• Title/Summary/Keyword: Hybrid coating system

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Syntheses and Mechanical Properties of Quaternary Cr-Si-O-N Coatings by Hybrid Coating System (하이브리드 코팅시스템에 의한 Cr-Si-O-N 코팅막 합성 및 기계적 성질)

  • Lee, Jeong-Doo;Wang, Qi Min;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.5
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    • pp.238-242
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    • 2010
  • In the present work, the influence of oxide on the Cr-Si-N coatings was investigated for the Cr-Si-O-N coatings on AISI 304 and Si wafer deposited by hybrid system, which combines the DC magnetron sputtering technique and arc ion plating (AIP) using Cr and Si target in an $Ar/N_2/O_2$ gaseous mixture. As the O content in the Cr-Si-N coatings increased, the diffraction patterns of the Cr-Si-O-N coatings showed CrN and $Cr_2O_3$ phases. However, as the O content increased to 28.8 at.%, diffraction peak of $Cr_2O_3$ was disappeared in the Cr-Si-O-N coating. The $d_{200}$ value was decreased with increasing of O content. The average grain size increased from about 40 nm to 65 nm as the O content increased. The maximum micro-hardness of the Cr-Si-O-N coating was obtained 4507 Hk at the O content of 24.8 at.%. The average friction coefficient of the Cr-Si-O-N coatings was gradually decreased by increasing the O content and the average friction coefficient decreased from 0.37 to 0.25 by increasing the O content. These results indicated that amorphous phase was increased in the Cr-Si-O-N coatings by increasing of O content.

Development of AgNW/Reduced Graphene Oxide Hybrid Transparent Electrode with Long-Term Stability Using Plasma Reduction (플라즈마 환원 기술을 응용한 장수명의 은나노와이어/Reduced Graphene Oxide 하이브리드 투명전극 개발)

  • Jung, Sunghoon;Ahn, Wonmin;Kim, Do-Geun
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.87-91
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    • 2016
  • The development of high performance transparent electrode with flexibility have been required for flexible electronics. Here, we demonstrate the silver nanowire and reduced graphene oxide hybrid transparent electrode for replacing brittle indium-tin-oxide electrode by spray coating technique and plasma reduction. The spray coating system is applied to deposit silver nanowire and over coated graphene oxide films and it has a great potential to scale-up. The resistance of silver nanowire transparent electrode is reduced by 10% and the surface roughness is decreased after graphene oxide coating. The over-coated graphene oxide is successfully reduced by $H_2$ plasma treatment and it is effective in increasing the environmental stability of electrode. The lifetime of silver nanowire and reduced graphene oxide hybrid electrode at $85^{\circ}C$ of Celsius degree of temperature and 85% of relative humidity has much increased.

Corrosion Resistance by Organic/Inorganic Hybrid Solution for Cold Rolled Steel of SPCC and SPFC590 for Automobile (자동차용 냉연강판 SPCC와 냉연고장력강판 SPCF590의 유/무기 하이브리드 용액에 의한 내식특성)

  • Lee, So-Young;Lee, Kwang-Ho;Jeong, Hee-Rok;Nam, Ki-Woo
    • Journal of Power System Engineering
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    • v.19 no.5
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    • pp.38-44
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    • 2015
  • The cold-rolled steel sheet for automobile is liable to corrosion, and will be painting in a variety of ways for the anticorrosive. This paper was coated on cold rolled steel (SPCC and SPFC590) for automobiles using five kinds of organic/inorganic hybrid solution. This was evaluated corrosion resistance and so on by the salt spray. Corrosion area was less according to increasing of curing time in 2 types of steel plate with 5 types of the coating solution. No.1 solution was showed the best corrosion resistance regardless of the kinds of the steel sheet. It is judged that the melamin hardner had the role of bridge between $SiO_2$ polysilicate and urethan resin. Other properties were excellent in all solution.

Corrosion Resistance of SPCC, SPFC590, SPFC780 Steel by Organic/Inorganic Hybrid Solution (Case of different SiO2 polysilicate under a constant melamin) (유/무기하이브리드 용액에 의한 SPCC, SPFC590, SPFC780 강판의 내식성 (일정한 멜라민에서 SiO2 polysilicate 양이 다른 경우))

  • Nam, Ki-Woo;Jeong, Hee-Rok;Lee, Kwang-Ho
    • Journal of Power System Engineering
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    • v.21 no.2
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    • pp.5-13
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    • 2017
  • This study has developed an organic/inorganic hybrid solution according to amount of $SiO_2$ polysilicate, and the amount of melamine is constant. The three types of cold rolled steel were evaluated a corrosion resistance properties by using these solutions. $US_3M_3$ and $US_{11}M_3$ solutions were generate a lot of corrosion. $US_7M_3$ solution was excellent in corrosion resistance, regardless of the steel type. The appearance of coating by $US_3M_3$ and $US_{11}M_3$ solutions were bumpy surface, and were a lot of fine defects. $US_7M_3$ solution was made a sophisticated molecular cross-linking structure inside the coating, it was a slick surface. Other characteristics are exhibited the excellent property for all solutions.

