• 제목/요약/키워드: Hybrid coating

검색결과 314건 처리시간 0.029초

염료감응형 태양전지의 효율 향상을 위한 하이브리드 구조 광전극의 코팅특성 (Coating Property of Hybrid Structured Photo-Electrode to Increase Dye-Sensitized Solar Cells Efficiency)

  • 김민희;이형우;정영근
    • 한국분말재료학회지
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    • 제17권6호
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    • pp.449-455
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    • 2010
  • The hybrid structured photo-electrode for dye-sensitized solar cells was fabricated based on the composites of $TiO_2$ nanoparticles and nanowires. Three samples with different hybrid structures were prepared with 17 vol%, 43 vol%, and 100 vol% nanowires. The energy conversion efficiency was enhanced from 5.54% for pure nanoparticle cells to 6.01% for the hybrid structure with 17 vol% nanowires. For the hybrid structured layers with high nanowires concentration (43 vol% and 100 vol%), the efficiency decreased with the nanowire concentration, because of the decrease of specific surface area, and of thus decreased current density. The random orientations of $TiO_2$ nanowires can be preserved by the doctor blade process, resulted in the enhanced efficiency. The hybrid structured $TiO_2$ layer can possess the advantages of the high surface area of nanoparticles and the rapid electron transport rate and the light scattering effect of nanowires.

Investigation of Corrosion Fatigue Phenomena in Transient Zone and Preventive Coating and Blade Design against Fouling and Corrosive Environment for Mechanical Drive Turbines

  • Hata, Satoshi;Nagai, Naoyuki;Yasui, Toyoaki;Tsukamoto, Hiroshi
    • International Journal of Fluid Machinery and Systems
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    • 제1권1호
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    • pp.121-139
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    • 2008
  • For mechanical drive steam turbines, the investigation results of corrosion fatigue phenomena in the transient zone are introduced, including basic phenomena on expansion line and actual design and damage experience. These results were analyzed from the standpoint of stress intensity during the start of cracking. In order to resolve such problems, preventive coating and blade design methods against fouling and corrosive environments are developed. Detailed evaluation test results are given for coating performance using a unique test procedure simulating fouling phenomena and washing conditions. Finally, the results of the successful modification of internals and on-line washing results on site are introduced.

동결융해 이후의 FRP Hybrid Bar의 부식 저항성 (Resistance to Chloride Attack of FRP Hybrid Bar After Freezing and Thawing Action)

  • 류화성;박기태;윤용식;권성준
    • 한국건설순환자원학회논문집
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    • 제6권1호
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    • pp.59-65
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    • 2018
  • 콘크리트 구조물은 다양한 환경에 노출되며, 부식환경인 해안가에서는 매립 보강재의 부식저항성 및 동결융해 저항성이 함께 평가되어야 한다. 최근 개발된 FRP Hybrid Bar는 내부에 강재가 있으며 유리섬유와 에폭시가 코팅된 보강재인데, 기존 FRP Bar보다 탄성계수가 높은 장점이 있다. 본 연구에서는 FRP Hybrid Bar에 대하여 동결융해 300 cycle 시험을 수행한 뒤, 내부식특성과 중량결손율, 및 부착특성을 평가하였다. 300 cycle 이후 2번 에폭시를 코팅한 경우에 규사의 손실이 가장 적었으며, 외관의 결함이 관측되지 않았다. 부착강도는 규사코팅에 따른 조도의 증가로 FRP Hybrid Bar의 경우 일반철근의 120 % 수준을 나타내었다. 또한 일반철근을 가진 시편의 부착력은 부식시간 3일에서는 0.86 ~ 0.89 배, 5일에서는 0.35~0.38 배로 크게 감소하였으나, 동결융해 전후의 FRP Hybrid Bar를 가진 콘크리트 공시체는 부착강도의 감소가 발생하지 않았다.

투명 유-무기 하이브리드 하드코팅 필름 제조 및 SiO2 또는 ZrO2함량에 따른 필름의 물성 (Preparation of Transparent Organic-Inorganic Hybrid Hard Coating Films and Physical Properties by the Content of SiO2 or ZrO2 in Their Films)

  • 설현태;나호성;권동주;김정섭;김대성
    • 한국재료학회지
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    • 제27권1호
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    • pp.12-18
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    • 2017
  • Transparent organic-inorganic hybrid hard coating films were prepared by the addition of $SiO_2$ or $ZrO_2$, as an inorganic filler to improve the hardness property, filler was highly dispersed in the acrylic resin. To improve the compatibility in the acrylic resin, $SiO_2$ or $ZrO_2$ is surface-modified using various silanes with variation of the modification time and silane content. Depending on the content and kind of the modified inorganic oxide, transparent modified inorganic sols were formulated in acryl resin. Then, the sols were bar coated and cured on PET films to investigate the optical and mechanical properties. The optimized film, which has a modified $ZrO_2$ content of 4 wt% markedly improved in terms of the hardness, haze, and transparency as compared to neat acrylate resin and acrylate resin containing modified $SiO_2$ content of 8 wt%. Meanwhile, the low transparency and high haze of these films slowly appeared at $SiO_2$ content above 10 wt% and $ZrO_2$ content of 5 wt%, but the hardness values were maintained at 2H and 3H, respectively, in comparison with the HB of neat acrylate resin.

