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Investigation on optimum applied potential for corrosion resistance and cavitation-erosion damage reduction of Al alloy in seawater (알루미늄 합금의 해수 내 내식성 및 캐비테이션-침식 손상 저감을 위한 적용전위 규명)

  • Jeong, Gwang-Hu;Park, Il-Cho;Lee, Jeong-Hyeong;Han, Min-Su;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.112-112
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    • 2018
  • 알루미늄 합금은 내구성과 내식성이 우수한 경량 재료이다. 그 중 Al-Mg계 5083 Al 합금은 가공성 및 용접성이 우수하여 선체 재료로 널리 이용되고 있다. 이는 선체 중량의 경량화로 인해, 연료비 절감과 빠른 선속 등 다양한 이점을 지니기 때문이다. 그러나 선박의 고속화에 따라 선체에 가해지는 유체충격이 증가하고, 압력 저하에 기인하여 캐비테이션-침식 손상이 증가할 뿐만 아니라, 염소이온이 존재하는 해수환경에서는 침식과 부식의 시너지효과로 인하여 재료의 손상이 더욱 가속화된다. 이에 대한 다양한 방지책들이 제안되고 있으나, 강한 충격압을 동반한 캐비테이션 침식-부식 복합 손상 환경에서는 다소 한계가 있다. 따라서 본 연구에서는 알루미늄 5083에 대하여 캐비테이션 환경 하에서 일정 전위를 인가하며 침식-부식 손상이 최소화 되는 전위 구간을 규명하고자 하였다. 먼저, 분극 실험을 선행하여 재료의 전기화학적 거동을 파악 한 후 적용 전위구간을 선정하여, 해당 전위를 인가한 상태에서 캐비테이션 실험을 실시하였다. 전기화학적 분극실험과 캐비테이션-전기화학 복합 실험은 $25^{\circ}C$의 해수 하에서 실시하였으며, 시험편의 노출면적은 $3.24cm^2$으로 하였다. 분극 실험은 개로전위로부터 +3 V까지 2 mV/s의 분극속도로 전위를 인가하였고, 기준전극으로 Ag/AgCl, 대극으로 백금전극을 사용하였다. 캐비테이션-전기화학 복합 실험은 정전위를 인가한 상태에서 대향형 진동법으로 진동수 20 kHz, 진폭 $30{\mu}m$ 진동을 20분간 가하였으며, 혼팁과 시험편 사이의 거리는 1 mm로 일정하게 유지하였다. 실험 후 표면 손상의 정량적 분석을 위해 인가된 전위별 전류밀도를 비교하고, 무게감소량을 측정하였으며, 손상경향 파악을 위하여 3D광학현미경과 주사전자현미경(SEM)을 통해 표면을 분석하였다.

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Synthesis of Heteroatom-Carbon Nanosheets by Solution Plasma Process (솔루션 플라즈마를 이용한 이종 원소 카본 나노시트의 합성)

  • Hyeon, Gwang-Ryong;Jeong, Gwang-Hu;Park, Il-Cho;Lee, Jeong-Hyeong;Han, Min-Su;Kim, Seong-Jong;Saito, Nagahiro
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.114-114
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    • 2018
  • 탄소 재료는 뛰어난 물성에서 다양한 재료로의 응용이 기대되고 있다. 특히, 이종 원소 함유 카본 재료는 전기적 특성과 촉매성의 발현 등 새로운 기능을 카본 재료에 부여할 수 있어서 연료 전지, 에너지 저장, 태양 전지 등에의 응용이 기대되고 있다. 최근, 용액 중의 저온 플라즈마인 솔루션 플라즈마(solution plasma process)를 이용하여 벤젠 용액 등에서 탄소 재료 합성에 성공하였다. 그러나 기존의 연구에서는 솔루션 플라즈마 프로세스를 이용하여 합성한 이종원소 카본은 전도성이 낮아 이종원소의 함유량을 낮추는 고온의 열처리가 필요했다. 따라서 본 연구에서는 우수한 물리적 전기적 특성을 갖는 그래핀(graphene)과 같은 이종 원소 카본 나노시트(heteroatom carbon nanosheets)의 합성 및 메커니즘(mechanism)에 대해 검토하였다. 다양한 이종원소를 포함한 유기용매 안에 바이폴라 펄스 전원에 의한 전압을 두 텅스텐 전극 간에 인가하고, 솔루션 플라즈마를 생성하여 이종원소 카본 재료를 합성했다. 플라즈마 생성은 텅스텐 봉을 전극으로 사용하고 전압을 2.0 kV, 펄스 주파수를 200 kHz, 펄스 폭을 $1.0{\mu}s$, 전극 간 거리를 1.5 mm에서 일정하게 유지하며 200 mL 유기용매 중에서 방전시키는 것으로 재료를 합성했다. 플라즈마 방전 후, 필터을 이용하여 흡인 여과한 뒤 $200^{\circ}C$에서 1 시간 동안 건조 시켰다. 건조 후의 이종원소 카본의 물리적 특성을 원소 분석, X선 회절 법(XRD), 저항률 측정, 투과형 전자 현미경(TEM) 및 라만 분광법, 전자 현미경(SEM), X-선광전자분광기(XPS)등을 이용하여 카본의 형상 및 특성을 분석하였다. 그 결과 다양한 이종원소를 포함한 유기용매 중 2-pyrrolidone을 사용했을 때, 이종 원소 카본 나노시트를 합성하는데 성공하였다. 또한, 이 연구방법을 통해서 솔루션 플라즈마 프로세스를 통한 카본 나노시트 합성의 메커니즘을 규명하였다.

