• Title/Summary/Keyword: Household chemical

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Synthesis of Amino Acid-based Anionic Surfactants from Coconut Oil and Characterization of Interfacial Properties (코코넛 오일로부터 유래된 아미노산계 음이온 계면활성제의 합성 및 계면 특성 연구)

  • Yea, DaNan;Jo, SeonHui;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.524-532
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    • 2018
  • In this study, two types of amino acids-based anionic biosurfactants such as potassium cocoyl glutamate (CTK) and sodium cocoyl glutamate (CTN) were synthesized from coconut oils and the structure elucidation of CTK and CTN was carried out by using FT-IR, $^1H-NMR$ and $^{13}C-NMR$ spectrophotometries. Measurements of interfacial properties such as static and dynamic surface tensions and emulsification activity showed that both CTK and CTN were surface-active and effective in lowering the interfacial free energy. In particular, the CTK surfactant was found to be more efficient in reducing the interfacial free energy since the larger number of CTK molecules was preferentially adsorbed at the air-water interface due to the higher hydrophobicity and larger mobility of CTK than those of using CTN, indicating possible uses in cosmetics and household products formulation.

Estimation of Sludge Gas Composition and Heating Value from Anaerobically Digested Korean Food Wastes (우리나라 음식물 쓰레기의 혐기성소화 가스 성분과 발열량 예측)

  • Chang, Ho Nam;Hong, Won Hi;Lee, Tai-yong;Chang, Seung Teak;Chung, Chang Moon;Park, Young-Sook
    • Clean Technology
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    • v.9 no.1
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    • pp.23-28
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    • 2003
  • The generation of food waste in Korea amounts to 4.10 million per year, which corresponds to 820,000 dry ton of organic waste. This has been used traditionally as animal feed or soil conditioner, but its efficacy has remained doubtful in recent years. In this study as an alternative we considered methane production by anaerobic treatment, which has an advantage of 200 million US dollars over aerobic methods. The production of methane amounts to $4.40{\times}10^8m^3$, 3.43% of $1.28{\times}10^8m^3$, total natural gas used in Korea. Furthermore the methane from household kitchen food waste amounts to 28.9% of the total gas used in the kitchen.

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Review on Safety and Health Information on Humidifier Disinfectant (가습기 살균제 제품에 표기된 안전보건정보 고찰)

  • Park, Dong-Uk;Lee, Seunghee;Lim, Heung-Kyu;Bae, Seo-Youn;Ryu, Seung-Hun;Ahn, Jong-Ju
    • Journal of Environmental Health Sciences
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    • v.43 no.5
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    • pp.349-359
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    • 2017
  • The objective of this study is to review the safety and health information displayed on containers of humidifier disinfectants (HD). We summarized not only general characteristics related to the marketing and manufacturing of HD, such as the duration sold and the name of the company, but also the safety and health information, such as identification of disinfectants, recommended use volume, and precautions. All of this information was reviewed by HD brand. We collected safety and health information from 31 HD brands. We found that companies that sold and manufactured HD brands differ. Two companies were found to sell their HD without permission after 2011 when the health effects caused by HD were widely known. The name of the disinfectants were not identified on the container of HD. The recommended volumes were found not to be based on toxicological evidence and set without consideration of the level of susceptibility of users. Most companies displayed phrases such "this HD is safe for humans, even children" on the front of the container. No inhalation and skin toxicity precautions were provided. In conclusion, most HD did not properly display information related to safety and health to protect the health of HD users. There has been no official investigation to evaluate the risks posed by HD, such as the sales volume by HD, identification of chemical disinfectants, or their concentration, nor have there been actions to control the chemical quality of HD. In addition, government actions to punish the malicious practices of companies that manufactured and sold HD were found to inappropriate.

Restoration of Membrane Performance for Damaged Reverse Osmosis Membranes through in-situ Healing (손상된 역삼투막의 in-situ 힐링을 통한 막 성능 복원)

  • Yun, Won Seob;Rhim, Ji Won;Cho, Young Ju
    • Membrane Journal
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    • v.29 no.2
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    • pp.96-104
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    • 2019
  • The purpose of this paper is whether or not the in-situ restoration of the reverse osmosis (RO) membranes which its membrane function is lost is possible. The damaged RO membranes are double coated through the salting-out method by the poly(styrene sulfonic acid) sodium salt as the cationic exchange polymer and the polyethyleneimine as the anionic exchange polymer and also conducted the opposite order of the coating materials. And according to the concentration, time and ionic strength, the flux and rejection are measured for the coated membranes. Then the best coating condition is to apply for the RO membrane module of the household water purifier to know the possibility of the in-situ restoration for the commercial module. When the condition of the PEI 30,000 ppm (IS = 0.1)/PSSA 20,000 ppm (IS = 0.7) is applied, the rejection was enhance from 69% for the damaged module to 86% (90% for the pristine module).

