• Title/Summary/Keyword: Hydration resistance

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Long-term Durability Characteristics of Fly ash Concrete Containing Lightly Burnt MgO Powder (저온 소성한 MgO 분말을 함유한 플라이애시 콘크리트의 장기재령에서의 내구특성)

  • Jang, Bong-Seok;Choi, Seul-Woo;Lee, Kwang-Myong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.3
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    • pp.909-916
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    • 2013
  • Concrete containing lightly burnt MgO has long term expansibility. It also could compensate for the thermal shrinkage of mass concrete, because the hydration of MgO proceeds at a slow pace to long-term age. Thus, lightly burnt MgO has been applied to the construction of mass concrete such as dams. Recently, the expansion characteristics of MgO concrete with fly ash that could be applied to mass concrete for the reduction of hydration heat have been studied and however, limited studies on its durability. This study investigates the long-term durability characteristics of fly ash concrete with lightly burnt MgO. The durability tests on carbonation, freezing-thawing, diffusion of chloride, and resistance to sulfate attack were carried out for MgO concrete with curing for 360 days in submerged condition with different temperature of 20 and $50^{\circ}C$. The results reveal that MgO concrete shows a greater resistance of carbonation, diffusion of chloride, and resistance to sulfate attack. On the other hand the resistance of freezing-thawing was little influenced by MgO powder.

Material Properties and Shrinkage Crack Resistance of Concrete Produced with Fluorine-Silicate Hybrid Type Crack Reducing Agent (불소-실리카 복합형 균열저감제가 첨가된 콘크리트의 재료 특성과 수축균열 저항성)

  • Lee, Man-Ik;Park, Jong-Hwa;Nam, Jae-Hyun;Kim, Do-Su;Kim, Jae-On
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.553-558
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    • 2006
  • In this study, fluorine-silicate hybrid type crack reducing agent(FS) consisted of fluorine and silicate compounds applied to concrete mix(specification : 25-30-18) between 0.5% and 2.0% at intervals of 0.5% based on cement weight. Experiments for material properties of concrete such as slump, air content and bleeding with elapsed time were performed. Experiment and elucidation for shrinkage crack resistance as well as adiabatic hydration temperature were also carried out. It was appeared that FS addition contributed to lower bleeding and hydration temperature without disturbance of fresh properties of concrete such as slump and air content compared to non-added concrete. Especially, shrinkage crack resistance of concrete resulted from plastic and drying shrinkage could be effectively reduced by the addition of FS ranging from 1.0% to 1.5%.

Hydration heat and autogenous shrinkage properties of silica-fume included mass concrete (실리카퓸을 사용한 매스콘크리트의 수화열과 자기수축 특성)

  • Kim, Chin-Yong;Kim, Jin-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.489-492
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    • 2008
  • Adiabatic temperature rise and autogenous shrinkage experiments were performed for three silica-fume included mass concrete mixtures and a reference mixture without silica-fume, in order to investigate the influence of silica-fume on the hydration heat and autogenous shrinkage properties of mass concrete, and to examine applicability of silica-fume to mass concrete. It was revealed from the experiment that, for mass concrete, the rate of hydration was hardly increased while the maximum adiabatic temperature rise decreased about 5$^{\circ}$C by the addition of silica-fume, and the amount of autogenous shrinkage was almost the same regardless of silica-fume replacement. These facts imply that silica-fume can enhance the resistance of mass concrete to temperature cracking as well as the durability.

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A Study on the Engineering Properties of Concrete Using Blast-furnace Slag Powder (고로슬래그 미분말을 사용한 콘크리트의 공학적 특성에 관한 연구)

  • Lee, Sang-Soo;Won, Cheol;Kim, Dong-Seok;Park, Sang-Jun
    • Journal of the Korea Concrete Institute
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    • v.12 no.4
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    • pp.49-58
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    • 2000
  • There are many methods to improve the performance of concrete. Especially, granuated blast furnace slag. by-products used in concrete as the replacement material of cement, could contribute to improve the fluidity, resistance of chemical attack and strength of concrete. Also, it could contribute to decrease the rate of generating hydration heat, in addition to cost-down of concrete and prevention of enviromental pollution. Therefore, in order to establish the systemical application of granuated blast furnace slag in normal concrete, the engineering properties of concrete, such as fluidity, strength, setting and hydration properties etc.. was evaluated. In this study, replacement ratio of granuated blast furnace slag was 0, 30, 50, 70(%), and target slump was 8, 12, 15, 18(cm). Results from the experiment, granuated blast furnace slag showed the outstanding effects of improving the engineering properties of concrete. From now on, positive application of granuated blast furnace slag is expected in the point of improving the performance and cost-down of concrete.

Application of waste biomass as ecological corrosion inhibitors for steel rebar embedded in cement mortar (시멘트 모르타르에 매립된 철근의 생태학적 부식방지제로서 폐기물 바이오매스의 적용)

  • Karthick, Subbiah;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.111-112
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    • 2022
  • In this present study, the corrosion mitigation effect of conifer cone extract (CC) was examined in the cement mortar to improve the steel rebar (SR) corrosion resistance. The corrosion inhibition properties of the SR embedded in cement mortar (CM) admixed with different percentage (0, 0.5, 1.0, 1.5, 2.0 %) of CC was studied by open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) tests. This result confirms that the CM with 0.5% of CC added has better corrosion resistance than the blank specimen (0 % of CC). Although, the percentage of CC increase above 0.5%, the CC could yield a negative impact on CM properties in terms of reducing the corrosion resistance due to the reduction of cement hydration reaction. It was highlighted that the SR embedded in CM containing 0.5% of CC had increased corrosion resistance.

