• 청정기술
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• 제10권3호
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• pp.149-158
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• 2004

초임계 이산화탄소는 다양한 화학공정에 유용한 성질을 지니고 있어 친환경 용매로 사용되고 있으나 이산화탄소의 극성 물질과 비휘발성 물질에 대한 낮은 용해력은 실제 공정에 있어 목표로 하는 물질을 균일상태로 만들지 못하는 단점을 가지고 있다. 친이산화탄소기를 갖는 이산화탄소용 계면활성제의 설계는 이러한 이유로 인하여 큰 의미를 갖는다. 이산화탄소용 계면활성제는 염색, 섬유 세탁, 고분자 중합과 가공, 반도체 세정, 전기 도금 및 화학 반응의 청정화 요구에 크게 기여하고 있다.

• Structural Engineering and Mechanics
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• 제57권2호
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• pp.239-263
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• 2016

The paper studies the natural oscillation of the three-layered solid sphere with a middle layer made of Functionally Graded Material (FGM). It is assumed that the materials of the core and outer layer of the sphere are homogeneous and isotropic elastic. The three-dimensional exact equations and relations of linear elastodynamics are employed for the investigations. The discrete-analytical method proposed by the first author in his earlier works is applied for solution of the corresponding eigenvalue problem. It is assumed that the modulus of elasticity, Poisson's ratio and density of the middle-layer material vary continuously through the inward radial direction according to power law distribution. Numerical results on the natural frequencies related to the torsional and spheroidal oscillation modes are presented and discussed. In particular, it is established that the increase of the modulus of elasticity (mass density) in the inward radial direction causes an increase (a decrease) in the values of the natural frequencies.

• Geomechanics and Engineering
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• 제21권1호
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• pp.11-21
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• 2020

The traditional formulations for estimation of bearing capacity in rock mechanics assume a homogeneous and isotropic rock mass. However, it is common that the rock mass consists of different layers of different rock properties or of the same rock matrix with distinct geotechnical quality levels. The bearing capacity of a heterogeneous rock is estimated traditionally through the weighted average. In this paper, the solution of the weighted average is compared to the finite difference method applied to a bilayer rock mass. The influence of different parameters such as the thickness of the layers, the rock type, the uniaxial compressive strength and the overall geotechnical quality of the rock mass on the bearing capacity of a bilayer rock mass is analyzed. A parametric study by finite difference method is carried out to develop a bearing capacity factor in function of the layer thickness and the rock mass quality expressed in terms of the geological strength index, which is presented in a form of a chart. Therefore, this correlation factor allows estimating the bearing capacity of a rock mass that is formed by two layers with distinct GSI, depending on the bearing capacity of the rock mass formed only by the upper layer and considered by that way as homogenous and isotropic rock mass.

• Journal of Advanced Marine Engineering and Technology
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• 제22권4호
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• pp.560-568
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• 1998

Recently to develop an automobile with better properities many researches and investments have been executed. In this paper we intend to improve the automobile properties by reducing the weight of the engine without changing the dynamic characteristics. At first the vibration analysis by the Substructure Synthesis Mehtod and the exciting test of the engine model performed to confirm the reliability of the analyzing tools. And the weight minimiza-tion is performed by the Sensitivity Analysis and the Optimum Structural Modificationl. To decrease the engine weight ideally the weight of the parts with the low sensitivity is to cut mainly and the changing quantity of the natural frequency by the cut is to be recovered by the weight modification of the parts with the high sensitivity. As actually the mathematical unique solution for the homogeneous problem(i. e. 0 object func-tion problem)does not exist we redesign the engine block with much thinner initial thickness and recover the natural frequencies and natural modes of original structure by the sensitivity analy-sis and then observe the Frequency Response Function(FRF) for the interesting points. In this analysis the original thickness of the engine model is 8mm and the redesigned initial thicknesses are 5mm and 6mm, And the number of the interesting natural frequencies are 1, 2, 3, 4 and 5 respectively.

• Bulletin of the Korean Chemical Society
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• 제24권5호
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• pp.593-599
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• 2003

The nanoparticle magnetite of which diameter was about 3 nm was synthesized in a homogeneous aqueous solution without a template. The synthesized magnetite nanoparticle was easily oxidized to maghemite in an ambient condition. The magnetic properties of the ferrite nanoparticle show superparamagnetism at room temperature and its blocking temperature is around 93 K. Modifying the sequential adsorption method of metal bisphosphonate, we have prepared a multilayer thin film of the ferrite nanoparticle on planar substrates such as glass, quartz and Si wafer. In this multilayer the ferrite nanoparticle layer and an alkylbisphosphonate layer are alternately placed on the substrates by simple immersion in the solutions of the ferrite nanoparticle and 1, 10-decanediylbis (phosphonic acid) (DBPA), alternately. This is the first example, as far as we know, of nanoparticle/alkyl-bisphosphonate multilayer which is an analogy of metal bisphosphonate multilayer. UV-visible absorption and infrared reflection-absorption studies show that the growth of each layer is very systematic and the film is considerably optically transparent to visible light of 400-700 nm. Atomic force microscopic images of the film show that the surface morphology of the film follows that of the substrate in μm-scale image and the nanoparticle-terminated surface is differentiated from the DBPA-terminated one in nm-scale image. The magnetic properties of this ferrite/DBPA thin film are almost the same as those of the ferrite nanoparticle powder only.

