• Title/Summary/Keyword: Homogeneous Solution

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Insulation Coating for non-oriented Silicon Steel Sheerts (무방향성 전기강판의 절연피막 코팅재)

  • 조남웅;장세기
    • Journal of the Korean institute of surface engineering
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    • v.30 no.6
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    • pp.382-390
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    • 1997
  • Good appearance of insulation coating is required for non-oriented silicon steel sheets, The property is influenced by both the chemical composition of coating solution and the species of resin. The composition of inorganic-organic coating was studied to obtain good surface quality for non-oriented silicon steel. The greenish degree of coating surface depended on $Cr^{3+}$ content in the coating layer, which was satisfied when chromate content was more than 54.60 wt. %, in the coating solution. The homogeneous pattern and roughness of the coating surface depended on spreading property of the resin. Surface appearance of the coating could be improved by using resin with good spreading property at the chemical composition of chromate 59.00 wt.%.. resin 34.23wt.%, and etyhylene glycol 6.67 wt.% without colloidal sillica.

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Axisymmetric bending of a circular plate with stiff edge on a soft FGM layer

  • Volkov, Sergey S.;Litvinenko, Alexander N.;Aizikovich, Sergey M.;Wang, Yun-Che;Vasiliev, Andrey S.
    • Structural Engineering and Mechanics
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    • v.59 no.2
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    • pp.227-241
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    • 2016
  • A circular plate with constant thickness, finite radius and stiff edge lying on an elastic halfspace is considered. The half-space consists of a soft functionally graded (FGM) layer with arbitrary varying elastic properties and a homogeneous elastic substrate. The plate bends under the action of arbitrary axisymmetric distributed load and response from the elastic half-space. A semi-analytical solution for the problem effective in whole range of geometric (relative layer thickness) and mechanical (elastic properties of coating and substrate, stiffness of the plate) properties is constructed using the bilateral asymptotic method (Aizikovich et al. 2009). Approximated analytical expressions for the contact stresses and deflections of the plate are provided. Numerical results showing the qualitative dependence of the solution from the initial parameters of the problem are obtained with high precision.

Influence of the Precursor Solutions on the Properties of BST Thin Films

  • Kang, Seong-Jun;Joung, Yang-Hee
    • Journal of information and communication convergence engineering
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    • v.1 no.2
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    • pp.70-73
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    • 2003
  • We have studied the effects of solvents and additives in the precursor solutions on the characteristics of barium strontium titanate (BST) thin films. The solution having two solvents, ie. acetic acid for barium acetate and strontium acetate and 2-methoxyethanol for titanium isopropoxide and also having an additive of ethylene glycol shows good stability and remains homogeneous even after a month of ageing. It produces excellent BST thin film without cracks. Dielectric constant, loss tangent at 10KHz and leakage current density at 3V of the BST (70/30) thin film made from this solution are 339, 0.052 and 13.3 ${\mu}\textrm{A}$/$\texmrm{cm}^2$, respectively.

A New Trend in the Sol-Gel Method and Thin Films from Metal Alkoxides

  • Soh, Deawha;Korobova, N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.814-819
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    • 2000
  • The progress in the field of electronic materials has been especially significant for applications involving a range of electrical properties. Its importance is increasing with the increasing demand for integrated circuits. The sol-gel technique has been used for many years, and the metal alkoxides have featured prominently as source materials. The method consist of making a homogeneous solution of the component metal alkoxides in a suitable solvent, usually the parent alcohol; and then causing the hydrolysis under controlled conditions to produce a gel containing the hydrated metal oxide. The gel is then dried, and fired to produce a ceramic or glassy material at a temperature much lower than that required by the conventional melting process. This project consists of important theoretical considerations, processing techniques and applications related to electrophoresis derived thin films. In the electrophoretic process a metal alkoxide solution is gelled through hydrolysis-polymerization and converted the gel thin layer to an oxide by heating at relatively low temperatures.

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NMR Study of Poly(γ-Glutamic Acid)Hydrogels Prepared by γ-Irradiation : Characterization of Bond Formation and Scission

  • 한옥희;최혁준
    • Bulletin of the Korean Chemical Society
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    • v.20 no.8
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    • pp.921-924
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    • 1999
  • Hydrogels were prepared from poly( Υ-glutamic acid) (PGA) solution by g-irradiation of 90 kGy and 170 kGy. The hydrogels were more cross-linked with a higher dosage g-irradiation and completely hydrolyzed at 85℃ within 4 hours resulting in homogeneous solution. NMR techniques were employed to clarify chemical bond formation and scission involved during γ-irradiation and hydrolysis. Characterization of these samples was carried out by taking both liquid state and solid state NMR spectra of PGA and hydrolyzed hydrogels and comparison of these spectra with the solid state NMR spectra of hydrogels. Our results indicate that complicated chemical bond formation and scission have occurred during hydrolysis and γ-irradiation. The samples prepared with higher dosage of γ-irradiation showed more diverse chemical bond formation and scission.

Numerical Calculation of λ-Mode of the Diffusion Equation (수치해법을 이용한 중성자 확산방정식의λ-Mode 계산)

  • Noh, T.W.;Oh, S.K.;Kim, S.Y.;Kim, C.H.
    • Nuclear Engineering and Technology
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    • v.19 no.4
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    • pp.310-316
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    • 1987
  • A successive iteration method to calculate the λ-modes of the diffusion equation was developed. The 2-group, 3-dimensional computer code MOGEN was developed to implement this method, The accuracy of the method was demonstrated using 2-dimensional bare homogeneous rectangular reactor. The numerical solution shows good agreement with the analytic solution in terms of eigenvalue and eigenfunction As for the standard CANDU-600 reactor, the 2-dimensional modes were generated and these represent the conventional mode characteristics well. Finally, application of theλ-mode in reactor engineering problems is described briefly.

