• Fibers and Polymers
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• v.1 no.1
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• pp.6-11
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• 2000

In the polycondensation reaction of polyethyleneterephthalate(PET), $Sb_2$$O_3$, can react effectively as a catalyst, if physically transformed. $Sb_2$$O_3$ powder is transformed into liquid solution by dissolving in ethylene glycol(EG). Homogeneous catalyst is made by mixing this liquid solution with glycols having different solubility. The efficient reaction of PET polymerization is expected by using homogeneous catalyst. PET was synthesized using homogeneous catalysts of 4 wt.% $Sb_2$$O_3$ solution dissolved in glycol[EG, 2,2-bis(4-(2-hydroxyethoxy)phenol)propane(BHPP), neopentyl glycol(NPO), and 1,3-propandiol(PD)]. PET using EG-BHPP($Sb_2$$O_3$) catalysts shows the highest I.V. within a reaction time of 120 min. In the p-d analysis, PET using EG-BHPP($Sb_2$$O_3$) catalysts has the fastest propagation rate and slowest degradation rate. EG-BHPP($Sb_2$$O_3$) catalysts are more efficient than EG($Sb_2$$O_3$) catalysts and $Sb_2$$O_3$ powder catalysts.

• Macromolecular Research
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• v.17 no.7
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• pp.506-515
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• 2009

We synthesized a series of polystyrene derivatives containing various side chain terminal moieties, such as phenoxymethyl, 4-methoxyphenoxymethyl, 4-fluorophenoxymethyl, 4-methylphenoxymethyl, and 4-trifluoromethoxyphenoxymethyl groups, using polymer analogous reactions, in order to investigate the effect of the side group on their liquid crystal (LC) alignment behaviors. The polymers containing 4-fluorophenoxymethyl, 4-methylphenoxymethyl, or 4-trifluoromethoxyphenoxymethyl side groups had lower surface energy values and the LC cells fabricated using the unrubbed films of these polymers showed homeotropic LC alignment behavior. The LC cells fabricated using the rubbed films of the polymers containing phenoxymethyl or 4-fluorophenoxymethyl groups showed homogeneous planar LC alignment behavior in which the LCs were aligned perpendicular to the rubbing direction. This homogeneous planar and perpendicular alignment behavior was ascribed to the favorable anisotropic interactions between the LC molecules and the side groups preferentially oriented perpendicular to the rubbing direction.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.11
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• pp.1008-1013
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• 2003

We have studied the effect of black matrix (BM) according to the dielectric anisotropy of liquid crystals (LCs) for a homogeneously aligned LC cell driven by fringe-electric field. The results show that for a LC with positive dielectric anisotropy (+LC) there is a large transmittance change when using a conductive BM, whereas the transmittance change is low for a LC with negative dielectric anisotropy (-LC). The conductive BM existing on top substrate produces vertical electric field, which makes the LC molecules be tilt upward from the substrate and have small twist angle for the +LC. However, for the -LC the conductive BM affects the LC distribution only slightly due to characteristic of the -LC orienting perpendicular to the field. Therefore, for the +LC the electro-optic characteristics are strongly dependent on conductivity of the BM on top substrate in a homogeneous liquid crystal cell driven by fringe-electric field.

• 한국정보디스플레이학회:학술대회논문집
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• 2006.08a
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• pp.792-795
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• 2006

In-plane-switching (IPS)-mode LCD is one of the most useful technologies for a broad range of viewing angles. To apply for IPS-LCDs, we synthesized novel homogeneous alignment materials, changing dianhydrides (BTDA and BPDA) and bridged diamines (ODA and PACM). We measured their pre-tilt angles using the crystal rotation method with positive LC and their surface properties.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1903-1908
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• 2004

A preconditioned numerical method for gas-liquid two-phase flows is applied to solve cavitating flow. The present method employs a finite-difference dual time-stepping integration procedure and the MUSCLTVD scheme. A homogeneous equilibrium cavitation model is used. The present density-based numerical method permits simple treatment of the whole gas-liquid two-phase flow field, including wave propagation, large density changes and incompressible flow characteristics at low Mach number. Some internal flows such as convergent-divergent nozzles are computed using this method. Comparisons of predicted and experimental results are provided and discussed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.449-450
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• 2005

