• Title/Summary/Keyword: Hydration process

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A Study on the Thermal Characteristics of a $MgO/H_2O$ Chemical Heat Pump ($MgO/H_2O$ 계 화학식 열펌프의 열적 특성에 관한 연구)

  • ;;;;Yukitaka Kato
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.1
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    • pp.34-41
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    • 2004
  • The chemical heat pump based on the Dehydration/Hydration process with a MgO/$H_2O$ system has been researched. The reactor bed could be expected to store the heat around 200∼37$0^{\circ}C$ by the dehydration reaction and to release the heat around 100∼16$0^{\circ}C$ by the hydration reaction under the heat amplification mode operation. The heat output rate of the heat pump system was evaluated using the experimentally determined parameters. The results show that 6∼50 W/kg of heat output and 0.5∼0.8 of heat recovery ratio are attainable. The heat pump will be applicable for a load leveling in a co-generation system by chemical storage of surplus heat at low heat demand and by supplying heat in the peak load period.

Experimental Study Mixing, Placing and Hydration Temperature of 1400kg/$\textrm{cm}^2$ Ultra High-Strength Concrete (1400kg/$\textrm{cm}^2$ 초고강도 콘크리트의 배합, 타설 및 수화온도 이력에 관한 연구)

  • 윤영수;장일영;원종필;최응규
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.430-435
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    • 1997
  • This paper presents the material properties and production of 1400kg/$\textrm{cm}^2$ ultra high-strength concrete in consideration of the history of hydration temperature for the practical utilization. A series of laboratory tests were conducted to optimize the mix proportion and then the full-scall mock up tests were performed to investigate the practicability. The thermal sensors were installed prior to concrete casting into the walls and columns, to measure the hydration temperature during the hardening process, which is inevitable to select the most appropriate curing scheme.

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Fundamental Properties and Adiabatic Temperature Rise of Concrete with the Combination of Mineral and Chemical Admixture (혼화재료의 조합사용에 따른 콘크리트의 기초물성 및 단열온도상승 특성)

  • Jeon Chung Keun;Kim Jong;Shin Dong-An;Yoon Gi-Won;Han Cheon Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.345-348
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    • 2005
  • This paper presents the result of adiabetic temperature rise and fundamental properties of concrete combining admixtures. According to results, difference of setting time with I5.5hours is observed between S-P and R-F30 mixture. Based on the adiabetic temperature rise test, 8$^{circ}C$of heat producted occurs between E-P and R-F30 mixture. is applied to estimate the temperature rising under adiabetic curing condition, which exhibits closer consistency with tested value. The function mentioned above can account for the effect of dormant period in hydration process at early stage on hydration heat production. It reveals that the consideration of placing layer based on the mixture adjustment(E-P mixture at top layer and R-F30 mixture at bottom layer) in mass concreting will contribute to reduce hydration heat as well as alleviate tensile stress discrepancy between placing layer.

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Effects of Petrolatum and Glycerin on Acetone Damaged Canine Skin Barrier

  • Oh, Won-Seok;Oh, Tae-Ho
    • Journal of Veterinary Clinics
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    • v.25 no.6
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    • pp.466-470
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    • 2008
  • The purpose of this study is to investigate whether the effects of topically applied petrolatum and glycerin on the barrier repair of acetone-induced skin damage in 6 beagle dogs. To confirm the effects of petrolatum and glycerin on acetone disrupted skin models, we performed to evaluate the characteristics of transepidermal water loss and SC hydration and scanning electron microscopic observations. TEWL and SC hydration measurements were carried out 3, 6, 12, 24, 48h after applying petrolatum and glycerin during recovery from acute disruption. Our results showed that there were some different effects between petrolatum and glycerin on the acetone damaged skin such as barrier function repair process and SC hydration status. The results indicate that the significant improvement could be observed in glycerin apply more than petrolatum after acetone damages, and further study will be required.

Solid-state NMR Studies of Phenethyl Sulfonic Acid-functionalized MCM-41

  • Chul Kim
    • Journal of the Korean Chemical Society
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    • v.68 no.2
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    • pp.74-81
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    • 2024
  • A sulfonic acid-water-silanol system in SO3H-functionalized MCM-41 was investigated using solid-state nuclear magnetic resonance techniques. The proton exchange rate between a water molecule and a silanol group in the S-PE-MCM-41 was determined by analyzing the 1D proton spectra, the proton EXSY spectrum, and 2H spin-lattice relaxation data under various hydration levels. Two kinds of water-bounding sites were found in the S-PE-MCM-41: weakly and strongly bound sites. Over several hours, water molecules bound to the weakly bound sites at the low hydration level migrated to the strongly bound sites. At high temperature, the S-PE-MCM-41 easily lost water molecules weakly bound to the silanol, while the strongly bound water molecules survived. Water molecules that participated in the hydration of the phenethyl sulfonate were involved in the hydrogenbonded silanol mechanism of proton conductivity. This phenomenon contributes higher proton conductivity to the S-PE-MCM-41 by the cooperation of sulfonyl and silanol groups in the proton transfer process, even at higher temperature.

