• Title/Summary/Keyword: Hydration energy

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A Study on the Compaction and Permeability According to the Mixture Ratio of Pond Ash and Bentonite for Liner Material (매립지 차수재로써 매립회-벤토나이트 혼합비에 따른 다짐 및 투수특성에 관한 연구)

  • Lee, Jungsang;Lee, Jonghwi;Lee, Jinkyu;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.1
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    • pp.31-36
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    • 2012
  • Recently, industrial by-products are exponentially growing because energy consumption is increasing due to rapid industrial development and improved living standards. The purpose of this study is to determine the proper mixing ratio to meet the liner conditions(must be less than $1{\times}10^{-7}$cm/sec), using pond ash and bentonite as liner. As the result of the compaction test, depending on the increase mixing ratio of bentonite, the maximum dry unit weight was decreased but the optimum moisture content was tended to be increased at the compaction curve. As the result of the permeability test, depending on the increase mixing ratio of bentonite, the coefficient of permeability showed tendency to be decreased in the form of index and the tendency was caused by the hydration reactions filling the void of the pond ash. When the mixing ratio of bentonite was approximately over 15%, it was satisfied with the land fill liner conditions. In other words, it is necessary to consider other mixtures containing the cement or another material in the economical aspect for application of the pond ash.

Effect of Types and Replacement Ratio of Alkali Activator on Compressive Strength of Ground Granulated Blast Furnace Slag Mortar (알칼리 자극제의 종류 및 치환율이 고로슬래그 미분말 모르타르의 압축강도에 미치는 영향)

  • Kim, Rae-Hwan;Kim, Gyu-Yong;Kim, Jong-Hee;Lee, Bo-Kyeong;Cho, Bong-Suk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.360-366
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    • 2014
  • In this study, effect of types and replacement ratio of alkali activator on compressive strength of ground granulated blast furnace slag mortar has been reviewed. Types of alkali activator are NaOH, $Ca(OH)_2$, $Na_2SO_4$, and KOH. Replacement ratio of alkali activator is 7.5, 10, 12.5, and 15%, respectively. As results, under high temperature curing condition, 1 day compressive strength development with NaOH and KOH was higher than that of $Ca(OH)_2$ and $Na_2SO_4$. Regardless of types of alkali activator, compressive strength increased with increasing pH. This can be explained by the fact that impermeable film on the surface of slag which is generated when slag contacts water has been destroyed by alkali activator, and this promotes hydration reaction. Also, 1 day age compressive strength of specimen with high temperature curing was higher than that of specimen with standard curing. 28 days age compressive strength of specimen with high temperature curing was less than or equal to that of specimen with standard curing.

A Study on Construction Methods of Roller Compacted Concrete Pavement for Bike Roads (자전거도로용 롤러 전압 콘크리트 포장의 시공 방안 연구)

  • Lee, Chang-Ho;Kim, Young-Kyu;Kang, Jae-Gyu;Park, Cheol-Woo;Lee, Seung-Woo
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.103-114
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    • 2011
  • Usage of bicycle has been supported the universal reduction of energy consumption and $CO_2$. For the same purpose, new constructions for long length bike roads are planned in Korea. Recently, laboratory tests of physical properties and resistance against environmental loading about optimum mix design of roller compacted concrete, that have advantages of high structural performance by cement hydration and aggregate interlocking, simple construction procedure and low construction cost, are performed for the effective construction of new bike roads. However, properties of roller compacted concrete had different results between laboratory and field tests since it had different compaction method. Also, construction method of roller compacted concrete are not defined for the application of bike roads since it had different demand performance such as thin pavement thickness, low strength and etc with road pavements. Thus, in this experimental research was launched to evaluate the core properties, visual inspection, compaction ratio, water content, thickness reduction rate of roller compaction, skid resistance and roughness by experimental construction about variable mix proportion and compaction method based on laboratory test results. And construction method of roller compacted concrete pavement were suggested for the application of bike roads.

