• Title/Summary/Keyword: Hybrid Material

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Synthesis of Amorphous Er3+-Yb3+ Co-doped TiO2 and Its Application as a Scattering Layer for Dye-sensitized Solar Cells

  • Han, Chi-Hwan;Lee, Hak-Soo;Lee, Kyung-Won;Han, Sang-Do;Singh, Ishwar
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.219-223
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    • 2009
  • $TiO_2$ doped with $Er^{3+\;and\;Yb^{3+}$ was used for fabricating a scattering layer and a nano-crystalline $TiO_2$ electrode layer to be used in dye-sensitized solar cells. The material was prepared using a new sol-gel combustion hybrid method with acetylene black as fuel. The $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide powder synthesized at 700oC had embossed structure morphology with a size between 27 to 54 nm that agglomerated to produce micron size particles, as observed by the scanning electron micrographs. The XRD patterns showed that the $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide had an amorphous structure, while using the same method without doping $Er^{3+}\;or\;Yb^{3+},\;TiO_2$ was obtained in the crystallite form with thea dominance of rutile phase. Fabricating a bilayer structure consisting of nano-crystalline $TiO_2$ and the synthesized $Er^{3+}$-$Yb^{3+}$ co-doped titanium oxide showed better scattering property, with an overall increase of 15.6% in efficiency of the solar cell with respect to a single nano-crystalline $TiO_2$ layer.

Mechanical Properties Evaluation of Gas Tungsten Arc Welding for INCONEL 718 alloy apply to Cryogenic Condition (극저온 환경에 적용되는 INCONEL 718합금의 Gas Tungsten Arc Welding 기계적 특성 평가)

  • Kim, Ki-Hong;Moon, In-Sang;Moon, Il-Yoon;Rhee, Byung-Ho
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.692-698
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    • 2009
  • Inconel 718 alloy has excellent mechanical properties at room temperature, high temperature and cryogenic conditions. UTS of base metal is about 900MPa at room temperature; this is increased up to 1300MPa after heat treatment & aging-hardening. Mechanical properties of Inconel 718 Alloy were similar to those shown in the the results for tensile test; mechanical properties of Inconel 718 alloy's GTAW were similar to those of base metal's properties at room temperature. Mechanical properties at cryogenic conditions were better than those at room temperature. Heat-treated Inconel 718, non- filler metal GTAW on Inconel 718 and GTAW used filler metal on Inconel 718's UTS was 1400MPa at cryogenic condition. As a result, the excellent mechanical properties of Inconel 718 alloy under cryogenic conditions was proved through tensile tests under cryogenic conditions. In addition, weldability of Inconel 718 alloy under cryogenic conditions was superior to that of its base-metal. In this case, UTS of hybrid joint (IS-G) at -100$^{\circ}C$ was 900MPa. Consequently, UTS of Inconel 718 alloy is estimated to increase from -100$^{\circ}C$ to a specific temperature below -100$^{\circ}C$. Therefore, Inconel 718 alloy is considered a pertinent material for the production of Lox Pipe under cryogenic conditions.

The Study on the Silver Fashion Icon Iris Apfel's Fashion Style (실버 패션 아이콘 Iris Apfel의 패션 스타일에 관한 연구)

  • Kim, Janghyeon;Kim, Youngsam
    • Journal of Fashion Business
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    • v.24 no.3
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    • pp.101-113
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    • 2020
  • This study considers aesthetic characteristics by examining the fashion style of the silver fashion icon Iris Apfel. The research methods were a quantitative and qualitative analysis of Iris Apfel's images that were collected from 2015 to 2019 on various web-sites according to four criterions following advanced research analysis of fashion style. The results of the study are as follows. The analysis results on the fashion style of Iris Apfel, an icon of silver style, showed that cocoon, barrel and A-line silhouettes appeared most in terms of silhouettes. Second, in terms of colors, achromatic colors dominated among solid colors while one particular vivid color appeared most it came to mixed color. In terms of multi colors, these appeared according to the patterns applied to her clothing, in particular, colorful colors were used to emphasize splendor. Third, flower, bird and geometric patterns appeared most in terms of material patterns. Lastly, it was found that white short cut hair, large necklaces or bangle bracelets, over-sized black glasses and fur mufflers or canes were used in terms of hair and accessories. The features derived through analysis of the fashion style of Iris Apfel, an icon of silver style, are as follows. The first feature is exaggeration through splendid primary colors and over-sized silhouettes. The second feature is the hybrid of modern composition methods using natural images and exotic preferences. The third feature is her representation of identity using fixed items.