Alignment characteristic of liquid crystal (LC) on in-cell retarder which is composed of reactive mesogens has been tested. The in-cell retarder which is polymerized on top of the homogeneous alignment layer (AL) has an optic axis along the rubbing direction of the homeogenous AL and does show good alignment effect of the LC without showing any defects, which possibly allows a skip of another AL on the in-cell retarder that was required conventionally to control alignment of the LC. However, the measured pretilt angle is only 0.04 degree so that disclination lines are generated for a cell that uses the in-cell retarder as an AL when the LC is tilted upward by a vertical electric field.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.426-427
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• 2006

In this paper, the neural network model of the pretilt angle in the nematic liquid crystal on the homogeneous polyimide surface with different surface treatments is investigated. The pretilt angle is one of the main factors to determine the alignment of the liquid crystal display. The pretilt angle is measured to analyze the variation of the characteristics on the various process conditions. The rubbing strength and the hard baking temperature are considered as input factors. Latin hypercube sampling was used to generate initial weights and biases.

• 한국가스학회:학술대회논문집
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• 2007.04a
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• pp.33-36
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• 2007

합성가스는 C1화학을 시작하는 반응원료 물질로 최근 DME(dimethyl-ether), 메탄올, GTL(gas to liquid), CTL(coal to liquid), 암모니아 생성 공정 등 많은 화학공정에 사용되고 있다. 합성가스를 생산하는 방법은 천연가스 개질반응과 석탄의 가스화반응, 그리고 원유의 정제 등을 통해 얻을 수 있다. 삼중개질반응은 천연가스와 산소, 수증기, 이산화탄소를 원료로 $1000^{\circ}C$ 이상의 고온에서 반응시켜 합성가스를 생산하며, 균일반응계와 불균일반응계로 이루어져 있다. 균일반응계에서는 천연가스와 산소가 주로 반응하며, 원료로 투입된 대부분의 산소는 균일반응계에서 소모되어 일산화탄소와 이산화탄소를 생성한다. 삼중개질반응의 균일반응계에서는 산소와 천연가스와의 반응으로 많은 발열이 발생하여 전체 반응계의 온도를 유지할 수 있도록 해준다. 본 연구에서는 산소로 인한 삼중개질반응의 온도 조절과 균일반응계의 온도 분포를 위치에 따라 관찰해 보았으며, 실험과 모사를 통해 비교해 보았다.

• International Journal of Fluid Machinery and Systems
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• v.9 no.1
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• pp.57-65
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• 2016

By high speed Liquid Droplet Impingement (LDI) on material, fluid systems are seriously damaged, therefore, it is important for the solution of the erosion problem of fluid systems to consider the effect of material in LDI. In this study, by using an in-house fluid/material two-way coupled method which considers reflection and transmission of pressure, stress and velocity on the fluid/material interface, high-speed LDI on wet/dry material surface is simulated. As a result, in the case of LDI on wet surface, maximum equivalent stress are less than those of dry surface due to damping effect of liquid film. Empirical formula of the damping effect function is formulated with the fluid factors of LDI, which are impingement velocity, droplet diameter and thickness of liquid film on material surface.

• Tribology and Lubricants
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• v.14 no.2
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• pp.42-48
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• 1998

Electro-Rheological (ER) fluid is a class of functional fluid whose apparent viscosity can be varied by the applied electric field strength. The ER fluid is classified into two types; one is a dispersive fluid and the other is a homogeneous. Dispersive ER fluid is a colloidal suspension of fine semiconducting particles in a dielectric liquid and liquid crystal (LC) is classed as homogeneous type ER fluid. LC has been originally developed for some electronic display devices. Various mechanical components applying ER fluid have been developed, and the their performance typically depends on the characteristics of ER fluid which have generally been evaluated by a rotational viscometer. However, the ER fluid introduced into various mechanical components undergoes not only simple shear flow but press flow or oscillating flow. For the evaluation of ER fluid, the authors developed an reciprocating type viscometer. The amplitude is controlled on 5 mm at the frequency from 50 to 1000 Hz. In the present paper, the performance of several types of ER fluid is evaluated by the reciprocating type viscometer and compared with those evaluated by a rotational viscometer.