• Title/Summary/Keyword: Hydration Reaction

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A Temperature Management of Mass Concrete for Crack Control in Machine Foundation (기계기초 매스콘크리트의 균열제어를 위한 온도관리)

  • 허택녕;이제방;손영현
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.394-401
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    • 1996
  • This paper persents the crack control of mass concrete in massive machine foundation. The dimension of the machine foundation is 52.6m$\times$14.4m$\times$8.5m. The one distinctive characteristic of mass concrete is thermal behavior. Since the cement-water reaction is exothermic by nature, the temperature rises inside the massive concrete structure. When the heat is not quickly dissipated, it can be quite high. Significant tensile stresses may develop from the volume change associated with the increase of decrease of temperature within the mass concrete structure. To avoid occurrence of harmful cracks due to hydration heat, special attention shall be given to the construction of mass cnocrete structures. The temperature control system of mass concrete is proposed in this paper. This system contains a discussion of materials and concrete mix proportioning, thermal analysis, curing method, temperature control, and measurement of hydration heat. As will be seen throughout the paper, the proposed temperature control system have a great effect on the temperature-related cracks on mass concrete structures.

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Diagnosis of Crack Occurrence of Very-Early Strength Latex-Modified Concretes through Field Tests (현장실험을 통한 VES-LMC 균열발생 원인분석)

  • Choi, Pan-Gil;Lee, Bong-Hak
    • Journal of Industrial Technology
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    • v.26 no.A
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    • pp.139-146
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    • 2006
  • Many concrete bridge decks develop transverse cracking shortly after construction. These cracks accelerate corrosion of reinforcing steel and lead to concrete deterioration, damage to components beneath the deck, unsightly appearance. These cracks shorten the service life and increase maintenance costs of bridge structures. In this study, VES-LMC overlay, which provides the same benefits as a conventional overlay, is designed to cure very quickly. Although the materials for VES overlays are more expensive, the cost is more than offset by the savings on traffic control and work zone safety measures. Otherwise, reaction of hydration occurs very rapidly in beginning step(concrete placing). As a results, thermal cracking can be occur by thermal stress in accordance with hydration-heat The purpose of this study was to estimate diagnosis of crack occurrence of VES-LMC through field tests at early-age.

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The Quality Control of Mass Concrete mixed with Fly-Asy (플라이애쉬를 혼합한 매스콘크리트의 품질관리)

  • 박칠림;권영호;이상수;김동석;박상준
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10b
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    • pp.940-945
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    • 1998
  • Recently, serious cracking problems have been reported in this country while the process of actual massive concrete construction. he hydration heat arising from the chemical reaction of cement with water causes temperature differentials in between inside and outside of a structural member, and these temperature differentials induce thermal stresses. In this paper, we described on the practical application and quality control of the mass concrete mixed with fly-ash. This project is investigating adiabatic temperature rise test of concrete, mock-up test in the laboratory, ad B/P before placing the mass concrete in site. As a result, we can be prevent temperature cracking from the cement hydration heat of mass concrete and also can be showed up secure quality control flow chart of mass concrete.

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Synthesis and Properties of Calcium Sulfoaluminate Type Expansive (칼슘설포알루미네이트계 팽창재의 제조 및 기초 물성)

  • 전준영;송종택
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.388-394
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    • 2000
  • The C4A3S clinker was prepared by the solid-state reaction. The mixture of raw materials; calcite, kaoline and gypsum, was fired at 135$0^{\circ}C$ for 1hr and cooled rapidly in air. C4A3S type expansive was made with C4A3S clinker, CaO and CaSO4. The cement replaced by 10 wt.% C4A3S type expansive was investigated by the measurement of the strength(compressive, tensile, flexural) and length change at various curing conditions. Hydration products were mainly ettringite, monosulfate and Ca(OH)2. The densification and the expansion due to the formation of ettringite during the hydration increased strength and reduced the drying shrinkage of hardened cement.

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The Characteristics of Isothermal Conduction Calorimetry and Specific Heat in Coal Gasification Slag (석탄 가스화 용융 슬래그의 비열 및 미소수화열 특성)

  • Han, Jun-Hui;Hu, Yun-Yao;Lim, Gun-Su;Kim, Su-Hoo;Kim, Jong;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.182-183
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    • 2021
  • In this study, This is the result of thermal characteristics analysis to suggest an efficient method of using coal gasification slag(CGS) of byproduct from integrated gasification combined cycle(IGCC). In Specific Heat characteristics, CGS and CS showed similar values. Isothermal Conduction Calorimetry showed that the hydration reaction of cement was retarded when CGS was used. Therefore, it is expected that CGS will be used as an efficient alternative to reducing the hydration heat of mass concrete as a functional aggregate combination.

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Hydration Characteristics Analysis of Conductive Grout Materials using XRD (X-선 회절분석을 활용한 전도성 그라우트재의 수화특성)

  • Im, Geon-Woo;Lim, Chang-Min;Kim, Young-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.35-36
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    • 2023
  • In this study, the hydration characteristics of conductive grout materials for each binder were investigated using XRD, and as a result of the experiment, the specimen with UFFA consumed more Ca(OH)2 than the specimen with other binders, which is judged to have activated the pozzolanic reaction of UFFA, a high powder.