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Evaluation of Hydration Heat Properties of Mass Concrete and Crack Resistance Performance in Practical Large Underground Structures Using Ternary Blended Cement (3성분계 시멘트를 활용한 실 대형 지하구조물의 매스 콘크리트 수화 발열 특성 및 균열 저항성 평가)

  • Choi, Yun-Wang;Oh, Sung-Rok;Lee, Jae-Nam
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.82-91
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    • 2019
  • In this study, in order to evaluate Hydration Heat Characteristics of mass concrete using ternary blended cement for large underground structures, the analysis considering the temperature history and the thermal characteristics inside the actual structure was performed. The results of the analysis are compared with the measured values to verify the reliability of the analysis and to evaluate the crack resistance performance. As a result of the measured the actual structure temperature, The adiabatic temperature rise coefficients K and ${\alpha}$ of the slab were $35.1^{\circ}C$ and 0.72, respectively, and the wall was analyzed as $29.3^{\circ}C$ and 0.67. The analytical results and the correlation coefficients(r) were 0.95 and 0.98, respectively. As a result of evaluating the crack resistance of slab and wall, the minimum crack index of slab and wall was 1.22 and 1.20, respectively. These results were found to satisfy the site management standards.

An Experimental Study on Properties of Concrete Using Latent Heat Binder (잠열성 결합재를 활용한 콘크리트의 특성에 관한 실험적 연구)

  • Kim, Yong-Ro;Kim, Do-Su;Khil, Bae-Su;Kim, Ook-Jong;Lee, Do-Bum
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.661-668
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    • 2008
  • It is necessary to develop a new technology for effectively reducing hydration heat and controlling thermal cracking caused increasing construction of large size massive concrete structures such as mat foundation of high-rise building, grandiose bridge, and LNG tank. Therefor, to develop a new technology for reducing hydration heat of large size massive concrete in this study, after developing the latent heat binder for controling hydration heat of concrete by application of latent heat material, it was investigated basic properties and durability such as slump, air content and compressive strength, shrinkage properties, permeability, freezing and thawing resistance, corrosion, and hydration heat generation properties of concrete using latent heat binder. As a test result, it was confirmed that latent heat binder was not affected adversely the basic property and durability of concrete, and was advanced on the reduction of hydration heat and control of thermal crack. It is expected to be applied as the excellent technology on the management of hydration heat and thermal crack in large size mass concrete structures.

Effect of Fiber Addition for Improving the Properties of Lightweight Foamed Concrete (경량 기포콘크리트의 성능향상에 대한 섬유혼입의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.383-389
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    • 2015
  • The objective of this study is to develop mixture proportioning approach of crack controlled lightweight foamed concrete without using high-pressure steam curing processes, as an alternative to autoclaved lightweight concrete blocks (class 0.6 specified in KS). To control thermal cracks owing to hydration heat of cementitious materials, 30% ground granulated blast-furnace slag (GGBS) was used as a partial replacement of ordinary portland cement (OPC). Furthermore, polyvinyl alcohol (PVA) and polyamid (PA) fibers were added to improve the crack resistance of foamed concrete. The use of 30% GGBS reduced the peak value of hydration production rate measured from isothermal tests by 28% and the peak temperature of foamed concrete measured from semi-adiabatic hydration tests by 9%. Considering the compressive strength development, internal void structure, and flexural strength of the lightweight foamed concrete, the optimum addition amount of PVA or PA fibers could be recommended to be $0.6kg/m^3$, although PA fiber slightly preferred to PVA fiber in enhancing the flexural strength of foamed concrete.

Effect of Gas Diffusion Layer Compression and Inlet Relative Humidity on PEMFC Performance (기체확산층 압축률과 상대습도가 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.68-74
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    • 2021
  • Gas diffusion layer (GDL) compression is important parameter of polymer electrolyte membrane fuel cell (PEMFC) performance to have an effect on contact resistance, reactants transfer to electrode, water content in membrane and electrode assembly (MEA). In this study, the effect of GDL compression on fuel cell performance was investigated for commercial products, JNT20-A3. Polarization curve and electrochemical impedance spectroscopy was performed at different relative humidity and compression ratio using electrode area of 25 ㎠ unit cell. The contact resistance was reduced to 8, 30 mΩ·㎠ and membrane hydration was increased as GDL compression increase from 18.6% to 38.1% at relative humidity of 100 and 25%, respectively. It was identified through ohmic resistance change at relative humidity conditions that as GDL compression increased, water back-diffusion from cathode and electrolyte membrane hydration was increased because GDL porosity was decreased.

Strength and abrasion resistance of roller compacted concrete incorporating GGBS and two types of coarse aggregates

  • Saluja, Sorabh;Goyal, Shweta;Bhattacharjee, Bishwajit
    • Advances in concrete construction
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    • v.8 no.2
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    • pp.127-137
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    • 2019
  • Roller Compacted Concrete (RCC) is a zero slump concrete consisting of a mixture of cementitious materials, sand, dense graded aggregates and water. In this study, an attempt has been made to investigate the effect of aggregate type on strength and abrasion resistance of RCC made by using granulated blast furnace slag (GGBS) as partial replacement of cement. Mix proportions of RCC were finalized based upon the optimum water content achieved in compaction test. Two different series of RCC mixes were prepared with two different aggregates: crushed gravel and limestone aggregates. In both series, cement was partially replaced with GGBS at a replacement level of 20%, 40% and 60%. Strength Properties and abrasion resistance of the resultant mixes was investigated. Abrasion resistance becomes an essential parameter for understanding the acceptability of RCC for rigid pavements. Experimental results show that limestone aggregates, with optimum percentage of GGBS, perform better in compressive strength and abrasion resistance as compared to the use of crushed gravel aggregates. Observed results are further supported by stoichiometric analysis of the mixes by using basic stoichiometric equations for hydration of major cement compounds.