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Bactericidal Efficacies of an Aquatic Disinfectant Tablet Composed to Calcium Hypochlorite Against Vibrio anguillarum and Streptococcus iniae

  • Cha, Chun-Nam;Lee, Yeo-Eun;Kang, In-Jin;Yoo, Chang-Yeul;Choi, Hyun-Ju;Kim, Suk;Lee, Hu-Jang
    • Journal of Food Hygiene and Safety
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    • v.27 no.3
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    • pp.290-294
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    • 2012
  • Vibrio spp. and Streptococcus spp. have caused a considerable disease of farmed fish and economic loss in fish farming and seafood industry. In this study, the efficacy of an aquatic disinfectant tablet composed to calcium hypochlorite was evaluated against V. anguillarum and S. iniae. A bactericidal efficacy test by broth dilution method was used to determine the lowest effective dilution of the disinfectant following exposure to test bacteria for 30 min at $4^{\circ}C$. An aquatic disinfectant tablet and test bacteria were diluted with distilled water (DW), hard water (HW) or organic matter suspension (OM) according to treatment condition. V. anguillarum on the DW, HW and OM condition was completely inactivated with 16,000 15,000 and 13,000 fold dilutions of the disinfectant, respectively. On the DW, HW and OM condition, S. iniae was absolutely inactivated with 17,000 16,000 and 14,000 fold dilutions of the disinfectant, respectively. As an aquatic disinfectant tablet possesses bactericidal efficacy against fish pathogenic bacteria such as V. anguillarum and S. iniae this disinfectant solution can be used to control the spread of fish infective bacterial diseases.

Effects of Carcass Treatments on Sarcomere Length, Drip Loss and Protein Solubility of Porcine Longissimus Muscle (사후 도체처리가 돈육 등심근의 근절길이와 육즙감량 및 단백질 용해성에 미치는 영향)

  • 강근호;이정일;주선태;박구부
    • Food Science of Animal Resources
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    • v.21 no.3
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    • pp.192-199
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    • 2001
  • The objective of this study was to investigate the effects of hot- and cold-boning on sarcomere length, drip loss and protein solubility of post-rigor porcine longissimus muscle. A total of ten pigs(borrow, 100$\pm$5 kg) were randomly selected at a commercial plant and the carcasses were split in half after slaughter. The longissimus muscle of the left side was dissected and chilled at 0$^{\circ}C$ after trimming of subcutaneous fat whereas the right side carcasses were served for cold-boning after chilling for 24 hrs. The temperature, pH and sarcomere length of porcine longissimus muscle were measured at postmortem 1, 3, 6, 12 and 24 hours. Drip loss, cooking loss, Minolta L*a*b*, shear force and protein solubility were measured at postmortem 24 hrs. The pH of cold-boning samples was rapidly decreased whereas temperature and sarcomere length of hot-boning samples were rapidly decreased during 24 hrs of chilling. Hot-boning muscles showed significantly (P<0.05) higher pHu and shorter sarcomere compared with cold boning muscles because of cold shortening. However, there were no significant differences in drip loss, cooking loss and shear force value between hot- and cold boned samples. The samples of hot-boning showed lower Minolta L* value and higher sarcoplasmic protein solubility compared with cold boned samples. These results suggest that the pale color changing of porcine longissimus muscle could be inhibited by hot-boning due to rapid chilling of the muscle although sarcomere length could be shortened because of cold shortening. Also these results show that hot-boning of porcine carcass could have a high protein solubility without negative effects of drip loss or tenderness of porcine longissimus muscle.