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Characteristics of $SnO_2$ Prepared by Preparation Method with Ammonium Nitrate (Ammonium Nitrate를 이용한 침전법으로 제조된 $SnO_2$ 특성분석)

  • Son, Hyang-Ho;Lee, Won-Gyu
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.440-444
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    • 2010
  • $SnO_2$ powders were prepared from the calcination of stannic acids precipitated from the aqueous solution of $SnCl_4$ with ammonium nitrate as a precipitator at $90^{\circ}C$. For the comparison of properties, the stannic acids were prepared from the homogeneous precipitation method using urea as a precipitator at the same temperature. The stannic acid from ammonium nitrate at a thermal gravity analysis showed the weight loss until $700^{\circ}C$ and the percentage of total weight loss was 16.5%. The crystallization of stannic acid into $SnO_2$ finished in the calcination at $600^{\circ}C$ for 2 h. The crystallite size of $SnO_2$ increased with the increase of calcination temperature and initial concentration of $SnCl_4$ solution. In case of the same calcination condition, $SnO_2$ prepared from homogeneous precipitation using urea had a relatively smaller crystallite size rather than $SnO_2$ prepared from ammonium nitrate.

Homogeneous Preparation of Barium Titanate by Dimethyl Oxalate in Ethanol Solution (에탄올 용액에서 Dimethyl Oxalate에 의한 티탄산바륨의 균일한 제조)

  • Ryu, Kyoung-Youl;Lim, Myoung-Hee;Huh, Woo-Young;Lee, Chul
    • Analytical Science and Technology
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    • v.12 no.5
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    • pp.382-386
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    • 1999
  • Spherical particles of barium titanyl oxalate(BTO) were homogeneously precipitated by thermal decomposition of dimethyl oxalate in hydrochloric mixture solutions of water and ethanol. The experimental parameters such as composition of the mixture solvents. the eoncentration of hydrochloric acid and reaction temperature had the paramount effect on the size of panicles collected from the bottom of the reaction vessel at the aging time of 120 min and the composition of BTO. Stoichiometric BTO powders were obtained under certain conditions as relatively low alcohol content in the mixtures, high chloride concentration and high temperature, Monosized, submicrometer, but titanium excess particles were obtained under certain reverse conditions.

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An Investigation of Dynamic Characteristics of Structures Subjected to Dynamic Load from the Viewpoint of Design (동하중을 받는 구조물의 동적특성에 관한 설계 관점에서의 고찰)

  • Lee Hyun-Ah;Kim Yong-Il;Kang Byung-Soo;Kim Joo-Sung;Park Gyung-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.10 s.253
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    • pp.1194-1201
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    • 2006
  • All the loads in the real world are dynamic loads and structural optimization under dynamic loads is very difficult. Thus the dynamic loads are often transformed to static loads by dynamic factors, which are believed equivalent to the dynamic loads. However, due to the difference of load characteristics, there can be considerable differences between the results from static and dynamic analyses. When the natural frequency of a structure is high, the dynamic analysis result is similar to that of static analysis due to the small inertia effect on the behavior of the structure. However, if the natural frequency of the structure is low, the inertia effect should not be ignored. Then, the behavior of the dynamic system is different from that of the static system. The difference of the two cases can be explained from the relationship between the homogeneous and the particular solutions of the differential equation that governs the behavior of the structure. Through various examples, the difference between the dynamic analysis and the static analysis are shown. Also dynamic response optimization results are compared with the results with static loads transformed from dynamic loads by dynamic factors, which show the necessity of the design considering dynamic loads.

Cyclic voltammetry characteristics of $MnO_2$ electrode mixed with PVDF in sulfuric acid solution (PVDF로 혼합된 $MnO_2$ 전극의 황산 수용액중의 cyclic voltammetry 특성)

  • Kim, Bong-Seo;Lee, Dong-Yoon;Lee, Hee-Woong;Kim, Hyun-Sik;Lee, Hae-Yon;Chung, Won-Sub
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.82-84
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    • 2002
  • Dimensionally stable anode(DSA) can be used for the electrowinning of non-ferrous metal like as a Zn, and electrolysis of sea water. $MnO_2$ electrode satisfies the requirements of DSA, and has a good cycle life and a low overpotential for oxygen evolution. $MnO_2$ electrodes coated with DMF and PVDF based on Pb alloy produced at several compositions and dry temperatures. The viscosity of solvent used as a binder of $MnO_2$ powder increased with the increasing PVDF contents. When the ratio of PVDF to BMF with the 5 times dipping at the solution mixed with PVDF and DMF was 1/9, the coating thickness was $150{\mu}m$. When the ratio of PVDF to $MnO_2$ was lower than 1/6, the electrode didn't show any reaction irrespective of the concentrations of DMF. However, When the ratio of PVDF to $MnO_2$ was higher than 1/6, the electrode showed a constant current reactions and homogeneous cyclic voltammetry even though at a high cycle. The reason for the high current and homogeneous cyclic voltammetry is the good catalytic reactions of $MnO_2$ powder in electrode. The reactions of Pb electrode coated with $MnO_2$ and PVDF based on the pure Pb electrode.

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