Formaldehyde Risk Assessment in Other Household Textile Products (가정용 섬유제품 중 기타 제품류의 폼알데하이드 위해성평가 연구)

  • Tae Hyun Park;Ji Hwan Song;Sa Ho Chun;Hee Rae Joe;Pil Jun Yoon;Ho Yeon Kang;Myeong Seon Ku;Jin Hyeok Son;Cheol Min Lee
    • Journal of Environmental Health Sciences
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    • v.50 no.2
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    • pp.138-145
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    • 2024
  • Background: Appropriateness issues have emerged regarding the non-application of hazardous substance safety standards for items classified as 'other textile products'. Objectives: Testing for formaldehyde (HCHO) and risk assessment were conducted on 'other textiles products' to provide reference data for promoting product safety policies. Methods: Testing was conducted on five items (102 products) classified as 'other textile products' according to relevant standards (textile products safety standards), and the risk of each product was assessed using the evaluation methodologies of the European Centre for Ecotoxicology and Toxicology of Chemicals (ECETOC) and European Chemical Agency (ECHA). Results: Out of the 102 products tested, HCHO was detected above the quantification limit in five. Based on these results, the screening risk assessment indicated that three products exceeded the criteria. Upon reassessing the emission and transfer rates of products exceeding the criteria, it was confirmed that there were no instances of exceeding the criteria. Conclusions: Risk assessment results can be used as supporting data for non-application of hazardous substance standards. However, it is deemed necessary to transition towards a management approach based on risks in order to addressing emerging trends such as convergence/new products.

Study on Installation Capacities of Wastewater Reclamation and Reusing System Applying to Contact Aeration Process using Cost-benefit Analysis (경제성분석을 이용한 접촉폭기방식 중수도의 설치규모분석에 관한 연구)

  • Nam, Young-Woo;Park, Tae-Uk
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.1945-1954
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    • 2000
  • This study provides economical installation capacities for wastewater reclamation and reusing system in 7 areas of South Korea applying to contact aeration process using NPV(net present value) model based on cost-benefit. First. considering only private benefits. economical installation capacities for wastewater reclamation and reusing system applying to contact aeration process in household use were more than $500m^3/day$ in Pusan. $1,000m^3/day$ in Taegu. $2,000m^3/day$ in Kwangju. However. installation capacities in Seoul. Inchen, Taejon, and Ulsan were not optimal for $3,000m^3/day$. Therefore, supply ways of wastewater reclamation and reusing system in household use in the latter areas were more optimal local recirculation system than individual recirculation system. Economical installation capacities for wastewater reclamation and reusing system in business use were more than $100m^3/day$ in Seoul. Pusan. and Kwangju and which were $300m^3/day$ in Taegu, Inchen, Taejon, and Ulsan. Economical installation capacities for wastewater reclamation and reusing system in commercial use were more than $100m^3/day$ in Seoul, Pusan, Taegu, Kwangju, Taejon, and Ulsan, and which were $300m^3/day$ in Inchen. Second, considering only social benefits. economical installation capacity for wastewater reclamation and reusing system applying to contact aeration process was more than $100m^3/day$.

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The Correlation Between Deltamethrin Exposure and Urinary 3-PBA Concentrations in Rats (Deltamethrin에 노출된 흰쥐의 뇨 중 3-PBA 검출 및 노출상관성)

  • Kim, Areumnuri;Chon, Kyongmi;Park, Kyung-Hun;Moon, Byeong-Chul;Ro, Jin-Ho;Paik, Min Kyoung
    • Korean Journal of Environmental Agriculture
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    • v.36 no.4
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    • pp.293-298
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    • 2017
  • BACKGROUND: Pyrethroids (PYRs) are a widely used insecticide in agriculture and household area. In mammals, PYRs such as deltamethrin is metabolized to 3-phenoxybenzoic acid (3-PBA) in liver that is mainly excreted in urine. This study is designed to single exposure of deltamethrin to rats in a dose-dependent manner and identify the correlation between deltamethrin exposure and its metabolite (3-PBA) in urine. METHODS AND RESULTS: Exposure levels of deltamethrin were control (0 mg/kg bw), low (0.0705 mg/kg bw), medium (0.705 mg/kg bw) and high (7.05 mg/kg bw) dose. Low concentration was derived by ussing Korea predictive operator exposure model (KoPOEM). Dermal exposure persisted for 6 h, and urine specimens were collected for 24 h. The urine matrix was removed after a series of procedures and 3-PBA was analyzed by gas chromatography/mass spectrometry. CONCLUSION: There was a strong correlation ($R^2=0.83$) between the amount of oral exposure to delta me thrin and urinary levelof3-PBAexcreted. In dermal exposure groups of deltamethrin except high-dose, also there was a good correlation between urinary 3-PBA and deltamethrin exposure, but not stronger than in oral deltamethrin exposure groups. Based on these results, therefore, the amount of 3-PBA in urine can be used as a good monitoring indicator that reflexing the exposure level of deltamethrin to human body.

