• Title/Summary/Keyword: Hydration experiment

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Study on Hydration Heat of Blended Belite Binder (벨라이트계 혼합 결합재의 수화열 특성에 관한 연구)

  • Lee, Kewn-Chu;Cho, Jae-Woo;Jung, Sang-Hwa;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.145-150
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    • 2011
  • Presently, mass concrete structures are being built in federal and private projects of civil infrastructures and building structures. The hydration heat of mass concrete structures is the most important factor in the quality of concrete matrix and construction period. Moreover, internal cracks caused by hydration heat degrades durability, water tightness, and strength of concrete. To reduce hydration heat, it is necessary to blend belite cement (${\beta}-C_2S$) with industrial by-products (i.e. granulated slag and fly ash). In this experiment, 14 levels of binary binders and 4 levels of ternary binders were used to understand the effect of different replacement ratio on hydration heat, strength and microstructure (i.e. SEM and XRD) of mortar. Cumulative hydration heat at 28 days for the binary and ternary binders was affected by replacement ratio of fly ash and/or granulated slag. As fly ash content increased, hydration heat decreased. As granulated slag content increased, reduction rate of the hydration heat was lower than when fly ash was used. Especially, the hydration heat of ternary binder blended with 40% flyash and 30% granulated slag showed about 50% of hydration heat from using belite cement (P). The study results showed that the temperature rise of concrete matrix can be decreased by using blended belite binders producing low hydration heat and reasonable strength.

The Study of experiment on preventing frost damage at early age of mortar in low temperature using Reduction slag. (환원슬래그를 사용한 콘크리트의 내구성 평가에 관한 연구)

  • Min, Tae-Beom;Choi, Hyun-Kuk;Mun, Young-Bum;Kim, Hyeong-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.150-151
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    • 2016
  • In previous study, researchers studied development of early anti-freezing cement at low temperature (-5℃) using hydration characteristics of reduction slag. In this study, the durability of concrete using reduction slag was conducted. The experiment result, reduction slag makes high temperature and improves compressive strength due to quick setting. And then result of durability show that it is no problem. However, it is considered that further study is needed about high shrinkages which was indicated in dry shrinkage.

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A Study on the Expansive Properties With Particle Size Distribution of Expansive Additives in Mortar (팽창제의 입도분포에 따른 팽창특성에 대한 기초연구)

  • 이종열;이웅종;박정준;박경상;김기수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.151-156
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    • 1998
  • Concrete structures is appeared the shrinkage after being harden of the hydration effect of cement. To overcome this disadvantage, expansive additives are used. In our country, the most popular expansive additives are hauyne(CSA) or free lime(free-CaO) systems. These expansive additives are used to expansive cement mortar or concrete materials. In this study, we analyzed the expansive property mechanism about the hydration reaction of the free lime systems and in particular we convinced size distributions of the free lime size affect the expansion ratio with expansion ratio with experiments. We carried out the experiment for the expansive properties by using the soundness molds and with various the humidity and dry setting conditions. The hydration reactions of the free lime affect the reaction properties according to the relative humidity by laboratory experiments.

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Dispertion Effect of Hydration Heat due to Materials and Standard Variation of Embedded Heat Pipe (매입형 히트파이프의 재질 및 규격변화에 따른 수화열 분산 효과)

  • Kim, Myung-Sik;Yeom, Chi-Sun;Baek, Dong-Il
    • Journal of Ocean Engineering and Technology
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    • v.23 no.6
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    • pp.111-116
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    • 2009
  • The cracking due to hydration heat in mass concrete must be resolved to improve the stability and durability of concrete structures. In this study, the economic efficiency was improved by replacing a copper pipe with a steel one for the heat pipe, and the heat pipe was standardized to significantly improve the operation efficiency, such as the processing, transport, assembly, and construction time. As a result of the experiment, the peak temperature of the ICSHP, ISSHP, and ISUHP specimens decreased by about $7.2{\sim}10.9^{\circ}C$ compared to the OPC specimen and the probability of a thermal crack being generated in the ICSHP, ISSHP, and ISUHP specimens decreased by up to 84~88%.

Theoretical Calculation of Hydration Number and Activity Coefficients of Salts in Concentrated Electrolyte Solutions (진한 전해질 용액 중에서 염의 수화수와 활성도 계수에 관한 이론적 연구)

  • Yong Kil Sung;Mu Shik Jhon
    • Journal of the Korean Chemical Society
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    • v.14 no.2
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    • pp.185-192
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    • 1970
  • The extension of the theory of the electrolyte solution to the calculation of the hydration number and the mean activity coefficient of some 1:1 electrolytes in the concentrated solutions has been made. In this derivation, the hydration number has been calculated from the equation of the dielectric constant proposed by Hobbs, Jhon, and Eyring, and the mean activity coefficient from the theoretical formula developed by Jhon and Eyring. The agreement between theory and experiment over a.wide concentration range is quite satisfactory.