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A Occupant Load Density and Computer Modelling of Evacuation time in Office Buildings (사무소 건물의 거주밀도 분포와 피난시간 예측)

  • Kim, Un-Hyeong;Rui, Hu;Kim, Hong
    • Fire Science and Engineering
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    • v.13 no.3
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    • pp.35-42
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    • 1999
  • A occupant load density of contemporary office buildings were surveyed by a building w walk through procedure in Korea. The survey results of ten office buildings are range from 1 2 2 2 213.14 m !person 041.4 ft !person) to 22.69 m /person (244.34 ft !person) with 95% confidence l level and the mean occupant load density is 17.92 m2/person 092.87 ft2/야rson). The impacts of occupant load on evacuation flow time was analyzed by applying time-based egress m model, SIMULEX with various occupant load densities from previous studies. I In order to demonstrate the validation of egress modeling method, fire evacuation exercise a and computer simulation were used to simulate the actual evacuation plan for a high-rise office building. An analysis and comparison of the results of these approaches was made to i illustrate the influence of model limitations on the result of prediction The result of the study shows that the introduction of occupant load concept in building c code of Korea is essential to achieving resonable building life safety design in future.

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Bioconversion of Ginsenoside Rd into Compound K by Lactobacillus pentosus DC101 Isolated from Kimchi

  • Quan, Lin-Hu;Cheng, Le-Qin;Kim, Ho-Bin;Kim, Ju-Han;Son, Na-Ri;Kim, Se-Young;Jin, Hyun-O;Yang, Deok-Chun
    • Journal of Ginseng Research
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    • v.34 no.4
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    • pp.288-295
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    • 2010
  • Ginsenosides are the principal components responsible for the pharmacological and biological activities of ginseng. Ginsenoside Rd was transformed into compound K using cell-free extracts of food microorganisms, with Lactobacillus pentosus DC101 isolated from kimchi (traditional Korean fermented food) used for this conversion. The optimum time for the conversion was about 72 h at a constant pH of 7.0 and an optimum temperature of about $30^{\circ}C$. The transformation products were identified by thin-layer chromatography and high-performance liquid chromatography, and their structures were assigned using nuclear magnetic resonance analysis. Generally, ginsenoside Rd was converted into ginsenoside F2 by 36 h post-reaction. Consequently, over 97% of ginsenoside Rd was decomposed and converted into compound K by 72 h post-reaction. The bioconversion pathway to produce compound K is as follows: ginsenoside Rd$\rightarrow$ginsenoside F2$\rightarrow$compound K.

Direct Synthesis of H2O2 over Ti-Containing Molecular Sieves Supported Gold Catalysts: A Comparative Study for In-situ-H2O2-ODS of Fuel

  • Zhang, Han;Liu, Guangliang;Song, Haiyan;Chen, Chunxia;Han, Fuqin;Chen, Ping;Zhao, Zhixi;Hu, Shaozheng
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3065-3072
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    • 2013
  • Direct synthesis of $H_2O_2$ and in situ oxidative desulfurization of model fuel over Au/Ti-HMS and Au/TS-1 catalysts has been comparatively investigated in water or methanol. Maximum amount (82%) of active $Au^0$ species for $H_2O_2$ synthesis was obtained. Au/Ti-HMS and Au/TS-1 exhibited the contrary performances in $H_2O_2$ synthesis as $CH_3OH/H_2O$ ratio of solvent changed. $H_2O_2$ decomposition and hydrogenation in water was inhibited by the introduction of methanol. Effect of $O_2/H_2$ ratio on $H_2O_2$ concentration, $H_2$ conversion and $H_2O_2$ selectivity revealed a relationship between $H_2O_2$ generation and $H_2$ consumption. The highest dibenzothiophene removal rate (83.2%) was obtained over Au/Ti-HMS in methanol at 1.5 of $O_2/H_2$ ratio and $60^{\circ}C$. But removal of thiophene over Au/TS-1 should be performed in water without heating to obtain a high removal rate (61.3%). Meanwhile, $H_2$ conversion and oxidative desulfurization selectivity of $H_2$ were presented.

