• Title/Summary/Keyword: Hydration rate

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A Study on Characteristics of Wood Pellet Gasification in Two Stage Gasifier (Two Stage Gasifier에서의 우드펠릿 가스화 특성 연구)

  • Lee, Moon-Won;Choi, Sun-Yong;Kim, Lae-Hyun
    • Journal of Energy Engineering
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    • v.19 no.4
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    • pp.240-245
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    • 2010
  • In this study, characteristics of wood pellet gasification was studied using a Two Stage Gasifier which is consisted of pyrolysis reactor and ultra high temperature reformer. The average yields of $H_2$, $CH_4$, CO, $CO_2$ were 16.7, 11.3, 37.2, 26.6 L/mim, conversion rate from biomass to gas was 65% in pyrolysis reactor and gas yields in reformer were 55.4, 0.8, 120.8, 56.8 L/mim, respectively. The hydrogen flow rate from reformer is obtained 360.1 L/hr. The most of $CH_4$ was decomposed from 12.3 to 0.3 vol.% while $H_2$ is from 18.2 to 23.7 vol.% in reformer by methane dry reforming, Boudouard reaction, oxidation and/or steam reforming. The amount of $H_2O$ generated by hydration reaction from reformer was 1111.8 g, its accelerated conversion of $CH_4$ to other products. The conversion rate from $CH_4$ to other Compounds was 97.2%. Cold gas efficiency was 53.2%.

Characterization of Concrete Composites with Mixed Plastic Waste Aggregates (복합 폐플라스틱 골재 치환 콘크리트의 기초 물성 평가)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.317-324
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    • 2020
  • Plastic wastes generated from domestic waste are separated by mixed discharge with foreign substances, and the cost of the separation and screening process increases, so recycling is relatively low. In this study, as a fundamental study for recycling mixed plastic wastes generated from domestic waste into concrete aggregates, changes in concrete properties according to the plastic waste types and the substitution rate were evaluated experimentally. The mixed plastic waste aggregate(MPWA) was found to have a lower density and a higher absorption rate compared to the coarse aggregate with good particle size distribution. On the other hand, the single plastic waste aggregate(SPWA) was composed of particles of uniform size, and both the density and the absorption rate were lower than that of the fin e aggregate. It was found that the MPWA substitution concrete did not cause a material separation phenomenon due to a relatively good particle size distribution even with the largest amount of plastic waste substitution, and the amount of air flow increased little. The compressive strength and flexural strength of the PWA substitution concrete decreased as the amount of substitution of the PWA increased due to the low strength of the PWA, the suppression of the cement hydration reaction due to hydrophobicity, and the low adhesion between the PWA and the cement paste. It was found that the degree of deterioration in compressive strength and flexural strength of concrete substituted with MPWA having good particle size distribution was relatively small.

A Study on the Factors Affecting Entrapment Efficiency and Particle Size of Ethosomes (Ethosomes의 포집효율과 입자크기에 영향을 주는 인자에 관한 연구)

  • Jin, Byung Suk;Lee, Sang Mook;Lee, Kwang Hee
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.138-143
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    • 2006
  • Ethosome is a liquid crystalline vesicle prepared by hydration of ethanol-dissolved lecithin with a solution containing hydrophilic components. Investigation of factors affecting the entrapment efficiency and particle size of ethosomes was carried out, because the high entrapment efficiency and small particle size are prerequisite in developing ethosomes as a drug delivery system. The variations of properties of ethosomes with constituent composition and preparation method were examined using a calcein as a hydrophilic marker. It was observed that the amount of ethanol and calcein solution, phosphatidyl choline content in lecithin, preparation temperature, stirring rate, and PBS addition method had a considerable effect on the properties of ethosome. Sonication treatment resulted in the reduction of entrapment efficiency of ethosome, which was due to the release of entrapped components in the vesicles by strong sonication vibration.