A Study on the Strength Safety of a Gas Valve (가스밸브의 강도안전성에 관한 연구)

  • Kim, Chung Kyun
    • Journal of the Korean Institute of Gas
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    • v.22 no.1
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    • pp.60-63
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    • 2018
  • This paper presents the FEM analysis results on the strength safety of a gas valve for a LPG cylinder. Based on the FEM analysis, the maximum von Mises stress on the boundary zone between a safety valve and the upper area of the thread is 99.2 MPa for the supplied gas pressure of 3.5 MPa in which the gas valve is fully opened. The maximum von Mises stress of 99.2 MPa is considered as safety value, because that value is lower than the yield stress of a brass material. In this case, the maximum deformation at the upper right part of the pressure regulator is 0.002mm. The maximum deformation zone is not a meaning part of the sealing part such as an O-ring or a diaphragm of a gas valve and a pressure regulator. The proposed hybrid gas valve model in which is integrated with a conventional cut-off valve and a pressure regulator is recommended as a gas leakage free mechanism and minimized compact size for a LPG cylinder.

Evaluation of Flexural Strength for UHPC Deck Joints with Lap-Spliced Reinforced Steel Bar (UHPC 바닥판 철근겹침이음 연결부의 휨강도 평가)

  • Hwang, Hoon Hee;Yeo, In Soo;Cho, Keun Hee;Park, Sung Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.6
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    • pp.92-99
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    • 2011
  • Ultra High Performance Concrete(UHPC) is a superior structural material with high strength and durability. Construction of light and slim structures is realized to apply this expectable new materials in practice. This research is a part of the project to develop UHPC precast deck system for hybrid cable stayed bridge. The main object of this study is to investigate behavior of the lap-spliced reinforced connection in UHPC. The major parameter considered in experimental plan was lap-spliced length. The 4-points bending test for 12 specimens were conducted to verify the effect of considered parameters. Test results show that the minimum value of lap spliced length of 300mm which specified in current korea high bridge design code was very conservative for UHPC precast deck system.

Numerical and Experimental Investigation on Impact Performance of Fiber Metal Laminates Based on Thermoplastic Composites (열가소성 복합재료를 기반한 섬유금속적층판의 충격 거동에 관한 실험 및 수치적 연구)

  • Lee, Byoung-Eon;Kang, Dong-Sik;Park, Eu-Tteum;Kim, Jeong;Kang, Beom-Soo;Song, Woo-Jin
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.5
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    • pp.566-574
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    • 2016
  • Fiber metal laminates, which are hybrid materials consisting of metal sheets and composite layers, have contributed to aerospace and automotive industries due to their reduced weight and improved damage tolerance characteristics. In this study, the impact performance of the laminates, which are comprised of a self-reinforced polypropylene and two aluminum sheets, and the pure aluminum alloy sheet material were investigated experimentally via numerical simulation. In order to compare the impact performance, the laminates and aluminum alloy were examined by assessing the impact force, energy time histories, and specific energy absorption. ABAQUS is a commercial software that is used to simulate the actual drop-weight tests. Based on this study, it is noted that the impact performance of the laminates was superior to that of the aluminum alloy. In addition, a good agreement between the experimental and numerical results can be achieved when the impact force and energy time histories from the experiments and the numerical simulations are compared.

A Study on the Development of Defense Performance Specification and Conversion into it (국방 성능형 규격 작성 및 전환 방안에 관한 연구)

  • Choi, Seok-Cheol;Song, Yu-Ha
    • Journal of the military operations research society of Korea
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    • v.33 no.1
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    • pp.135-155
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    • 2007
  • A performance specification states requirements in terms of the required results, such as performance, environment and interchangeability, but without stating the methods for achieving the required results, such as material and process. therefore the performance specification is applied to attain economic efficiency and high reliability by using the advanced commercial Technology for the weapon systems and The development of performance specification and conversion into performance specification have been activated in the advanced nations. The Ministry of National Defence of Korea has regulated the specification to make performance type in developing specification and prepared performance specification guide. but the result of the development of and conversion into performance specification is very unsatisfactory, To efficiently develop and convert into performance specification, this study gives the way of market research, the creation of the performance specification from development of weapon system and part localization, the process and method for conversion of detail specification into performance specification, the use of hybrid type of performance and detail specification.