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Evaluation of Hydration Heat Characteristics of Strontium Based Hydration Heat Reducer Addition on Concrete in Hot Weather Condition (서중환경에서 스트론튬계 수화열저감재를 사용한 콘크리트의 수화발열특성 평가)

  • Suh, Dong-Kyun;Kim, Gyu-Yong;Kil, Bae-Su;Koyama, Tomoyuki;Nam, Jeong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.189-196
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    • 2020
  • When concrete member become large like in high rise buildings, hydration heat makes temperature difference inside and outside and cause cracks. The method of using latent heat material as heat reducer could be more accessible, usable and efficient than other methods. Therefore, many studies using PCM as heat reducer are being conducted. Since heat reducer have different reacting temperature, they may be affected by environmental factors like ambient and concrete mixing temperature but studies issuing this are insignificant. Therefore, this paper attempt to evaluate the hydration heat characteristics and quality of concrete using strontium-based PCM under hot weather conditions. As a result, when the strontium-based hydration heat reducer was mixed 3wt.% and 5wt.% in hot weather condition, hydration heat speed and heating rate could be reduced by 8%, 21%, and 75, 85 minutes compared to OPC, respectively. This is considered to be the phase change reaction is relatively promoted when the temperature is high and cause improve performance than room condition result. Later, comparing the efficiency of other types of P.C.M in hot weather condition, and conduct detailed reviews on the strength development in long-term age.

Effects of Mineral Admixture on the Paste Fluidity and Mortar Strength Development of High Chloride Cement (염소 고함유시멘트의 페이스트 유동성과 모르타르 강도발현성에 미치는 무기질 혼화재의 영향)

  • Jeong, Chan-Il;Park, Soo-Kyung;Lee, Eui-Hak;Lee, Kyung-Hee
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.43-51
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    • 2007
  • Fluidity, setting time, hydration heat, bond water ratio, compressive strength, SEM and BET of OPC were measured by adding 1.0 wt% KCl and replacing 20 wt% mineral admixture in order to examine effects of blast furnace slag (BFS), limestone powder (LSP), and fly ash (FA) on fluidity and strength development of the cement contained much chloride. In general, the cement contained much chloride was high in heat of hydration, short in its setting time, low in its fluidity and low in its strength at 28 days due to the rapid hydration in its initial stage. As a result of the experiment, it has been demonstrated that fluidity became improved but the compressive strength at 28 days was decreased as replaced LSP to the cement contained much chloride. the fluidity and compressive strength at 28 days was improved as replaced BFS, the initial compressive strength development was improved due to the activation of initial reaction by KCl. Fluidity, initial compressive strength and late compressive strength at 28 days of cement contained much chloride replaced 5 wt% LSP and 15 wt% BFS concurrently was better than OPC, but the hydration heat was lower.

The Hydration Characteristics of High-Durable Portland Cement Treated with Asphalt and Carbon Black (ASPHALT와 CARBON BLACK으로 처리(處理)된 고내구성(高耐久性) 포틀랜드시멘트의 수화특성(水化特性))

  • Cho, Heon-Young;Kim, Hee-Rack;Hong, Won-Pyo
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.148-155
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    • 1992
  • For the enhancement of the concrete durability, we developed high - durable portland cement (ACTPC) by physical treatment of ordinary portland cement with asphalt and carbon black. In this research, the hydration reaction characteristics of ACTPC were studied by using SEM, X-Ray, Conduction Micro Calolimeter etc. When the ACTPC is mixed with water, it is believed the asphalt films on cement particles suppress the early stage of hydration reactions of cements, because the films hinder the contact with water and the elusion of soluble ions from particles. But the carbon blacks on the cement particles accelerated the hydration reactions of cement after a while, because the micro particles can be used as seed crystals in $CaO-SiO_2-H_2O$ gel formation.

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Effect of Limestone Powder on Hydration of C3A-CaSO4·2H2O System (C3A-CaSO4·2H2O 계의 수화반응에 미치는 석회석 미분말의 영향)

  • Lee, Jong-Kyu;Chu, Yong-Sik;Song, Hun
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.584-588
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    • 2011
  • In this work, effects of limestone powder on hydration of $C_3A-CaSO_4{\cdot}2H_2O$ system was discussed based on the XRD Quantitative analysis, and the possibility of Delayed Ettringite Formation was also discussed. The early hydration of $C_3A$ was delayed by addition of $CaCO_3$ powder. The delay effect was enhanced by increasing of $CaCO_3$ content and finer powder of $CaCO_3$ addition. After consumption of $CaSO_4{\cdot}2H_2O$, the reaction of $CaCO_3$ is started. Delayed Ettringite Formation would take place because monosulfoaluminate is not stable in presence of $CaCO_3$. In order to prevent the delayed ettringite formation in $C_3A-CaSO_4{\cdot}2H_2O-CaCO_3$ system, the reduction of monosulfoaluminate formation is important. Therefore, by increasing the amount of $CaCO_3$ addition and finer $CaCO_3$ powder addition, the delayed ettringite formation can be prevented.