• 제목/요약/키워드: Hole-transporting material

검색결과 68건 처리시간 0.029초

The effect of fullerene on the device performance of organic light-emitting

  • Lee, Jun-Yeob
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1805-1808
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    • 2006
  • In this paper, we describe a versatile use of fullerene(C60) as a charge transporting material for organic light-emitting diodes. The use of fullerene as a buffer layer for an anode, a doping material for hole transport layer, and an electron transport layer was investigated. Fullerene improved the hole injection from an anode to a hole transport layer by lowering the interfacial energy barrier and enhanced the lifetime of the device as a doping material for a hole transport layer. In addition, it was also effective as an electron transporting material to get low driving voltage in the device.

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정공수송층의 변화에 따른 청색 유기 발광 소자의 특성 (Characteristics on the Variation of Hole transporting layer of Blue organic light-emitting diodes)

  • 김구영;박정현;서지훈;이금희;윤승수;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.434-435
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    • 2007
  • We have demonstrated the characteristics on the variation of hole transporting layer in blue organic light-emitting diodes (OLEDs) using new blue fluorescent emitter. We fabricated two types of hole transporting layer structures that one is 4,4',4"-Tris(N-(2-naphthyl)-N-phenyl-amino)-triphenylamine (2-TNATA) of $600{\AA}$ as a hole injection layer, N,N'-diphenyl-N,N'- (2-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB) of $200{\AA}$ as a hole transporting layer and another device is NPB of $500{\AA}$ without the 2-TNATA. The devices without the 2-TNATA showed improved characteristic of the luminance and efficiency.

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정공 및 전자 전달체의 기능기를 가진 공중합체를 사용한 단층형 유기 발광소자의 특성에 관한 연구 (Studies on the Characteristics of Single-Layered Organic EL Device Using a Copolymer Having Hole and Electron Transporting Moieties)

  • 이창호;김승욱;오세용
    • 폴리머
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    • 제26권4호
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    • pp.543-550
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    • 2002
  • 곁사슬에 정공 및 전자 전달체로 triphenylamine moiety와 triazine moiety를 갖는 새로운 공중합체를 합성하였다. ITO/공중합체와 발광물질 (DCM, coumarin 6, DPvBi)/Al으로 구성되는 단층형 유기 EL 소자는 정공 전달 단위체와 전자 전달 단위체 비율이 6:4와 방광물질의 함유량이 30 wt%일 때 최고의 외부 양자 효율을 나타내었다. 특히 위에서 제작한 유기 EL 소자는 각각 발광물질에 상응하는 빨강 (620 nm), 초록 (520 nm)과 파랑색 (450 nm)의 빛을 발광하였다. 최고 휘도는 DC 12V에서 ITO/공중합체 (6:4)와 DCM (30 wt%)/Al으로 구성되는 소자를 구동하였을 때 500 cd/$m^2$이었다.

유기 전기 발광 소자에서 $\alpha$-septithiophene을 이용한 buffer layer의 영향 (The effects of buffer layer using $\alpha$-septithiophene on the organic light emitting diode)

  • 이기욱;임성택;신동명;박종욱;박호철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
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    • pp.53-56
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    • 2002
  • The effect of $\alpha$-septithiophene (${\alpha}-7T$) layers on the organic light emitting diode(OLED) was studied. The ${\alpha}-7T$ was used for a buffer layer in OLED. Hole injection was investigated and improved emission efficiency. The OLEDs structure can be described as indium tin oxide(ITO)/ buffer layer / hole transporting layer / emitting layer / electron transporting layer / LiF / Al. The hole transporting layer were composed of N,N-diphenyl-N,N-di(3-methylphenyl)-1,1-biphenyl-4,4-diamine(TPD), and N,N-di(naphthalene-1-ly)-N,N-diphenyl-benzidine( ${\alpha}$-NPD). The emitting layer, and electron transporting layer consist of tris(8-hydroxyquinolinato) aluminum($Alq_3$). All organic layer were deposited at a background pressure of less than $10^{-6}$ torr using ultra high vacuum (UHV) system. The ${\alpha}-7T$ layer can substitute the hole blocking layer, and improve hole injection properties.

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페로브스카이트 태양전지용 홀 전도체 개발과 비납계 페로브스카이트 연구 동향

  • 송명관
    • 세라미스트
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    • 제21권1호
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    • pp.98-111
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    • 2018
  • The lead-based perovskite (CH3NH3PbI3) material has a high molar coefficient, high crystallinity at low temperature, and long range of balanced electron-hole transport length. In addition, PCE of perovskite solar cells (PSCs) has been dramatically improved by over 22% by amending the electronic quality of perovskite and by using state-of-the-art hole transporting materials (HTMs) such as tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD) due to enhanced charge transport toward the electrode via properly aligned energy levels with respect to the perovskite. Replacing the spiro-OMeTAD with new HTMs with the desired properties of appropriate energy levels, high hole mobility in its pristine form, low cost, and easy processable materials is necessary for attaining highly efficient and stable PSCs, which are anticipated to be truly compatible for practical application. Furthermore, Recently Pb-free perovskite materials much attention as an alternative light-harvesting active layer material instead of lead based perovskite in photovoltaic cells. In this work, we demonstrate a Pb-free perovskite material for the light harvesting and emitter as optoelectronic devices.