Effect of Aluminum on Nitrogen Solubility in Zinc Oxide: Density Functional Theory (산화 아연에서의 질소 용해도에 대한 알루미늄의 효과 : 밀도 범함수 이론)

  • Kim, Dae-Hee;Lee, Ga-Won;Kim, Yeong-Cheol
    • Korean Journal of Materials Research
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    • v.21 no.12
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    • pp.639-643
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    • 2011
  • Zinc oxide as an optoelectronic device material was studied to utilize its wide band gap of 3.37 eV and high exciton biding energy of 60 meV. Using anti-site nitrogen to generate p-type zinc oxide has shown a deep acceptor level and low solubility. To increase the nitrogen solubility in zinc oxide, group 13 elements (aluminum, gallium, and indium) was co-added to nitrogen. The effect of aluminum on nitrogen solubility in a $3{\times}3{\times}2$ zinc oxide super cell containing 72 atoms was investigated using density functional theory with hybrid functionals of Heyd, Scuseria, and Ernzerhof (HSE). Aluminum and nitrogen were substituted for zinc and oxygen sites in the super cell, respectively. The band gap of the undoped super cell was calculated to be 3.36 eV from the density of states, and was in good agreement with the experimentally obtained value. Formation energies of a nitrogen molecule and nitric oxide in the zinc oxide super cell in zinc-rich conditions were lower than those in oxygen-rich conditions. When the number of nitrogen molecules near the aluminum increased from one to four in the super cell, their formation energies decreased to approach the valence band maximum to some degree. However, the acceptor level of nitrogen in zinc oxide with the co-incorporation of aluminum was still deep.

Study on the Mechanical Properties of Hybridized Carbon Fiber Composite According to Stacking Structure (하이브리드 탄소섬유 적층구조에 따른 복합재료의 기계적 특성 연구)

  • Koo, Seon Woong;Oh, Woo Jin;Won, Jong Sung;Lee, Ha Ram;Youn, Ju Young;Lee, Seung Goo
    • Textile Coloration and Finishing
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    • v.30 no.4
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    • pp.313-320
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    • 2018
  • As carbon fiber reinforced composites(CFRP) are widely used in aerospace, automobile, marine, and sports goods applications, they have been studied extensively by various researchers. However, CFRP have been pointed out because of machining problems such as delamination and burr phenomenons. Especially, hole machining process, drilling, has non-smooth features on inlet and outlet surfaces of drilled hole. This kind of machining problem can be controlled to some extent by using high modulus pitch-CF, which has considerable effects on fracture behavior of composite compared with only PAN CF composite. Therefore, PAN and pitch hybridized CF composites were prepared having high strength and modulus. The results demonstrate that the hybrid CFRP specimens with pitch CF offer the good potential to enhance modulus as well as strength properties. Dynamic mechanical, flexural, and impact properties were measured and analyzed. Morphological surface of the composites were also observed by IFS-28, canon after hole machining.

Printability of Thermally and Chemically Stable Silica-Titanium Dioxide Composite Coating Layer (실리카-이산화티탄 복합 코팅층의 열적, 화학적 안정성 및 인쇄적성 평가)

  • Kim, Hye Jin;Han, Kyu Sung;Hwang, Kwang Taek;Nahm, Sahn;Kim, Jin Ho
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.631-638
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    • 2019
  • As automation systems become more common, there is growing interest in functional labeling systems using organic and inorganic hybrid materials. Especially, the demand for thermally and chemically stable labeling paper that can be used in a high temperature environment above $300^{\circ}C$ and a strong acid and base atmosphere is increasing. In this study, a composite coating solution for the development of labeling paper with excellent thermal and chemical stability is prepared by mixing a silica inorganic binder and titanium dioxide. The silica inorganic binder is synthesized using a sol-gel process and mixed with titanium dioxide to improve whiteness at high-temperature. Adhesion between the polyimide substrate and the coating layer is secured and the surface properties of the coating layer, including the thermal and chemical stability, are investigated in detail. The effects of the coating solution dispersion on the surface properties of the coating layer are also analyzed. Finally, it is confirmed that the developed functional labeling paper showed excellent printability.