Physical and Chemical Properties of Cement Mortar with Gamma-C2S

  • Lee, Sung-Hyun;Kim, Kyungnam;Mabudo, Mabudo;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.53 no.2
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    • pp.194-199
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    • 2016
  • Presently, for the cement industry, studies that seek to reduce $CO_2$, because of the development of the plastic industry and demand for reduction of energy use, have been actively conducted among them, studies attempting to use Gamma-$C_2S({\gamma}-C_2S)$ to fix $CO_2$ have been actively conducted. The ${\gamma}-C_2S$ compound has an important function in reacting to $CO_2$ and stiffening through carbonatization in the air. The ${\gamma}-C_2S$ compound, reacting to $CO_2$ in the air, generates $CaCO_2$ within the pore structure of cement materials and densifies the pore structure this leads to an improvement of the durability and to the characteristic of resistance against neutralization. Therefore, in this experiment, in order to synthesize ${\gamma}-C_2S$, limestone sludge and waste foundry sands are used these materials are plasticized for 30 or 60 minutes at $1450^{\circ}C$, and are prevented from being cooled in the temperature range of $30{\sim}1000^{\circ}C$ when they are about to be cooled. XRD analysis and XRF analysis are used to determine the effects of this process on ${\gamma}-C_2S$ synthesization, the temperature at which a thing is plasticized, and the conditions for cooling that obtain in the plasticized clinker also, in order to confirm the $CO_2$ capture function, analysis of the major hydration products is conducted through an analysis of carbonatization depth and compressive strength, and through MIP analysis and XRD Rietveld analysis. As a result of these analyses, it is found that when ${\gamma}-C_2S$ was synthesized, the clinker that was plasticized at $1450^{\circ}C$ for one hour demonstrated the highest yield rate the sample with which the ${\gamma}-C_2S$ was mixed generated $CaCO_3$ when it reacted with $CO_2$ therefore, carbonatization depth and porosity were reduced, and the compressive strength was increased.

Strength Development of Fiber Reinforced Lean Concrete Using Fly Ash and Reject Ash under Different Compaction Methods including Small Scale Roller Vibrator (플라이애쉬와 리젝트애쉬를 활용한 섬유보강 빈배합 콘크리트의 강도 특성 및 롤러다짐을 활용한 현장적용 실험)

  • Kim, Seung-Won;Jang, Young-Jae;Park, Young-Hwan;Park, Cheol-Woo
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.543-551
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    • 2012
  • Road pavements in Korea generally show shorter service life than the predicted one. There are many reasons for this phenomenon including increased traffic load and other attacks from exposure conditions. In order to extend a service life and upgrade the pavement, a new multi-functional composite pavement system is being developed in Korea. This study is to investigate the performances of fiber-reinforced lean concrete for pavement base. This study considered mineral admixtures of fly ash and reject ash. The reject ash is defined as ash that does not meet the specifications for fly ash so that it cannot be used as a supplemental material for cement replacement. Due to the inherent property of lean concrete, compaction during the fabrication of specimens is a key factor. Therefore, this study suggests an appropriate compaction method. From the test results, the compressive strengths of the concrete satisfied the required limit of 5 MPa at 7 days. When a compaction roller was used to mimic actual field conditions, the strength development seemed to be influenced by the compaction energy rather than hydration of cement itself.

Analysis of Relationship Between Compressive Strength and Compaction Ratio of Roller-Compacted Concrete Pavement (포장용 롤러전압콘크리트의 다짐도와 압축강도의 상관관계 분석)

  • Chung, Gun Woo;Song, Si Hoon;Lee, Seung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.6
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    • pp.1117-1123
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    • 2016
  • Roller-Compacted Concrete Pavement (RCCP) is a type of pavement that shares conventional concrete pavement material characteristics and asphalt pavement construction characteristics. Even though RCCP is compacted in the same way and have similar aggregate gradation to asphalt pavements, its materials and structural performance properties are similar to those of conventional concrete pavement. With cement hydration and aggregate interlock, Roller-Compacted Concrete or RCC can provide strength properties equal to those of conventional concrete with low cement content. Therefore, compaction ratio of RCC can highly influence on its strength. In general, 95% of compaction ratio is required for proper strength development. RCC strength can be highly influenced by compaction energy which depends on compaction equipment and compaction method. Therefore, it is necessary to analyze the relationship between compressive strength and compaction ratio of RCC. RCCP specimens were produced at different compaction ratio by using different compaction methods and energies. The compaction ratio was defined by the ratio of the specimen's dry density and its maximum dry density. The maximum dry density was obtained from Modified Proctor test. 28 days compressive strength corresponding to each compaction ratio case was tested. Finally, the relationship between compressive strength and compaction ratio can be analyzed. For application of roller-compacted concrete in domestic construction site, the relationship is important for field compaction management.