Effect of the Curing Temperature on Autogenous Shrinkage of the High Strength Mortar incorporating Mineral Admixtures (양생온도가 혼화재 치환 고강도 모르터의 응결 및 자기수축에 미치는 영향)

  • Han, Min-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.127-133
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    • 2012
  • In this paper, tests were carried out to monitor the effect of the curing temperature on autogenous shrinkage of the high strength cement mortar incorporating silica fume, blast furnace slag and fly ash ranged from 10%~30% by mass of cement. The curing temperatures were varied from $5^{\circ}C$ to $35^{\circ}C$, respectively. According to results, the setting time exhibited to delay with increase of admixture and drop of temperature. As for the effect of curing temperature on autogenous shrinkage, the increase of SF and BS resulted in an increase of autogenous shrinkage, while the use of FA decrease. The higher the curing temperature is, the greater the autogenous shrinkage is. This is due to the accelerated hydration rate of cement. It is found that the maturity does not consider the effect of curing temperature on autogenous shrinkage.

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Study on preparation of blast furnace slag mortars using alkali activation (알칼리 활성화에 의한 고로슬래그 경화체의 제조 연구)

  • Shin, Jae Ran;Lim, Yun Hui;Lee, Ju Yeol;Park, Byung Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.188-193
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    • 2015
  • Blast Furnace Slag is good for enhancing the qualities of concrete such as reducing hydration heat increasing fluidity, long-term strength and durability, but it has some problems: construction time is increased or the rotation rate of form is decreased due to low development of early strength. In this study, an aqueous alkali solution for alkali activated reaction was obtained by the electrolysis using concentrated water discharged from seawater desalination process. Prepared aqueous alkali solution was applied to produce mortars using blast furnace slag. The results can be summarized as follows : For the mortar, compressive strength was decreased below 2% of NaOH and increased below 6% of NaOH. And compressive strength was increased gradually with increasing NaOCl contents. However, NaCl contents of mortars caused a decrease of 28days strength above early strength.

Development of Specific Organ-Targeting Drug Delivery System (III)-In Vitro Study on Liver-Targeting Adriamycin Delivery System using Human Serum Albumin Microspheres- (장기표적용 약물수송체의 개발에 관한 연구(제 3보 -알부민 미립구를 이용한 Adriamycin의 간 표적용 수송체에 관한 in vitro 연구-)

  • Kim, Chong-Kook;Hwang, Sung-Joo;Yang, Ji-Sun
    • Journal of Pharmaceutical Investigation
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    • v.19 no.4
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    • pp.195-202
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    • 1989
  • In attempt to improve the chemotherapeutic activity of adriamycin, adriamycin-entrapped HSA microspheres were prepared and investigated by the various in vitro experiments. The shape, surface characteristics and size distribution of HSA microspheres are observed by scanning electron microscopy. The in vitro drug release, albumin matrix degradation by protease of HSA microspheres were studied. The shape of HSA microspheres were spherical and the surface was smooth and compact. The size of HSA microspheres ranged from 0.4 to $2.5\;{\mu}m$ and have average diameters of 0.5 to $0.7\;{\mu}m$. The size distribution of HSA microspheres prepared by ultrasonication was mainly affected by albumin concentration and heating time in the process of hardening. In in vitro, almost all adriamycin was released from HSA microspheres for 8 hr. Analysis of the resulting adriamycin release profiles demonstrated that adriamycin is released from the microspheres in two distinct steps, a fast phase (until 30 min) followed by a much slower sustained release phase. Drug release, which is due to diffusion, was depended on the rate of matrix hydration. Drug release was largely affected by albumin concentration and heating temperature during the process of hardening. Albumin matrix degradation of HSA microspheres was affected by heating temperature and albumin concentration. Higher temperature and longer times generally produce harder, less porous, and slowly degradable microspheres.

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A Study on the Watertightness Improvement of Cementitious Material for Durability Improvement of Concrete (콘크리트 내구성 향상을 위한 시멘트 재료의 수밀성 개선에 관한 연구)

  • Kang, Hyun-Ju;Song, Myong-Shin;Jeong, Eui-Dam
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.5
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    • pp.17-25
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    • 2010
  • We studied on the watertightness improvement of cementitious material for durability enhancement of concrete. For improvement of watertightness of OPC and OPC with fly ash, we used various materials with watertightness properties to OPC and OPC with fly ash. The performance of watertightness improvement of cementitious materials closely related to formation of CSH by pozzolanic reaction and to reducing of size of contact angle in cement pore by using organic fatty acid. And volume of CSH formation at early hydration have an influence of watertightness improvement and reduction of long-term water absorption rate. In using of fly ash, improvement of workability by using the spherical fly ash caused to densify on the structures of cement material and CSH formation by pozzolanic reaction and cement using fly ash also caused watertightness improvement of cementitious materials. For improvement of concrete durability by watertightness, cementitious materials need using watertightness materials and at using fly ash, also it have to the effect of improvement of watertightness of cementitious materials by pozzolanic reaction.