A Study on Salt Removal in Controlled Cultivation Soil Using Electrokinetic Technology (전기동력학 기술을 이용한 시설재배지 토양의 염류제거 효과연구)

  • Kim, Lee Yul;Choi, Jeong Hee;Lee, You Jin;Hong, Soon Dal;Bae, Jeong Hyo;Baek, Ki Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.1230-1236
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    • 2012
  • To verify that the electrokinetic remediation is effective for decreasing salinity of fields of the plastic-film house, field tests for physical property, chemical property, and crop productivity of soils have been conducted. The abridged result of those tests is as follows. In the EK treatment, the electrokinetic remediation has been treated at the constant voltage (about 0.8 V $cm^{-1}$) for fields of the farm household. At this time, an alternating current (AC) 220 V of the farm household was transformed a direct current. The HSCI (High Silicon Cast Iron) that the length of the stick for a cation is 20cm, and the Fe Plate for an anion have been spread out on the ground. As the PVC pipe that is 10 cm in diameter was laid in the bottom of soils, cations descend on the cathode were discharged together. For soil physical properties according to the EK treatment, the destruction effect of soil aggregate was large, and the infiltration rate of water was increased. However, variations of bulk density and porosity were not considerable. Meanwhile, in chemical properties of soils, principal ions of such as EC, $NO_3{^-}$-N, $K^+$, and $Na^+$ were better rapidly reduced in the EK treated control plot than in the untreated control plot. And properties such as pH, $P_2O_5$ and $Ca^{2+}$ had a small impact on the EK. For cropping season of crop cultivation according to the EK treatment, decreasing rates of chemical properties of soils were as follows; $NO_3{^-}$-N 78.3% > $K^+$ 72.3% > EC 71.6% $$\geq_-$$ $Na^+$ 71.5% > $Mg^{2+}$ 36.8%. As results of comparing the experimental plot that EK was treated before crop cultivation with it that EK was treated during crop cultivation, the decreasing effect of chemical properties was higher in the case that EK was treated during crop cultivation. After the EK treatment, treatment effects were distinct for $NO_3{^-}$-N and EC that a decrease of nutrients is clear. However, because the lasting effect of decreasing salinity were not distinct for the single EK treatment, fertilization for soil testing was desirable carrying on testing for chemical properties of soils after EK treatments more than two times. In the growth of cabbages according to the EK treatment, the rate of yield increase was 225.5% for the primary treatment, 181.0% for the secondary treatment, and 124.2% for third treatment compared with the untreated control plot. The yield was increased by a factor of 130.0% for the hot pepper at the primary treatment (Apr. 2011), 248.1% for the lettuce at the secondary treatment (Nov.2011), and 125.4% for the young radish at the third treatment (Jul. 2012). In conclusion, the effect of yield increase was accepted officially for all announced crops.

The Properties of Plant Fibers -Kuzu Vine, Indian Mallow, Mulberry Paper, Yucca, New Zealand Hemp, and Corn Fibers- (식물 섬유 특성에 관한 연구 -어저귀, 칡, 닥, 실유카, 신서란, 옥수수를 중심으로-)

  • Bae, Hyun-Young;Lee, Hye-Ja;Yoo, Hye-Ja;Han, Young-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.4
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    • pp.598-607
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    • 2008
  • Bast fibers were applied for various usages from fabrics to household care products long time ago. In this study, we investigated the physical characteristrus of water retted & chemically rotted fibers of Yucca, New Zealand hemp, Corn, Kuzu vine, Indian mallow, and Mulberry paper that have been harvested by domestic cultivation. Water retting is more effective than chemical rotting for six kinds of plant fibers. When all fibers were rotted chemically with 1% sodium hydroxide, only Kuzu vine and Indian mallow were retted. Indian mallow, Yucca, New Zealand hemp, and Com fibers have higher tensile strength than any other fibers. The crystallinity of Kuzu vine, Indian mallow, Yucca, New Zealand hemp, and Corn was as low as 60% but Yucca, New Zealand hemp were flexible. Yucca had fewer lumina whereas New Zealand hemp more lumina in cross sectional shape. Especially com fibers have a structure like sponge, and Indian mallow had a net shape. The longitudinal section of New Zealand hemp showed smooth and long shape. Mulberry paper was proved to be short and thin, which is quite appropriate for making paper. In this study, we found that plant fibers for living material could be used for cloth materials.

Current Status and Technical Development for Di-Methyl Ether as a New and Renewable Energy (신재생 에너지로서 DME 기술개발 현황)

  • Cho, Wonjun;Kim, Seung-Soo
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.355-362
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    • 2009
  • Fuels based on petroleum will eventually run out in the near future. DME (Di-methyl Ether) is a clean energy source that can be manufactured from various raw materials such as natural gas, coal as well as biomass. As DME has no carbon-carbon bond in its molecular structure and is an oxygenate fuel, its combustion essentially generates no soot as well as no SOx. Because the physical properties of DME are similar to those of LPG, the LPG distribution infrastructure can be converted to use with DME. DME has such high cetane number of 55~60 that it can be used as a diesel engine fuel. Practical use of DME as a next-generation clean fuel or next-generation chemical feedstock is advancing in the fields of power generation, diesel engines, household use, and fuel cells, among others. The purpose of this paper is review the characteristics, standardization, status of research and development in domestic and foreign countries of DME.