• Bulletin of the Korean Chemical Society
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• 제20권9호
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• pp.1035-1039
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• 1999

Manganese-activated zincgallate (Zn1-xMnxGa2O4) phosphor as a green phosphor was readily prepared by coprecipitation in aqueous basic solution of metal salts. The obtained product converted to amorphous zincgallate even at 300℃, followed by crystallization at 1000 ℃. The pyrolyzed phosphor showed fine particle, then reduction treatment at 900 ℃ changed into homogeneous shape with slight grain growth(particle size less than 0.5 mm). The photoluminescence characteristics of the zincgallates have been investigated as a function of dopant concentrations, reducing atmospheres and temperatures. Under UV excitation the phosphors displayed the highest green emission efficiency at 504 nm when the specimen oxidized at 1000 ℃ was reduced at 900 ℃ in a mild hydrogen atmosphere (97% N2, 3% H2) with a flow rate of 100 ml/min.

• Bulletin of the Korean Chemical Society
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• 제18권12호
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• pp.1296-1301
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• 1997

Polymerization of terminal alkynes (phenlacetylene and 4-ethynyltoluene) catalyzed by water soluble rhodium (Ⅰ) complex, RhCl(CO)(TPPTS)2 (TPPTS=m-P(C6H4SO3Na)3) (1) selectively produces cis-transoid polymers at room temperature in homogeneous solution of H2O and MeOH as well as in biphasic solutions of H2O and CHCl3. The rate of polymerization is higher in H2O/MeOH than in H2O/CHCl3. The iridium analog, IrCl(CO)(TPPTS)2 (2) shows catalytic activity for the polymerization of phenylacetylene only at elevated temperature to give trans-polymers. The polymerization rate increases significantly when the trimethylamine N-oxide (Me3NO) was added to the reaction mixtures. The electronic absorption spectra of the cis-transoid polymers show three absorption bands whereas the trasn-polymers show only one absorption band. It seems that the electronic absorption bands depend on the configuration of the polymers.

• Structural Engineering and Mechanics
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• 제57권1호
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• pp.21-43
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• 2016

A conditional probability based approach known as Particle Filter Method (PFM) is a powerful tool for system parameter identification. In this paper, PFM has been applied to identify the vehicle parameters based on response statistics of the bridge. The flexibility of vehicle model has been considered in the formulation of bridge-vehicle interaction dynamics. The random unevenness of bridge has been idealized as non homogeneous random process in space. The simulated response has been contaminated with artificial noise to reflect the field condition. The performance of the identification system has been examined for various measurement location, vehicle velocity, bridge surface roughness factor, noise level and assumption of prior probability density. Identified vehicle parameters are found reasonably accurate and reconstructed interactive force time history with identified parameters closely matches with the simulated results. The study also reveals that crude assumption of prior probability density function does not end up with an incorrect estimate of parameters except requiring longer time for the iterative process to converge.

• Earthquakes and Structures
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• 제10권3호
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• pp.681-697
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• 2016

The model of two-temperature magneto-thermoelasticity for a non-simple variable-thermal-conductivity infinitely-long solid cylinder is established. The present cylinder is made of an isotropic homogeneous thermoelastic material and its bounding plane is traction-free and subjected to a time-dependent temperature. An exact solution is firstly obtained in Laplace transform space to obtain the displacement, incremental temperature, and thermal stresses. The inversion of Laplace transforms has been carried out numerically since the response is of more interest in the transient state. A detailed analysis of the effects of phase-lags, an angular frequency of thermal vibration and the variability of thermal conductivity parameter on the field quantities is presented.

• 한국전기전자재료학회논문지
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• 제32권4호
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• pp.302-306
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• 2019

We investigated a solution-derived $Y_2O_3$ film treated by ion beam (IB) irradiation as a liquid crystal (LC) alignment layer. With IB irradiation, homogeneous LC alignment was achieved irrespective of the annealing temperature. To verify the effect of IB irradiation, we conducted surface analyses such as X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). As $Y_2O_3$ is a high-k material, the electro-optical properties of the twisted nematic (TN) cells were superior to those of conventional TN cells based on a rubbed polymer, with an LC rising time of 4.1ms and falling time of 2.9ms. The IB-irradiated $Y_2O_3$ is a good alternative as an alignment layer for fast-switching TN LC displays.