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The Evaluation of Temperature History in Concrete by Using Cement Hydration Model (수화모델을 이용한 콘크리트의 초기온도 예측에 관한 연구)

  • Wang, Xiaoyong;Cho, Hyeong-Kyu;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.253-254
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    • 2012
  • In this study, it carried out measurement experiment Ca(OH)2 and chemically bound water to verify Ca(OH)2 and chemically bound water prediction model out of hydration model of cement incorporating blast furnace slag. It compared and analyzed prediction results using prediction model with measurement results of Ca(OH)2 quantity using thermogravimetric differential temperature analysis and chemically bound water quantity using electronic furnace. It agrees well experiments results with prediction results.

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Study on Temperature History and Compressive Strength of Mock-up Concrete Considering Seasonal Change (매스콘크리트의 계절에 따른 온도이력과 압축강도에 관한 실험)

  • Kim Young-Joo;Gong Min-Ho;Kim Kwang-Ki;Yang Dong-Il;Pack Moo-Young;Jung Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.11a
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    • pp.89-92
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    • 2005
  • Our country has experienced variations in temperature as belong to the area of the continental climate that shows four significant seasons. These occur quality of construction. As the hydration of cement processes, the strength of concrete is developed. In order to improve the quality of concrete, various conditions including temperature and humidity should be maintained appropriately and concrete itself should be cured sufficiently This paper is basic experiment for estimating influence of strength by seasonal mock-up concrete's heat of hydration and estimate relationship of compressive strength development by curing temperature. And show basic document as quality control.

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Hydration Properties of Cement Matrix using Surface Treatment Blast Furnace Slag by Arc Discharge (아크방전에 의해 표면개질 된 고로슬래그를 사용한 시멘트 경화체의 수화 특성)

  • Kim, Sun-A;Kim, Hyeon-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.91-92
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    • 2018
  • A glassy thin film was formed on the surface of the blast furnace slag. When blast furnace slag is used as an admixture of concrete, addition of alkali activators were required. However, alkali activators are not only dangerous as chemical products, but they are also difficult to use as expensive materials. Therefore, it is necessary to study the way of removal of the glassy thin film of blast furnace slag without the risk and cost increase. In this study, to solve this problem, experiment was carried out to improve the hydration reactivity by treatment the surface of blast furnace slag using arc discharge. Experimental results show that when the surface of the blast furnace slag was tratmented by arc discharge, the glassy thin film was destroyed. And the hydration reactivity was improved, the compressive strength was increased.

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Hydration Characteristics of Cement Paste Added Liquid and Neutralized Red Mud (액상 및 중화 레드머드를 첨가한 시멘트 페이스트의 수화특성)

  • Kang, Hye Ju;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.104-105
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    • 2020
  • Red mud is a highly alkaline waste by-product of the aluminum industry. Although recycling of red mud is being actively researched, a feasible technological solution has not been found yet. In this study, we propose that neutralization of red mud alkalinity could assist in its use as a construction material. Neutralized red mud ( pH 6-8) was prepared by adding sulfuric acid to liquefied red mud (pH 10-12). After adding liquid and neutralized red mud to the cement paste, the heat of hydration was measured. As a result of the experiment, the calorific value of the cement paste with liquid red mud was lowered and delayed compared to the cement paste with neutralized red mud.

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Modeling of chloride diffusion in a hydrating concrete incorporating silica fume

  • Wang, Xiao-Yong;Park, Ki-Bong;Lee, Han-Seung
    • Computers and Concrete
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    • v.10 no.5
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    • pp.523-539
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    • 2012
  • Silica fume has long been used as a mineral admixture to improve the durability and produce high strength and high performance concrete. And in marine and coastal environments, penetration of chloride ions is one of the main mechanisms causing concrete reinforcement corrosion. In this paper, we proposed a numerical procedure to predict the chloride diffusion in a hydrating silica fume blended concrete. This numerical procedure includes two parts: a hydration model and a chloride diffusion model. The hydration model starts with mix proportions of silica fume blended concrete and considers Portland cement hydration and silica fume reaction respectively. By using the hydration model, the evolution of properties of silica fume blended concrete is predicted as a function of curing age and these properties are adopted as input parameters for the chloride penetration model. Furthermore, based on the modeling of physicochemical processes of diffusion of chloride ion into concrete, the chloride distribution in silica fume blended concrete is evaluated. The prediction results agree well with experiment results of chloride ion concentrations in the hydrating concrete incorporating silica fume.