Hydration Characteristics and Synthesis of Hauyne-Belite Cement as Low Temperature Sintering Cementitious Materials

  • Park, Sang-Jin;Jeon, Se-Hoon;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.224-229
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    • 2018
  • OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

A Mushroom-Rice(Ganoderma lucidum) development which uses the brown rice (현미를 이용한 영지버섯쌀 생산)

  • 정인창;곽희진
    • Journal of Applied Tourism Food and Beverage Management and Research
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    • v.14 no.1
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    • pp.47-58
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    • 2003
  • Brown rice was used as material for solid-substrate cultivation of Ganoderma lucidum. The hydration time with cold water appeared to be 10 hours for brown rice, but the final water content was much less than optimum water content(65%). Hot water reduced the hydration time of brown rice, and the water content reached to 65% within 40 mins. From this result, hot water was better than cold water for the hydration of brown rice. We attempted to develop a practically applicable process by combining the soaking and sterilization. The water content of 65% appeared to be the best for the growth of the fungi and production of glucosamine related to the amount of mycelium. The content of free sugar increased far more in brown rice fermented with mycelium than in brown rice which was not fermented. Addition was most suitable 20% when add mushroom-rice to brown rice.

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An Experimental Study on Hydration Heat Control in The Mass Concrete Using Oscillating Capillary Tube Heat Pipe (진동세관형 히트파이프(OCHP)를 이용한 매스콘크리트의 수화열 제어에 관한 실험적 연구)

  • Beak, Dong-Il;Kim, Myung-Sik;Lee, Moon-Sik;Kim, Kang-Min;Yum, Chi-Sun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.409-412
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    • 2006
  • In process of reinforced concrete(RC) box structure, the heat of hydration may cause serious thermal cracking problems. In order to eliminate hydration heat of mass concrete, this paper reports results of hydration heat control in mass concrete using the OCHP(Oscillating Capillary tube Heat Pipe). Recently OCHP is drawn special attention from these points of low cost as well as short construction schedule for the manufacturing of heat exchanger, flexibility, simplification and high performance. There were three RC box molds$(1.2{\times}1.2{\times}1.2m)$ which shows a difference as compared with each other. One was not equipped with OCHP. While others were equipped with OCHP and these were cooled with air natural convection and spraying water respectively. The OCHP was composed of copper pipe with 12 turns(O.D : 4mm, I.D : 2.8mm). The working fluid was R-22 and its charging ratio was 30(Vol. %). In order to analyze the distribution of temperature and index figure of thermal crack in sequential placement of mass concrete, we used HYCON of computer program. As a result of the experiment, the peak temperature decreased about $15.6\sim23.4^{\circ}C$ than the general specimen and the probability of thermal crack generated in mass concrete decreased up to 0%.

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A Study on Field Applications of Hydration Heat Control in the Mass Concrete Using Oscillating Capillary Tube Heat Pipe (OCHP를 이용한 매스콘크리트 수화열 제어의 현장적용에 관한 연구)

  • Yum, Chi-Sun;Bae, Won-Mahn;Kim, Myung-Sik;Beak, Dong-Il;Kim, Kang-Min
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.413-416
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    • 2006
  • In process of the mass concrete structure, the heat of hydration may cause serious thermal cracking. In order to eliminate hydration heat of mass concrete, this paper reports results of hydration heat control of mass concrete using the Oscillating Capillary tube Heat Pipe(OCHP). There were the several RC box molds which shows a difference as compared with each other. One was not equipped with OCHP. The others were equipped with OCHP. All of them were cooled with natural air convection. The OCHP was composed of copper pipe with 11 turns(outer diameter : 4mm, inner diameter : 2.8mm) and heat type was non-looped type. The working fluid was R-22 and its charging ratio was 40% by volume. The core of the concrete temperature was approximately $55^{\circ}C$ in the winter without OCHP. But the concrete temperature with OCHP was reduced its difference in temperature with the outdoor temperature to $12^{\circ}C$. Finally we saw the index figure of the thermal crack of the structures were varied from 0.75 to 1.47.

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An Experimental Study on the Dispersion Effect of Hydration Heat in the Mass Concrete Using OCHP (OCHP를 이용한 매스콘크리트 수화열 분산효과에 관한 실험적 연구)

  • Kim, Myung-Sik;Baek, Dong-Il;Kim, Kang-Min;Yum, Chi-Sun;Bae, Won-Mahn
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.437-440
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    • 2006
  • In process of the mass concrete structure, the heat of hydration may cause serious thermal cracking. In order to eliminate hydration heat of mass concrete, this paper results of hydration heat control of mass concrete using the Oscillating Capillary tube Heat Pipe(OCHP). There were the several molds which shows a difference as compared with each other. One was not equipped with OCHP. Other were laid with OCHP, and the other were laid in 100cm, and exposed out 50cm. All of them were cooled with natural air convection. The OCHP was composed of copper pipe(outer diameter : 4mm, inner diameter : 2.8mm) and heat type was non-looped type. The working fluid was R-22 and its charging ratio was 40% by volume. The core of the concrete temperature was approximately $53^{\circ}C$ without OCHP. But the concrete temperature with OCHP was reduced its difference in temperature with the outdoor temperature to $12{\sim}15^{\circ}C$. Finally we saw the index figure of the thermal crack of the structures were varied from 0.6 to 1.6.

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