Analysis of the antibiotic resistance gene in Salmonella Typhimurium isolates from diseased pigs in Gyeongbuk province (경북지역 환돈 유래 Salmonella Typhimurium의 약제내성 유전자 분석)

  • Kim, Joo-Hyung;Kim, Seong-Guk;Kim, Seon-Soo;Kim, Jeong-Hwa;Park, Sye-Hee;Nam, Ki-Hu;Kim, Hyoung-Bae
    • Korean Journal of Veterinary Service
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    • v.36 no.2
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    • pp.73-78
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    • 2013
  • This study was conducted to investigate antibiotic resistance among Salmonella Typhimurium isolates from diseased pigs in Gyeongbuk province during the period 1998~2011. One hundred forty one isolates were tested for antibiotic resistance using the standard disk diffusion method and were examined for presence of resistance gene by PCR method. S. Typhimurium showed high drug resistance rates to tetracycline (95.7%), streptomycin (93.6%), ampicillin (86.5%), cephalothin (80.1%), gentamicin (79.4%), and trimethoprim/sulfamethoxazole (72.3%). Resistance gene, blaTEM, blaPSE1, tetA, tetB, tetG, sul1, sul2, aadA, strA, grm, and temA were detected among the antibiotic resistance isolates and temB, tetC, aadB gene were not detected. One hundred twenty one (89.6%) tetA, two (1.5%) tetB and one (0.7%) tetG gene were detected in the 135 tetracycline resistant isolates. Two (1.6%) temA gene were detected in one hundred twenty two ampicillin resistance isolates and temB was not detected.

Continuity of Care in Chronic Diseases: A Concept Analysis by Literature Review

  • Hu, Jingjing;Wang, Yuexia;Li, Xiaoxi
    • Journal of Korean Academy of Nursing
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    • v.50 no.4
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    • pp.513-522
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    • 2020
  • Purpose: This study aimed to utilize concept analysis to obtain a better understanding of the concept of "continuity of care" in chronic diseases. Methods: The concept of continuity of care was analyzed using the Walker and Avant method. Covering literature in English from 1930 to 2018, the data sources included CINAHL Complete, Academic Search Complete, MEDLINE, PsyARTICLES, Health Source: Nursing/Academic Edition, Google Scholar, Science Direct, and the Cochrane Library. Results: A comprehensive definition of concept of continuity of care was developed based on a systematic search and synthesis. The key defining attributes were identified as (a) care over time, (b) the relationship between an individual patient and a care team, (c) information transfer, (d) coordination, and (e) meeting changing needs. The antecedents of continuity of care were having a chronic disease, inexperienced with disease management, a poorly coordinated healthcare system, and medical care limitations. The consequences of continuity of care were decreasing hospital admissions, reducing costs, reducing emergency room visits, improving the quality of life, improving patient satisfaction, and delivering good healthcare. Conclusion: The thorough concept analysis provides insight into the nature of "continuity of care" in chronic diseases and also helps ground the concept in healthcare.

Numerical simulation of the neutral equilibrium atmospheric boundary layer using the SST k-ω turbulence model

  • Hu, Peng;Li, Yongle;Cai, C.S.;Liao, Haili;Xu, G.J.
    • Wind and Structures
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    • v.17 no.1
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    • pp.87-105
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    • 2013
  • Modeling an equilibrium atmospheric boundary layer (ABL) in an empty computational domain has routinely been performed with the k-${\varepsilon}$ turbulence model. However, the research objects of structural wind engineering are bluff bodies, and the SST k-${\omega}$ turbulence model is more widely used in the numerical simulation of flow around bluff bodies than the k-${\varepsilon}$ turbulence model. Therefore, to simulate an equilibrium ABL based on the SST k-${\omega}$ turbulence model, the inlet profiles of the mean wind speed U, turbulence kinetic energy k, and specific dissipation rate ${\omega}$ are proposed, and the source terms for the U, k and ${\omega}$ are derived by satisfying their corresponding transport equations. Based on the proposed inlet profiles, numerical comparative studies with and without considering the source terms are carried out in an empty computational domain, and an actual numerical simulation with a trapezoidal hill is further conducted. It shows that when the source terms are considered, the profiles of U, k and ${\omega}$ are all maintained well along the empty computational domain and the accuracy of the actual numerical simulation is greatly improved. The present study could provide a new methodology for modeling the equilibrium ABL problem and for further CFD simulations with practical value.