Analysis on a Dynamic Model with One Dimension in Water Transportation of PEM Fuel Cell (PEM연료전지의 수분전달에 있어서 1차원 해석을 수행한 동적모델에 관한 연구)

  • Bakhtiar, Agung;Hong, Boo-Pyo;You, Jin-Kwang;Kim, Young-Bok;Yoon, Jung-In;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.32 no.5
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    • pp.118-123
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    • 2012
  • Water balance has a significant impact on the overall fuel cell performance. Maintenance of proper water management should provide an adequate membrane hydration and avoidance of water flooding in the catalyst layer and gas diffusion layer. Considering the important of advanced water management in PEM fuel cell, this study proposes a simple one dimensional water transportation model of PEM fuel cell for use in a dynamic condition. The model has been created by assumption that the output is the water liquid saturation difference. The liquid saturation change is the total difference between the additional water and the removal water on the system. The water addition is obtained from fuel cell reaction and the electro osmotic drag. The water removal is obtained from capillary transport and evaporation process. The result shows that the capillary water transport of low temperature fuel cell is high because the evaporation rate is low.

Moisturization and Transdermal Penetration Characteristics of PEGimpregnated Aloe vera Gel from DIS Processing (DIS에 의한 Polyethylene Glycol 함침 알로에 베라 겔의 보습 및 경피흡수 특성)

  • Kwon, Hye Mi;Hur, Won;Lee, Shin Young
    • KSBB Journal
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    • v.28 no.5
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    • pp.319-326
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    • 2013
  • This study was carried out to investigate the in vitro and in vivo moisturizing properties and percutaneous absorption of PEG-impregnated Aloe vera gel. The PEG-i-Aloe gel was obtained from dewatering and impregnation by soaking (DIS) of Aloe vera leaf slice. The moisturizing property of the obtained sample was evaluated by moisture determination using gravimetric method in desiccator under different RH% and by water sorption-desorption test on human skin. The transdermal penetration characteristics of PEG-i-Aloe gel was investigated by Franz diffusion cell in vitro transdermal absorption method. PEG-i-Aloe gel had high moisture retention ability and could significantly lead the enhancing skin hydration status as well as reducing the skin water loss due to the film formation as a skin barrier. The skin penetration rate of PEGi- Aloe gel at steady state was 9.76 ${\mu}g/(h{\cdot}cm^2)$ and the quantity of the transdermal absorption was 144 ${\mu}g/cm^2$ in 9 hr. The penetration mechanism was well fitted with Higuchi model ($R^2$ = 0.974-0.994). The results show that PEG-i-Aloe gel has the significant moisturizing effect and strong penetration of the animal skin. It could be used as the moisturizing additive in cosmetic skin products.

Enhanced Flame Resistant Properties of Aluminum Hydroxide Addition on Electrospun Polyurethane Nanofibers (전기방사법에 의해 제조된 폴리우레탄 나노섬유의 수산화알루미늄 내첨에 의한 내염화 특성 향상)

  • Kim, Hyeong Gi
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.9-13
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    • 2016
  • Anti-oxidation and flame resistant polyurethane nanofibers were prepared by electrospinning and aluminum hydroxide addition. Electrospinning was carried out under the following procedure conditions; applied voltage, 20 kV; polymer solution feeding rate, 1.2 ml/h; collector rolling speed, 120 rpm; and tip to collector distance, 15 cm. Aluminum hydroxide was added to the prepared polymer solution for electrospinning to enhance the oxidation and flame resistant properties. The thermal properties were investigated by thermogravimetric analysis to determine the polymer decomposition temperature, integral procedure decomposition temperature, final decomposition temperature, and remaining amount after thermal decomposition. The activated energy for polymer degradation was also investigated using the Horowitz-Metzger equation. The activation energy increased to more than 50%. The thermal properties of the polyurethane nanofibers were improved by a hydration reaction during the thermal decomposition of aluminum hydroxide around $300{\sim}500^{\circ}C$.