• Carbon letters
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• 제27권
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• pp.81-89
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• 2018

The present study aimed to prepare a novel efficient flame retardant additive for polypropylene. The new flame retardant was prepared by chemical grafting of melamine to graphene oxide with the aid of thionyl chloride. Fourier-transform infrared spectroscopy and thermogravimetric analysis proved that melamine had been successfully grafted to the graphene oxide. The modified graphene oxide was incorporated into polypropylene via solution mixing followed by anti-solvent precipitatio. Homogeneous distribution as well as exfoliation of the nanoplatelets in the polymer matrix was observed using transmission electron microscopy. Thermogravimetric analysis showed a significant improvement in the thermo-oxidative stability of the polymer after incorporating 2 wt% of the modified graphene oxide. The modified graphene oxide also enhanced the limiting oxygen index of the polymer. However, the amount of improvement was not enough for the polymer to be ranked as a self-extinguishing material. Cone calorimetry showed that incorporating 2 wt% of the modified graphene oxide lowered total heat release and the average production rate of carbon monoxide during burning of the polymer by as much as 40 and 35%, respectively. Hence, it was concluded that the new flame retardant can retard burning of the polymer efficiently and profoundly reduce suffocation risk of exposure to burning polymer byproducts.

• The Korean Journal of Ceramics
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• 제5권2호
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• pp.142-147
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• 1999

The interaction between commercial $Si_3N_4$ powder and two types of additives (nitrate and oxide additives) during the sintering of $Si_3N_4$ was investigated. The nitrates solution or oxide particles were added as a sintering additives. The surface of mixed powder was observed with FT-IR, TG, and HREM. DTA was used to characterize the reactivity of the powders. The formation of crystalline phases and phase transformation were analyzed by XRD. The adsorption of the additives on the surface of silicon nitride was confirmed in the nitrate salts. It was shown that the adsorption occurred by interaction between the amorphous $SiO_2$ layer on the $Si_3N_4$ surface and metal cations $(Al^{3++\; and \;Y^{3+})$ and anions $(NO_3\;^-\; or\; OH^-)$, resulting in a higher degree of homogeneous distribution of additives.

• 한국세라믹학회지
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• 제49권6호
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• pp.498-504
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• 2012

Oxide layers were prepared by an environmentally friendly plasma electrolytic oxidation (PEO) process on an Al-1050 substrate. The electrolyte for PEO was an alkali-based solution with $Na_2SiO_3$ (8 g/L) and NaOH (3 g/L). The influence of the electrical parameters on the phase composition, microstructure and properties of the oxide layers formed by PEO were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The voltage-time responses were recorded during various PEO processes. The oxides are composed of two layers and are mainly made of ${\alpha}$-alumina, ${\gamma}$-alumina and mullite phases. The proportion of each phase depends on various electrical parameters. It was found that the surface of the oxides produced at a higher current density and Ia/Ic ratio shows a more homogeneous morphology than those produced with the electrical parameters of a lower current density and lower Ia/Ic ratio. Also, the oxide layers formed at a higher current density and higher Ia/Ic ratio show high micro-hardness levels.

• 한국항공우주학회지
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• 제31권1호
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• pp.34-41
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• 2003

경사기능재료 판에 대한 열탄성 변형과 응력 해석을 위해 Green 함수 방법이 채택되었다. 3차원 정상 온도분포에 대한 해는 적층판 이론에 의해 얻어진다. 열탄성 문제에 대한 기본 방정식은 각각 평면의(out-plane) 변형과 평면내(in-plane) 힘에 의해 유도되었다. 굽힙과 평면내 힘으로 인한 열탄성 변형과 응력분포는 Galerkin 방법에 근거한 Green 함수를 이용하여 해석되었다. 열탄성 변형과 응력분포 해석을 위한 Galerkin Green 함수의 특성함수들은 사각판의 제차 경계조건을 만족시키는 허용함수들의 급수 형태로 근사화 되었다. 수치예제가 수행되었으며, 경사기능재료의 물성치가 판의 열탄성 거동에 미치는 영향이 검토되었다.

• 한국군사과학기술학회지
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• 제11권4호
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• pp.83-91
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• 2008

The development of the equal channel angular pressing(ECAP) process in metals has recently provided a feasible solution to produce ultra-fine or nano-grained bulk materials with tailored material properties. However, ECAP process is difficult to scale up commercially due to requirements of an excessive load. In this paper, a new Hybrid-ECAP process with torsional die is considered to obtain materials of ultra-fine grain structure under low forming load. An upper bound analysis and numerical simulation (DEFORM 3D, a commercial FEM code) are carried out on the torsional die. By the upper bound analysis, analytical expression for the compression force and rotation speed are obtained. By the FEM analysis, the distribution of strain, stress and deformation are obtained. These results show that the Hybrid-ECAP is a useful process because this process can obtain the homogeneous deformations with relatively low forming load. Additionally, due to decreased forming load, die life can be improve.