Europium complexes 단층과 다층 구조 박막의 전기적ㆍ광학적 특성에 관한 연구 (Studies on The Optical and Electrical Properties if Europium Complexes with Monolayer and Multilayer)

  • 이명호;표상우;이한성;김영관;김정수
    • 한국전기전자재료학회논문지
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    • 제11권10호
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    • pp.871-877
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    • 1998
  • Electroluminescent(EL) devices based on organic materials have been of great interest due to their possible applications for large-area flat-panel displays, where they are attractive because of their capability of multicolor emission, and low operation voltage. In this study, glass substrate/ITO/Eu(TTA)$_3$(phen)/Al, glass substrate/ITO/Eu(TTA)$_3$(phen)/Al and glass substrate/ITO/Eu(TTA)$_3$(phen)/AlQ$_3$/Al structures were fabricated by vacuum evaporation method, where aromatic diamine(TPD) was used as a hole transporting material, Eu(TTA)$_3$(phen) as an emitting material, and Tris(8-hydroxyquinoline) aluminu-m(AlQ$_3$) as an electron transporting layer. Electrolumescent(EL) and I-V characteristics of Eu(TTA)$_3$-(-phen) were investigated. These structures show the red EL spectra, which are almost the same at the PL spectrum of Eu(TTA)$_3$(phen). I-V characteristics of this structure show that turn-on voltage was 9V and current density was 0.01A/㎤ at a operation voltage of 9V. Electrical transporting phenomena of these structures were explained using the trapped-charge-limited current model with I-V characteristics.

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혼합된 정공 수송 층을 이용한 유기발광소자의 효율 및 수명 개선 (Improved Efficiency and Lifetime for Organic Light-emitting Devices based on Mixed-hole Transporting Layer)

  • 서지현;박정현;박일흥;김준호;김영관
    • 한국전기전자재료학회논문지
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    • 제20권3호
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    • pp.257-262
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    • 2007
  • Organic light-emitting diodes (OLEDs) with the high efficieney and long lifetime are of growing interest in next-generation displays. Among the factors influencing OLEDs properties, one of unstable factor is $Alq_3$ cationic species caused by the excess holes resided in $Alq_3$ layer. Therefore, we suppressed the accumulation of excess holes by using the mixed-hole transporting layer (MHTL) of NPB and CBP in multilayer green OLEDs. The devices with MHTL showed improved characteristics in the luminous efficiency and lifetime. More characteristics and the carrier transport mechanism will be discussed.

혼합된 정공 수송 층을 이용한 유기발광소자의 효율 및 수명 개선 (Improved Efficiency and Lifetime for Organic Light-Emitting Devices Based on Mixed-Hole Transporting Layer)

  • 서지현;박정현;김준호;김영관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.67-68
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    • 2006
  • Organic light-emitting devices (OLEDs) with the high efficiency and long lifetime are of growing interest in next-generation displays. Among the factors influencing OLEDs properties, one of unstable factor is $Alq_3$ cationic species caused by the excess holes resided in $Alq_3$ layer. Therefore, we suppressed the accumulation of excess holes by using the mixed-hole transporting layer (MHTL) of NPB and CBP in multilayer green OLEDs. The devices with MHTL showed improved characteristics in the luminance efficiency and lifetime. More characteristics and the carrier transport mechanism will be discussed.

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Zn-complex를 이용한 OLED 효율향상에 관한 연구 (A Study on the efficiency improvement of OLED using Zn-Complex)

  • 장윤기;김병상;이범종;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 영호남 합동 학술대회 및 춘계학술대회 논문집 센서 박막 기술교육
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    • pp.23-24
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    • 2006
  • We have synthesized electroluminescence materials. including [2-(2-hydroxyphenyl)benzoxazole] (Zn(HPB)$_2$), [(2-(2-hydroxyphenyl)benzoxazole)(8-hydoxyquinoline)] (Zn(HPB)q) and [(1, 10-phenanthroline)(8-hydroxyquinoline)] Zn(phen)q. The ionization potential (IP) and electron affinity (EA) of each Zn-complex was measured using cyclic-voltammetry (C-V). Basing on the consideration of matched in the energy levels of the materials. We investigated the electron transporting properties of Zn(HPB)q and Zn(phen)q compared with $Alq_3$, and also we investigated the hole blocking properties of Zn(HPB)$_2$, compared with BCP. As a result, we used Zn-complex to enhance the performance of OLED. Therefore, we demonstrate that Zn(HPB)q and Zn(phen)q are useful as an electron transporting material. Zn(HPB)$_2$ is also good a hole blocking material.

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전하수송층에 따른 청색인광 OLED의 전기적.광학적 특성 (Effect of carrier transporting materials on the optical and electrical characteristics of blue phosphorescent organic light emitting devices)

  • 서유석;문대규
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.36-37
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    • 2009
  • We have studied the effect of the hole transporting layers on the device efficiencies blue phosphorescent organic light emitting diodes (PHOLED) with of iridiumIIIbis4,6-di-fluorophenyl-pyridinato-N,C2picolinate (FIrpic) doped 3,5--N,N-dicarbazole-benzene (mCP) host. The highest efficiency of blue PHOLED is strongy dependent on the hole transporting materials, exhibiting the maximum current efficiency.

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