• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.172.2-172.2
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• 2011

다양한 저급연료나 폐기물로부터 가스엔진이나 연료전지의 연료로 사용하기위한 연료가스를 얻기 위한 방법으로 가스화 기술을 적용할 수 있다. 폐기물의 가스화를 통해 발생된 합성가스에는 CO, $H_2$, $CO_2$와 같은 주요성분 이외에 황화합물($H_2S$, COS), 염소화합물(HCl), 고형 물질(분진)등의 오염물질이 포함되어 있으므로, 이용목적에 따라 적절한 정제 기술이 필요하게 된다. 현재 가장 널리 알려진 저온 습식 정제공정은 장치운전이 쉽고 오염물질 제거효율이 높은 장점이 있으나, 합성가스 온도를 상온까지 낮추기 때문에 현열 손실이 발생하는 단점을 가지고 있다. 고온 건식 정제공정에 의해 $300^{\circ}C$ 이상의 고온에서 오염물질의 제거가 가능하다면 에너지 이용효율을 높일 수 있고, 습식공정에 의해 발생되는 폐수처리에 따른 비용 절감효과도 얻을 수 있다. 폐기물 합성가스를 최종 적용처에 이용하기위한 고온 정제 공정의 적용을 위해 흡착제를 이용하여 탈황, 탈염 실험을 실시하였고, 실험결과로부터 장치 설계의 기초인자를 도출하였다.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.169-178
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• 2000

Perovskite oxide catalysts doped on porous alumina beads are prepared in a citric acid solution. To investigate the applicability of the catalysts to the hot gas cleanup, a series of experiments on the reduction characteristics of $NO_x$ by CO as a reducing agent are carried out in a packed bed reactor containing the catalysts. Parameters tested are the operating temperature and $CO/NO_x$ molar ratio. It is found that mixed complex oxides of $La_{0.5}Sr_{0.5}CoO_3$, $SrAl_{12}O_{19}$ and $LaAl_{11}O_{18}$ are uniformly distributed on the alumina beads. The conversion efficiency of $NO_x$ by CO sharply increases with the operating temperature up to $700^{\circ}C$ and then approaches 100% when $CO/NO_x$ molar ratio is greater than 1.0. The conversion efficiency of $NO_x$ is maintained by over 98% during a continuous operation for 23 hours at $800^{\circ}C$ and space velocity of $10700hr^{-1}$.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.341-344
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• 2008

Computational studies have been performed to analyze the particle loadings onto the filters according to the different inflow pattern of dusty gas and the flow uniformities on the filter surface of back-blown gas at different permeability of porous media setup at the filter outlet. This is preliminary study to find how we can reduce the regeneration time and improve the regeneration efficiency of filters with dust layer.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.11a
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• pp.61-66
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• 1999

화석 연료중 석탄을 가장 경제적이고, 환경친화적으로 이용하는 신발전기술로 석탄가스 복합발전(IGCC)이 있으며, 이러한 신발전 기술의 핵심은 석탄가스화와 석탄가스 중에 있는 불순물을 제거하는 정제 기술이다. 현재 저온정제와 기존의 복합발전 시스템을 이용한 1세대 IGCC는 상용단계에 있으며 열효율은 40% 전후이다. 이런 IGCC의 발전 단가를 줄이고 열효율을 45%이상 증가시켜 타 발전기술과 경쟁력을 갖추기 위해서는 고온고압에서 석탄가스 중에 있는 불순물을 제거하는 고온정제기술(hot gas cleanup)은 필수적이다.(중략)

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.812-815
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• 2007

Computational simulation has been performed to design the filtration system for Korea model IGCC demonstration plant. The filtration system for optimal design has four effective filters corresponding to the clusters composed of a group of ceramic candle filters. It was analyzed how the different entrance geometry influences the flow field and the particle behavior in the filtration system. The particle loading is minimum when the gas mixed with particles flows into the filter vessel with a shroud tube through a tangential inlet. However, the particle loading is maximum when the gas with particles enters the filter vessel through a normal inlet which a entrance tube extended from. By controling adequately both conditions of inflow, the filtration system can be operated optimally to prolong the filter life-time and to save the energy for cleaning filters.