A Study on Setting Time and Early Strength of Tablet-Shaped Accelerators (타블렛 형태 급결제가 콘크리트의 응결시간 및 조기강도에 미치는 영향에 관한 연구)

  • Ryou, Jae-Suk;Lee, Yong-Soo
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.347-352
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    • 2011
  • When concrete is worked in cold weather, the methods of using hot air, water and aggregate heating, accelerators are used to prevent early frosting and to improve early strength. But these methods raise problems such as implementation difficulty, high cost, and energy losses. Among the available cold weathering methods, accelerator method is the most economical but with the drawbacks of rapid setting and insufficient workability in the initial hydration stage. Therefore, the tablet method usually used for pharmaceutical field was applied to the accelerator method to compare the controlled reaction time of the new and old accelerator method. Based on the test results, physical and mechanical properties of concrete were tested and the possibility of delaying initial reactions to increase the total reaction time was evaluated. The results showed that when both accelerators and tablet were used, setting-time decreased. Physical properties of concrete were optimal for tablet 0.5% and 1.0%. Also, accelerator 0.5%, tablet 0.5% and 1.0% showed good early strengths.

Effects of Gluten and Moisture Contents on Texturization of Extruded Soy Protein Isolate (글루텐 함량과 수분 함량이 압출성형 분리대두단백의 조직화에 미치는 영향)

  • Park, Ji-Hoon;Chatpaisarn, Apapan;Ryu, Gi-Hyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.4
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    • pp.473-480
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    • 2017
  • The aim of this study was to investigate the effects of gluten and moisture contents on the physical properties of extruded soy protein isolate. Extrusion conditions included various moisture (45, 50, and 55%) and gluten contents (20, 40, and 60%) at a fixed screw speed and die temperature of 250 rpm and $140^{\circ}C$, respectively. Specific mechanical energy input decreased as gluten content increased from 20 to 60%. Hydration ratio was highest ($293.23{\pm}13.68%$) at gluten and moisture contents of 20 and 55%, respectively. Lightness and yellowness increased as gluten content increased from 20 to 60% while redness decreased as gluten content increased. Color difference was the highest at low gluten and moisture contents. Integrity index was the highest ($71.15{\pm}0.93%$) at gluten and moisture contents of 60 and 45%, respectively. Nitrogen solubility index was not significantly affected by moisture content and was lowest ($22.46{\pm}1.11%$) at gluten and moisture contents of 60 and 55%, respectively. In conclusion, higher gluten and lower moisture contents were effective for texturization of soy protein isolate.

Variations of Complex Permittivity due to Water Content and Heavy Metal Contamination (함수비와 중금속 오염도에 따른 유전상수의 변화)

  • Oh Myoun-Hak;Kim Yong-Sung;Yoo Dong-Ju;Park Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.21 no.5
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    • pp.231-241
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    • 2005
  • Laboratory experiments were performed to examine the effects of water content and to see if permittivity had sufficient sensitivity to identify subsurface contamination. Both real and imaginary permittivities of unsaturated sand were strongly governed by the volumetric water content. Especially, a linear relationship between real permittivity and volumetric water content was derived at high frequencies (MHz ranges). Heavy metals in pore fluid result in significant increases in the effective imaginary permittivity, due to ionic conduction, but decreases in the real permittivity arises due to the decreased orientational polarization of water molecules caused by hydration of ions. Clear increase in the effective imaginary permittivity with heavy metal concentration was found to be valuable in the application of electrical methods for detecting heavy metals in the subsurface. However, because the permittivity is primarily dependent on the volumetric water content of soil, pre-evaluation on the volumetric water content is required.

Freeze-Thaw Resistance of Alkali Activated Ternary Blended Cement Incorporated with Ferronickel Slag (알칼리 활성화제를 첨가한 페로니켈슬래그 혼입 삼성분계 콘크리트의 동결융해 저항성)

  • Cho, Won-Jung;Park, Kwang-Pil;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.159-167
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    • 2022
  • The present study assessed the micro structure and durability characteristics of ternary blended cement with different types of alkali activators. Ground granulated blast furnace slag(GGBS) and ferronickel slag(FNS) was replaced until 50 % of the weight of cement. In addition, potassuim hydroxide and sodium hydroxide were used for comparing the properties of different type of alkali activator. Ternary blended cement with alkali activators showed higher peak portlandite peak than that of OPC(Ordinary Portlande Cement) and non activated ternary blended cement. Also, there was no new hydration products in ternary blended cement or/and alkali activators. Based on the mercury intrustion porosimetry(MIP) test result, ternary blended cement increased macro pore while alkali activated ternary blended cement modified pore structure and increased microp pore as compared to OPC as control. Combination with alkali activators is desirable to enhance the compressive strength and freeze thaw resistance.