is to enhance electrokinetic remediation of diesel-contaminated silty sand by increasing the solubility of the hydrocarbons in the soil and then increase the efficiency. For this purpose, sodium dodecyl sulfate (SDS) was used as a catholyte. In this content, SDS 0.05 M was used as catholyte and $Na_2SO_4$ 0.1 M was used as an anolyte. Low (1 V/cm) and high (2 V/cm) voltage gradients were used in periodic and continuous forms. The best removal efficiency was observed for high voltage gradient (2 V/cm) in a periodic form, which was 63.86. This result showed that a combination of periodic voltage application in addition to the employment of SDS is an effective method for hydrocarbon removal from low permeable sand.

혼합 균주의 유류 분해 특성에 관한 호흡율 연구

  • 목지예;류두현;유병수;유지선;박준석;안병구
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.323-326
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    • 2002
  • Oxygen uptake characteristics of soil microcosm added by hydrocarbon degrading bacteria screened from polluted site in Korea was studied. The degradation of TPH was enhanced by additon of nononionic surfactants. The amount of oxygen consumed was decreased at higher concentration. The degradation rate of hydrocarbon was decreased by increasing the hydrcarbon concentration.

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The Change of Flammability Limit by the Addition of Halogenated Hydrocarbons (할로겐화 탄화수소의 첨가에 의한 폭발한계의 변화)

  • 한우섭;신창섭;정국삼
    • Journal of the Korean Society of Safety
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    • v.9 no.1
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    • pp.83-88
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    • 1994
  • The change of flammability limit of n-heptane by the addition of halogenated hydrocarbon was studied. Experimental results showed that halogenated hydrocarbon has a combustion suppression effect and the heat capacity was a Important factor on the flammability limit. The combustion suppression effect of halogenated hydrocarbon was lower than halon, but higher than nitrogen, and the order of effect was $C_3$C1$_3$F$_3$> $C_2$HC1$_2$F$_3$> $C_2$H$_2$F$_4$.

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SVE & Bioventing Techniques for the Treatment of Hydrocarbon (SVE와 Bioventing 기술을 이용한 유류 오염토양의 복원)

  • 김무훈;강순기;조미영;정우성;박덕신
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.137-140
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    • 2000
  • The purpose of this study is to see the effect of SVE (Soil Vapor Extraction) and Bioventing (biostimulation) hydrocarbon contaminated areas. The removal rate of VOC for three weeks were 17.43 kg on 3.6 ㎥/hr at steady-state. In the application of Bioventing, every flow rate were tested, and it was found that 4.0 ㎥/hr were adequate for best control of the system. At this stage, the addition of microbial agent accelerated the biodegradation of the hydrocarbon.

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POLYCHLORINATED BIPHENYLS INDUCE ARYL HYDROCARBON RECEPTOR-INDEPENDENT APOPTOSIS OF MOUSE SPLEEN CELL

  • Jeon, Young-Jin;Youk, Eun-Soo;Lee, Sang-Han;Jaehong Suh;Na, Yong-Joo;Kim, Hwan-Mook
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2002.05a
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    • pp.79-79
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    • 2002
  • Polychlorinated biphenyls (PCBs) are ubiquitous environmental contaminants, and many of their toxic effects, including their immunotoxicities, are mediated by the activation of aryl hydrocarbon receptor (AhR). We previously reported that Aroclor 1254, one of the most widely used PCB mixtures, increased DNA fragmentation in mouse spleen cells, suggesting that apoptosis was correlated with the immunotoxicity of PCB (Yoo et al., 1997).(omitted)

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유류분해 미생물의 표면특성에 따른 분해성 및 거동성 변화

  • 류두현;목지예;최명석;김진명;김동일;전경화;박소연
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.273-276
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    • 2004
  • The adhesion of hydrocarbon degrading bacteria(HDB) differing in surface hydrophobicity was investigated. Cell wall hydrophobicity was modified chemically and physiologically. Modified adhesion deficient mutant of HDB was selected in a soil column assay. Physiologically and chemical modification increased cell surface hydrophobicity. Cell surface characteristics including BATH and FTIR were measured. Physiological modification using ampicillin was not stable, but chemical modification was stable. Hydrocarbon degrading efficiency was measured of TPH modified and unmodifed HDB.

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