• Structural Engineering and Mechanics
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• 제69권6호
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• pp.607-614
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• 2019

The present investigation has focus on the study of deformation due to thermomechanical sources in a thick circular plate. The thick circular plate is homogeneous, transversely isotropic with two temperatures and without energy dissipation. The upper and lower surfaces of the thick circular plate are traction free. The Laplace and Hankel transform has been used for finding the general solution to the field equations. The analytical expressions of stresses, conductive temperature and displacement components are computed in the transformed domain. However, the resulting quantities are obtained in the physical domain by using numerical inversion technique. Numerically simulated results are illustrated graphically. The effects of two temperatures by considering different values of temperature parameters are shown on the various components. Some particular cases are also figured out from the present investigation.

• Coupled systems mechanics
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• 제9권6호
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• pp.521-538
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• 2020

The present study is concerned with the thermoelastic interactions in a two dimensional homogeneous, transversely isotropic thermoelastic solid with new modified couple stress theory without energy dissipation and with two temperatures in frequency domain. The time harmonic sources and Hankel transform technique have been employed to find the general solution to the field equations.Concentrated normal force, normal force over the circular region, thermal point source and thermal source over the circular region have been taken to illustrate the application of the approach. The components of displacements, stress, couple stress and conductive temperature distribution are obtained in the transformed domain. The resulting quantities are obtained in the physical domain by using numerical inversion technique. Numerically simulated results are depicted graphically to show the effect of angular frequency on the resulted quantities.

• Bulletin of the Korean Chemical Society
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• 제4권4호
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• pp.169-171
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• 1983

It has been found that the acrylonitrile solution of trans-$RhCl(CO)(Ph_3P)_2$ produces propionitrile catalytically at $90^{\circ}C$ under $P_{H_2}$=3 atm. This catalytic hydrogenation proceeds only for a certain period of time producing ca. 50 moles of propionitrile per mole of the rhodium complex. The hydrogenation with trans-$RhCl(CO)(Ph_3P)_2$ in the presence of formaldehyde is much faster than in the absence of formaldehyde, and continues without a decrease in the rate for a prolonged period of time. It is suggested that the hydrogenation with trans-$RhCl(CO)(Ph_3P)_2$ proceeds through the unsaturated route initiated by the dissociation of CO from trans- $RhCl(CO)(Ph_3P)_2$ to give coordinatively unsaturated $RhCl(Ph_3P)_2$.

• Steel and Composite Structures
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• 제45권6호
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• pp.851-863
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• 2022

This research deals with the study of the Thomson heating effect in magneto-thermoelastic homogeneous isotropic rotating medium, influenced by linearly distributed load and as a result of modified couple stress theory. The charge density is taken as a function of the time of the induced electric current. The heat conduction equation with energy dissipation and with hyperbolic two-temperature (H2T) is used to formulate the model of the problem. Laplace and Fourier transforms are used to solve this mathematical model. Various components of displacement, temperature change, and axial stress as well as couple stress are obtained from the transformed domain. To get the solution in physical domain, numerical inversion techniques have been employed. The Thomson effect with GN (Green-Nagdhi) -III theory and Modified Couple Stress Theory (MCST) is shown graphically on the physical quantities.

• Advances in materials Research
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• 제11권1호
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• pp.23-39
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• 2022

This work deals with the two-dimensional deformation in a homogeneous isotropic nonlocal magneto-thermoelastic solid with two temperatures under the effects of inclined load at different inclinations. The mathematical model has been formulated by subjecting the bounding surface to a concentrated load. The Laplace and Fourier transform techniques have been used for obtaining the solution to the problem in transformed domain. The expressions for nonlocal thermal stresses, displacements and temperature are obtained in the physical domain using a numerical inversion technique. The effects of nonlocal parameter, rotation and inclined load in the physical domain are depicted and illustrated graphically. The results obtained in this paper can be useful for the people who are working in the field of nonlocal thermoelasticity, nonlocal material science, physicists and new material designers. It is found that there is a significant difference due to presence and absence of nonlocal parameter.