유전체 장벽 방전-광촉매 복합공정에 의한 NO와 $SO_2$ 제거 (NO and $SO_2$ Removal by Dielectric Barrier Discharge-Photocatalysts Hybrid Process)

  • 김동주;;김교선
    • 청정기술
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    • 제13권2호
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    • pp.115-121
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    • 2007
  • 본 연구에서는 유전체 장벽 방전-광촉매 복합 공정에 의한 NO 및 $SO_2$ 제거를 실험적으로 분석하였다. 유전체 장벽 방전을 위해 유전체로서 유리구가 사용되었고 $TiO_2$ 광촉매 입자는 딥코팅(dip-coating) 방법에 의해 높은 비표면적을 가지는 스펀지 형태로 유리구에 코팅되었다. 플라즈마 반응기에 인가된 전압이나 펄스 주파수, 혹은 기체의 체류시간이 증가함에 따라, NO 및 $SO_2$의 제거효율은 증가하였다. NO 및 $SO_2$ 공급농도 증가하면 NO 및 $SO_2$ 제거에 더 많은 에너지가 요구되어 NO 및$SO_2$의 제거효율이 감소하였다. 본 연구의 실험 결과들은 NO 와 $SO_2$를 제거하기 위한 유전체 장벽 방전-광촉매 복합 공정 설계의 기초 자료로 사용될 수 있다.

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하이브리드 슈퍼코팅(HSC)과 유리섬유를 통한 조적조 내진보강 연구 (Experimental Study of Hybrid Super Coating (HSC) and Cast Reinforcement for Masonry Wall)

  • 이가윤;문아해;이승준;김재현;이기학
    • 한국지진공학회논문집
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    • 제25권5호
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    • pp.213-221
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    • 2021
  • Many Korean domestic masonry structures constructed since 1970 have been found to be vulnerable to earthquakes because they lack efficient lateral force resistance. Many studies have shown that the brick and mortar suddenly experience brittle fracture and out-of-plane collapse when they reach the inelastic range. This study evaluated the seismic retrofitting of non-reinforced masonry with Hybrid Super Coating (HSC) and Cast, manufactured using glass fiber. Four types of specimen original specimen (BR-OR), one layered HSC (BR-HS-O), two-layered HSC (BR-HS-B), one layered HSC, and Cast (BR-CT-HS-O) were constructed and analyzed using compression, flexural tensile, diagonal compression, and triplet tests. The specimen responses were presented and discussed in load-displacement curves, maximum strength, and crack propagation. The compressive strength of the retrofit specimens slightly increased, while the flexural tensile strength of the retrofit specimens increased significantly. In addition, the HSC and Cast also produced a considerable increase in the ductile response of specimens before failure. Diagonal compression test results showed that HSC delayed brittle cracks between the mortar and bricks and resulted in larger displacement before failure than the original brick. The triplet test results confirmed that the bonding strength of the retrofit specimens also increased. The application of HSC and Cast was found to restrain the occurrence of brittle failure effectively and delayed the collapse of masonry wall structures.

Hydroxyethyl Methacrylate와 Methyl Methacrylate의 첨가량 변화가 수분산 폴리우레탄-아크릴 혼성 용액의 물성에 미치는 영향 (Effect of Addition Amounts of Hydroxyethyl Methacrylate and Methyl Methacrylate on the Properties of Waterborne Polyurethane-Acrylic Hybrid Solutions)

  • 김병석;유병원;이명구;변태강;송기창
    • Korean Chemical Engineering Research
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    • 제50권4호
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    • pp.632-638
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    • 2012
  • Isophorone diisocyanate (IPDI), polycarbonate diol (PCD), dimethylol propionic acid (DMPA)를 출발물질로 하여 수분산 폴리우레탄(waterborne polyurethane dispersion, PUD)을 합성하였다. 이 PUD에 아크릴 단량체인 HEMA (2-hydroxyethyl methacrylate)와 MMA (methyl methacrylate)의 혼합물을 첨가하여 수분산 폴리우레탄-아크릴 혼성 용액을 제조하였다. 그 결과 제조된 혼성 용액의 평균 입도는 아크릴 단량체의 첨가량이 증가함에 따라 증가하였다. 또한 수분산 폴리우레탄-아크릴 혼성 용액으로부터 제조된 코팅 도막의 내마모성과 내화학성은 순수한 PUD 보다 크게 향상되었다.