• Macromolecular Research
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• v.10 no.6
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• pp.297-303
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• 2002

We have investigated the microstructural properties of a weakly charged polyelectrolyte modeled with both Hookean spring and Debye-Huckel potential, by employing a novel hybrid scheme of molecular dynamics (MD) and Monte Carlo (MC) simulations. Although the off-lattice pivot step facilitates the earlier computations stage, it gives rise to oscillations and hinders the stable equilibrium state. In order to overcome this problem, we adopt the MC off-lattice pivot step in early stage only, and then switch the computation to a pure MD step. The result shows that the computational speed-up compared to the previous method is entirely above 10 to 50, without loss of the accuracy. We examined the conformations of polyelectrolyte in solvents in terms of the end-to-end distance, radius of gyration, and structure factor with variations of the screening effects of solvent and the monomer charges. The emphasis can favorably be given on the elongation behavior of a polyelectrolyte chain, with observing the simultaneous snapshots.

• Journal of Hydrogen and New Energy
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• v.35 no.2
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• pp.230-239
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• 2024

Efforts are being made to replace ship diesel engines with electric propulsion motors in response to emission regulations. In particular, in the case of short-range small ships, research is being conducted to replace polymer electrolyte membrane fuel cells (PEMFC) with power sources. However, PEMFC has problems such as slow dynamic response characteristics and reduced durability at high temperatures. To solve this problem, a high-precision ship model was developed with power distribution and thermal management strategies applied, and through this, the required power, heat, and power characteristics of the propulsion system according to the ship's speed profile were analyzed.

• Journal of Hydrogen and New Energy
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• v.35 no.4
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• pp.437-450
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• 2024

Sustainable shipping depends on eco-friendly energy solutions. This paper reviews methods for predicting marine fuel cell performance, including empirical approaches, physical modeling, data-driven techniques, and hybrid methods. Accurate prediction models tailored to the marine environment's unique conditions are crucial for operational efficiency. By evaluating the strengths and weaknesses of each method, this study provides a comprehensive analysis of effective strategies for forecasting polymer electrolyte membrane fuel cell and solid oxide fuel cell performance in marine applications. These insights contribute to the advancement of eco-friendly shipping technologies and enhance fuel cell performance in challenging marine environments.

• Journal of Adhesion and Interface
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• v.18 no.1
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• pp.13-24
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• 2017

In this study, nanoparticles which encapsulated hydrophobic antimicrobial compounds with 50wt% of payload and 70%of solid content were prepared. These nanoparticles could be dispersed at water as well as various medium. Water dispersible organic-inorganic (O-I) hybrid nanoparticles were first prepared using alkoxysilane-functionalized amphiphilic polymer precursors through a conventional sol-gel process. Hydrophobic antimicrobial compound, Eugenol encapsulated nanoparticles were prepared using these O-I hybrid nanoparticles through a new nanoprecipitation process. The effect of various preparation on the size of nanoparticles, amount of payload, antimicrobial activity, and release rate of encapsulated compounds was investigated. All eugenol-encapsulated O-I nanoparticles regardless of preparation condition showed the same minimal inhibitory concentration (MIC) (50mg/ml) and 99% of antimicrobial activity for every strain. Their antimicrobial activity could maintain longer than two weeks. Especially, eugenol-encapsulated O-I nanoparticles prepared using tetraethoxysilane (TEOS) exhibited the highest payload (50wt%) and the lowest release rate which was owing to higher inorganic content in the O-I nanoparticles. And these O-I nanoparticles dispersed in hexanediol (HD) showed the highest antimicrobial activity and solid content (70wt%) because HD acted as a solvent as well as a antimicrobial agent.

• Bulletin of the Korean Chemical Society
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• v.25 no.7
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• pp.1025-1030
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• 2004

A hybrid linear polymer-dendrimer block copolymer, poly(ethylene glycol)-block-poly(L-lysine) dendrimer, was synthesized and introduced to form polyionic complexes with DNA. The copolymer formed core-shell type nanoparticles with plasmid DNA. From dynamic light scattering experiments, the mean diameter of the polyplexes was observed to be 154.4 nm. The complex showed much increased water solubility compared to poly(L-lysine). The plasmid DNA in polyplexes was efficiently protected from the enzymatic digestion of DNase I. The cytotoxicity and transfection efficiency for 293 cells was measured in comparison with poly(Llysine).

• Structural Engineering and Mechanics
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• v.51 no.6
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• pp.1047-1065
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• 2014

The article presents the methodology for finding material damping capacity at higher frequency and at relatively lower amplitudes. The Lamb wave dispersion theory and loss less finite element model is used to find the damping capacity of composite materials. The research has been focused on high frequency applications materials. The method was implemented on carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) plates. The Lamb waves were generated using ultrasonic pulse generator setup. The hybrid method has been explored in this article and the results have been compared with bandwidth methods available in the literature.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.230-230
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• 2006

Density functional theory (DFT) calculations using the B3LYP hybrid functional and the 6-311++G(d,p) basis set have been performed to predict the wavelength dispersion of optical absorbance and refractive indices for organic compounds and polymers in the range between the vacuum UV (${\sim}157\;nm$) and near-IR (${\sim}850\;nm$). The DFT calculations can reproduce the experimental dispersions of absorbance and refractive indices with high accuracy and low costs. The calculated dispersions demonstrate that the judicious introductions of $-F\;and\;-CF_{3}$ into alicyclic and heterocyclic compounds are effective in reducing the absorption at shorter wavelengths. In addition, the calculated Abbe numbers that represent the refractive index dispersion in the visble region are linearly proportional to the calculated refractive indices at 589 nm.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.315-315
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• 2006

A variable surface coating with the potential to fulfill the requirements of industry will be presented. Via controlled radical polymerization methods from a functionalized Polymethylsilsesquioxane delivers an inorganic-organic block copolymer, which can be easily modified and tuned for different applications. Spin coated or dip coated on various substrates show promising results. By using different block copolymers the contact angle on a silicon wafer can be varied in a range of $90^{\circ}\;up\;to\;145^{\circ}$ After curing and complete condensation a perfect adhesion on glasses, plastics and metals is achieved.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.1
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• pp.35-41
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• 2009

This paper proposes a stand alone type single-phase fuel cells micro-source with a voltage sag compensator for compensating the ac output voltage variations (sag or swell) of micro-source. The proposed micro-source is consist of a PEM(polymer electrolyte membrane) fuel cells simulator, a full bridge de converter, a 60Hz PWM(pulse width modulation) VSI(voltage source inverter), and a voltage sag compensator. Voltage sag compensator is similar to the configuration of hybrid series active power filter, and it is directly connected to micro-source through the injection transformer. Compensation algorithm of a voltage sag compensator adopts a single phase p-q theory. Effectiveness of the proposed the system is verified by the PSIM(power electronics simulation tool) simulation in the steady state and transient state which the proposed system is able to simultaneously compensate the harmonic current and source voltage sag or swell.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.1063-1064
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• 2008

Bimodal tram has a carbody made of polymer composite material which is good electrical insulator. As an series hybrid type, Alternating voltage generated from generator coupled with CNG engine are rectified and transformed to variable voltage ranges which are applied to electrical apparatus and ECUs equipped inside of the tram. The failures of electrical insulation between high voltage($400V{\sim}800V$) and low voltage(24V) or between different kind of voltages such as AC and DC may cause some electrical interferences to prevent from operating rightly and other safety problem. This paper have investigated about the degradation factors of the electrical insulation and the earthing method available to bimodal tram, which is effective for preventing the electromagnetic interference coming from the inside or outside of tram but need some detecting measurements of earth leakage through electrical systems.