• Journal of Hydrogen and New Energy
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• v.25 no.5
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• pp.482-490
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• 2014

Gaseous sulfur compound such as $H_2S$ or COS in coal- or biomass-derived hot syngas can be purified by solid sorbents at high temperatures. In this study, we investigated the physical properties and reactivity of solid regenerable desulfurization sorbents with 37.2, 41.9, and 46.5wt% ZnO to look into the ZnO content effect. The sorbents were produced by spray-drying method to apply to a fluidized-bed process. Sulfidation and regeneration reaction were carried out using a thermogravimetric analyzer. Sorbent prepared with 46.5wt% ZnO had physical properties suitable for a fluidized-bed process applications such as spherical shape, sufficient mechanical strength and density, high porosity and surface area. It showed high sulfur sorption capacity of 10.4wt% (ZnO utilization of 57%) at reaction temperatures of 500 and $650^{\circ}C$ for sulfidation and regeneration, respectively. However, the sulfur sorption capacity and ZnO utilization were significantly reduced and dimple shape appeared when the ZnO content decreased to 37.2 and 41.9wt%. Sulfur sorption capacity and regenerability were improved as reaction temperature increased within the experimental temperatures used in this work. The reaction temperature zones of $1500{\sim}550^{\circ}C$ and $650{\sim}700^{\circ}C$ are recommended for sulfidation and regeneration, respectively, to lead best reaction performances of the ZnO-based spray-dried sorbents developed in this work.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.246-249
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• 2008

IGCC (석탄가스화 복합발전) 시스템 공정 중 가스화기에서 발생되는 합성가스 내에는 높은 농도의 분진들이 함유되어 있기 때문에 하부 공정들을 보호하기 위해서는 가스화기 후단에 집진장치가 필히 설치되어야 한다. 집진장치의 설계 제작 운전에 있어서 점착성 분진층 부착,분진 브리징, 필터 파손 현상 등과 같은 다양한 문제점들로 인하여 고온의 합성가스를 처리하는 데는 아직 기술적 한계들이 산재해 있는 상황이다. 이와 같은 문제점들은 필터에 부착된 분진층의 탈진성능을 향상시키거나, 필터의 열피로를 줄일 수 있도록 필터 재생을 위한 탈진의 횟수를 줄이는 방법을 통하여 해결될 수 있다. 본 연구에서는 파일롯 규모의 IGCC용 세라믹캔들필터 집진장치에서의 가스 유입 및 탈진 조건에 따른 집진장치의 차압 특성 변화를 수치해석과 실험을 통하여 분석함으로써 탈진성능을 향상시킬 수 있는 조건과 탈진 횟수를 최소화시킬 수 있는 방안을 도출하고자 하였다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.5
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• pp.1639-1648
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• 1996

Protection of gas turbine blade from its erosion and abrasion at high temperature and pressure is the first goal to cleanup the hot gas upstream for IGCC and PFBC. Ceramic filters represent an attractive technology for particle removal at high temperature and high pressure condition. They have demonstrated being a good system for improvement of thermal efficiency and reduction of effluent pollutants in advanced coal-based power systems such as IGCC and PFBC. Ceramic filter elements currently being developed were evaluated in the previous paper. In this paper, we measured the ash size and distribution on cleaning of ceramic candle filter. The results are as follows : in this experimental range, ceramic candle filter was shown to be fully adequate for the removal process of dust under high temperature and pressure. Also filtration efficiency of ceramic candle filter was higher than 98% compared with the regulation limit of particle size in gas turbine inlet.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.983-987
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• 2008

Computational simulation has been performed to design optimally the filtration system for IGCC pilot plant. It was analyzed how the different inflow pattern influences the flow field and the particle behavior in a filter vessel. The particle loading onto the filter surface lowers significantly and decreases dramatically with particle size when the dusty gas flows into the filter vessel with a shroud tube through a tangential inlet setup tangentially on the vessel outer wall. However, the particle loading is considerably high when the dusty gas enters the filter vessel through a normal inlet setup vertically on the vessel top wall, and the decrease of the particle loading with particle size is not steeper compared with the tangential inflow pattern.