Corrosion Resistance of Degraded STS310S and STS347H by Cr-free Modified Si Organic/Inorganic Hybrid Coating Solution (Cr-free Si 변성 유/무기하이브리드 코팅액에 의한 열화된 STS310S 및 STS347H의 내식성)

  • Lee, So-Young;Kim, Young-Soo;Jeong, Hee-Rok;Kim, Gui-Shik;Nam, Ki-Woo
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.12-18
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    • 2015
  • Austenitic stainless steels generally experience the occurrence of chromium-depleted zones at the boundaries, known as sensitization, caused by the carbide precipitation that takes place due to a welding process or heat treatment. Normally, the depleted zones become the focus of the intense corrosion. In this study, the Cr-free organic/inorganic hybrid solution was developed, and the artificially degraded STS316S and STS347H with the solution-coating investigated the corrosion resistance by salt spray test. Both the OIBD-1 and OIBD-2 solutions improved the corrosion resistance of STS310S and STS347H. The corrosion resistance with the OIBD-1 solution was better than that of OIBD-2 solution. Additionally, Both solutions have been proven excellence in adhesion ability, boiling water resistance and flexibility. However, a problem of rubbing after the boiling was found out to be overcome.

Corrosion Resistance of Cold Rolled Steel by Organic/Inorganic Hybrid Solution according to Composition of SiO2 polysilicate and Melamine (SiO2 polysilicate 및 Melamine 조성에 따른 유/무기하이브리드 용액에 의한 자동차용 냉연강판의 내식성)

  • Nam, Ki-Woo;Jeong, Hee-Rok;Ahn, Byung-Gun;Lee, Kwang-Ho
    • Journal of Power System Engineering
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    • v.20 no.5
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    • pp.20-28
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    • 2016
  • This study has developed an organic/inorganic hybrid solution by addition of $SiO_2$ polysilicate and Melamine to the urethane. The three types of cold rolled steel were evaluated a corrosion resistance properties by using these solutions. The urethane solution(U) and the urethane solution with $SiO_2$ polysilicate($US_7$) were generate a lot of corrosion. The urethane solution with $SiO_2$ polysilicate and melamine($US_7M_3$) was excellent in corrosion resistance, regardless of the steel type. In addition, corrosion resistance has been shown to depend on the tensile strength. The appearance of coating by U and $US_7$ solution is bumpy surface, and were a lot of fine defects. $US_7M_3$ solution is made a sophisticated molecular cross-linking structure inside the coating, it was a slick surface. Other characteristics are exhibited the excellent property for all solutions.

Microstructure and Mechanical Properties of Mo-Si-N Coatings Deposited by a Hybrid Coating System (하이브리드 코팅시스템에 의해 제조된 Mo-Si-N 박막의 미세구조 및 기계적 특성연구)

  • Heo, Su-Jeong;Yun, Ji-Hwan;Kang, Myung-Chang;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.39 no.3
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    • pp.110-114
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    • 2006
  • In this work, comparative studies on microstructure and mechanical properties between $Mo_2N$ and Mo-Si-N coatings were conducted. Ternary Mo-Si-N coatings were deposited on AISI D2 steel substrates by a hybrid method, where AIP technique was combined with a magnetron sputtering technique. Instrumental analyses of XRD, HRTEM, and XPS revealed that the Mo-Si-N coatings must be a composite consisting of fine $Mo_2N$ crystallites and amorphous $Si_3N_4$. The hardness value of Mo-Si-N coatings significantly increased from 22 GPa of $Mo_2N$ coatings to about 37 GPa with Si content of 10 at.% due to the refinement of $Mo_2N$ crystallites and the composite microstructure characteristics. The average friction coefficient of the Mo-Si-N coatings gradually decreased from 0.65 to 0.4 with increasing Si content up to 15 at.%. The effects of Si content on microstructure and mechanical properties of Mo-N coatings were systematically investigated.

An Optimal Die Design for the Coating Uniformity of Non-Newtonian Liquids in Slot Coating Process (Slot 코팅 공정에서 Non-Newtonian 유체의 코팅 균일성을 위한 최적 다이 설계)

  • Lee, Si-Hyung;Koh, Hyun-Jung;Shim, Seo-Hoon;Jung, Hyun-Wook;Hyun, Jae-Chun
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.314-319
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    • 2011
  • In this study, the flow behavior of Newtonian and non-Newtonian coating liquids inside slot die has been scrutinized for the purpose of optimal internal die design in slot coating system from three-dimensional computations by CFD Fluent solver. A hybrid slot die could be optimally designed by changing the chamber or manifold structure to guarantee the uniform velocity distribution of coating liquids at die exit. Especially, for the non-Newtonian coating liquids, the length of coat-hanger for the uniform coating has been properly chosen, according to the degree of their shearthinning properties.