• Title/Summary/Keyword: Hydration properties

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Kinetic Study of Hydrations and Volume Change of Soybeans during Soaking (침지중 콩의 흡수 및 부피변화의 속도론적 연구)

  • Kim, Dong-Hee;Yum, Cho-Ae;Kim, Woo-Jung
    • Applied Biological Chemistry
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    • v.33 no.1
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    • pp.18-23
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    • 1990
  • Seven varieties of soybeans(Paldal, Danyeob, Jangbaek, Baegun, Jangyeob and 2 cultivars of Local 1 and Local 2) were investigated to compare the water uptake properties and volume changes during soaking in water. The hydration properties showed that the equilibrated weight increase ratio decreased as the soaking temperature raised to higher than $40^{\circ}C$, while the initial water uptake rate increased upto $80^{\circ}C$. The increase in hydration showed a linear relationship with the square root of the soaking time at $4^{\circ}{\sim}60^{\circ}C$. Local 1 was the highest in water uptake rate constant while Local 2 was the lowest. The activation energy calculated was in the range of $3,246{\sim}4,694\;cal/mole$. The Jangbaek and Local 1 were the highest and the Paldal was the lowest in the rate of volume increase. The activation energy for volume increase was in the range of $3,310{\sim}4,190\;cal/mole$. The z-values calculated from volume change was a little higher than those obtained from weight change.

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Statistical Analysis of the Physical Properties in a Slag-OPC-Gypsum System as a Compound Mixing Ratio

  • You, Kwang-Suk;Lee, Kyung-Hoon;Han, Gi-Chun;Kim, Hwan;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.44 no.9
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    • pp.477-482
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    • 2007
  • The effect of the mixing ratio of compounds in a slag-OPC-Gypsum system on the physical properties of Slag cement is investigated in this study. $Na_2SO_4$ was used as an alkali activator. Blast furnace slag cement was prepared from a mixture of blast furnace slag, ordinary Portland cement and anhydride gypsum. The fluidity and the compressive strength according to the ratio of each mixture were analyzed in statistical analyses in order to discover the parameters influencing the fluidity and compressive strength. The results showed that the hydration of blast furnace slag took place with the addition of $Na_2SO_4$ and that column-crystalline ettringite was created as the main hydration product of the blast furnace slag. In addition, it was found that the compressive strength of blast furnace slag cement tends to increase when the ordinary Portland cement content is higher up to three days. However, it is known that the compressive strength tends to increase as the blast furnace slag content becomes higher with increases in the level of OPC after 28 days. As a result of this analysis, it is believed that the ordinary Portland cement content influences the initial compressive strength of blast furnace slag cement, and that in later days this is highly influenced by the slag content.

Hardened Properties of Ultra Fine Cement with Superplasticizer (유동화제 변화에 따른 초미립자 시멘트의 경화특성)

  • 채재홍;이종열;이웅종;박경상;김진춘;이세웅
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.69-72
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    • 1999
  • In this study, we blended 2 grades of ultra fine cement using the results of previous stud. And the cement slurry was produced by water each water/cement ratio. The slurries were observed hydration phenomena during 28 days with SEM, XRD and DSC. The specimen made by slurry were evaluated with the hardened properties such as compressive strength, flexural strength length change and water absorption. And were tested the adhesive strength of specimen made by injecting the slurry between mortar bars.

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A Study on the Properties of Low-Heat Cement Concrete (저발열시멘트 콘크리트의 기초적 성질에 대한 연구)

  • 문한영;김성수;신화철;강석화
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.57-60
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    • 1997
  • The properties of Low-heat cement are especially in lower heat of hydration than that of other types of cement. In other respect, Low-heat concrete is more advantageous than OPC concrete in chemical resistance, long term age compressive strength, slump loss and resistance to seawater. This paper deals with 28 days age compressive strength and slump loss by elapsed time of mortar and concrete that made with Low-heat cement and 3 types of other cement.

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Shrinkage Properties of High Early Strength Fiber Reinforced Concrete (초기강도 섬유보강 콘크리트의 수축특성)

  • 원종필;김현호
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.5
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    • pp.124-131
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    • 2001
  • The shrinkage properties of high early strength concrete were investigated. One of the method to control microcrack and crack development due to restrained shrinkage is to reinforce concrete with randomly distributed fibers. Regulated-set cement and two different types of fiber were adopted. The experiments for heat of hydration, drying and autogenous shrinkage were conducted. The desirable resistance of high early strength fiber reinforced concrete to restrained shrinkage microcracking was achieved. These results indicate that use of fiber in high early strength concrete plays an important role in control of crack development due to restrained shrinkage.

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The effect of curing conditions on the cracking properties of flyash concrete (양생조건에 따른 플라이애쉬 콘크리트 균열특성에 미치는 영향)

  • Park, Jong-Hwa;Lee, Man-Ik;Nam, Jae-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.825-828
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    • 2006
  • In this paper, experimental studies are performed to find out properties of crack according to the change of curing conditions of flyash concrete. To study the effect of curing conditions on flyash concrete, slump, bleeding, air content and hydration temperature of fresh concrete are measured according to various curing conditions. In addition, the effect of caring conditions on compressive strength, tensile strength and Plastic drying shrinkage cracking of hardened concrete is also considered.

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Effect of Fineness of GGBS on the Hydration and Mechanical Properties in HIGH Performance HVGGBS Cement Paste (고성능 하이볼륨 슬래그 시멘트 페이스트의 고로슬래그 미분말 분말도에 따른 수화 및 강도 특성)

  • Choi, Young Cheol;Shin, Dongcheol;Hwang, Chul-Sung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.141-147
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    • 2017
  • Recently, lots of researches on concrete with high volume mineral admixtures such as ground granulated blast-furnace slag(GGBS) have been carried out to reduce greenhouse gas. The high volume GGBS concrete has advantages such as low heat, high durability, but it has a limitation in practical field application, especially low strength development in early ages. This study investigated the compressive strength and hydration characteristics of high performanc and volume GGBS cement pastes with low water to binder ratio. The effects of fineness($4,330cm^2/g$, $5,320cm^2/g$, $6,450cm^2/g$, $7650cm^2/g$) and replacement(35%, 50%, 65%, 80%) of GGBS on the compressive strength, setting and heat of hydration were analyzed. Experimental results show that the combination of high volume slag cement paste with low water to binder ratio and high fineness GGBS powder can improve the compressive strength at early ages.