• 통합자연과학논문집
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• 제5권3호
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• pp.195-197
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• 2012

Halogen atoms in a molecule are traditionally considered as electron donors, since they have unshared electrons. Normally when they are bonded, there are three lone pair electrons. These lone pairs can function as Lewis bases. However, when they are bound to electron withdrawing groups, they can act as Lewis acids. Since the situation is similar hydrogen bonding (HB), this type of interaction is named as halogen bonding (XB). This mainly comes from the uneven distribution of electron density around the halogen atoms. Since the electron density around halogen atom opposite to ${\sigma}$-bond is depleted, its electropositive region is called ${\sigma}$-hole. This ${\sigma}$-hole can attract halogen bond acceptors, requiring more stringent directionality compared to HB. Since this interaction mainly comes from electrostatic origin, the geometry tends to be linear. Since the XB energy is comparable to corresponding HB. Still in its infancy, XB shows a broad range of applicability, with potentially more useful properties, compared to corresponding HB.

• 대한기계학회논문집B
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• 제21권2호
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• pp.329-340
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• 1997

A passive control of interaction of condensation shock wave / boundary layer for reducing the strength of condensation shock was conducted experimentally in a 2.5 * 8 cm$^{2}$ indraft type supersonic wind tunnel. The effects of following factors on passive control were investigated: 1) the thickness of porous wall, 2) the diameter of porous hole, and 3) the orientation of porous hole. On the other hand, the location of nonequilibrium condensation region and condensation shock wave was controlled by regulation of the stagnation conditions. Surface static pressure measurements as well as Schlieren observations of the flow field were obtained, and their effects were compared with the results the cases of without passive control. It was found that thinner porous wall, smaller porous hole and FFH orientation for the same cavity size and porosity of 12% are more favourable than the cases of its opposite.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.381-388
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• 2003

The material deficiencies in the form of pre-existing defects can initiated cracks and fractures. The stress distribution and fatigue crack initiation life of engineering materials may be associated with the size, the shape and the relative location of defects contained in the component. The objective of this study is to investigate the effect of arbitrarily located hole defect around the rivet hole of a wing section in monolithic aluminum and Al/GFRP laminates under cyclic bending moment during a service load. The stress distribution and the fatigue crack initiation behavior near a rivet hole of on the relationships between stress concentration factor ($K_t$) and relative position of defects were considered. The test results indicated the features of different stress field. Therefore, the stress concentration factor ($K_t$) and the fatigue crack initiation behavior was illustrated different behavior according to each position of hole defect around the rivet hole in monolithic aluminum and Al/GFRP laminates.

• 한국자기학회지
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• 제26권4호
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• pp.119-123
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• 2016

Cu 원자 4개를 포함한 cubane 구조의 분자자성체의 전기구조 및 자기적 성질을 제1원리의 범밀도함수법을 이용하여 계산하였다. 계산 된 결과, Cu 원자는 +2가를 가지며, 팔면체 배위자중 면내 짧은 4개의 배위산소원자로 인해 3d $x^2-y^2$ hole 궤도를 가지고 있었다. 스핀배열에 따른 총 에너지 계산에서 면내는 반강자성, 면간은 강자성 자기구조가 가장 안정되었다. 교환상호작용 J의 크기는 면내의 J가 훨씬 크고 반강자성 성질을 나타내었으며, 나머지 면간의 J값은 아주 작았다. 이러한 원인은 Cu $x^2-y^2$ hole 궤도정렬로 인하여 면내 강한 초교환상호작용의 결과이다.

• Bulletin of the Korean Chemical Society
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• 제18권8호
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• pp.841-850
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• 1997

A simple molecular theory of mixtures is formulated based on the nonrandom two-fluid lattice-hole theory of fluids. The model is applicable to mixtures over a density range from zero to liquid density. Pure fluids can be completely characterized with only two molecular parameters and an additional binary interaction energy is required for a binary mixture. The thermodynamic properties of ternary and higher order mixtures are completely defined in terms of the pure fluid parameters and the binary interaction energies. The Quantitative prediction of vapor-liquid, and solid-vapor equilibria of various mixtures are demonstrated. The model is useful, in particular, for mixtures whose molecules differ greatly in size. For real mixtures, satisfactory agreements are resulted from experiment. Also, the equation of state (EOS) is characterized well, even the liquid-liquid equilibria behaviors of organic mixtures and polymer solutions with a temperature-dependent binary interaction energy parameter.

• 한국군사과학기술학회지
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• 제4권2호
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• pp.215-224
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• 2001

An experimental investigation was conducted on the interaction of vortices over a delta wing with the leading edge extension for three angles of attack($16^{\circ},\; 24^{\circ} \;and\; 28^{\circ}$) at Reynolds number of $1.76{\times}10^6.$ The experimental data included total pressure contours and velocity vectors using 5-hole probe measurements. Constant total pressure coefficient contours show the LEX vortex moves downward and outboard, while the wing vortex exhibited an inboard and upward migration. At near the trailing edge, these vortices reveal a direct interaction between the wing and LEX vortex, featuring a coiling of vortex cores about each other. The combined effect of the interaction of these two vortices and proximity to the wing surface results in the increase of the suction peak. This is in contrast to the result obtained on the delta wing alone configuration, where the effect of the vortex breakdown was manifested. The interaction of the wing and LEX vortices is more pronounced at higher AOA.

• 한국농공학회지
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• 제15권4호
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• pp.3147-3152
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• 1973

The factors to influence the travelling distance of sprayed particles for the medium range nozzle may by the groove depth of swirl plate, the cap slope, the diameter of cap hole, and pressure. 1. This study was conducted to examine Interaction effects among four factors to the travelling distance. The results of this study are summarized as followa; a) Interaction effects among four factors the groove depth(G), cap slope(C), diameter of cap hole(D), and pressure (P), were significant to influence the travelling distance except for $G{\times}P,\;C{\times}D{\times}P\;and\;G{\times}C{\times}D{\times}P$. b) Interaction effects with the pressure were very smaller than interaction effects among the other factors. c) Effect of change of the groove depth of swirl plate on the travelling distance of sprayed particles was generally a linear, the increasing rate of the change was about 0.345, which was very significant. d) Effect of change of cap slope on the travelling distance was generally a linear or a dull quadratic, the increasing rate was very small. e) Main effect of change of cap slope in the medium range nozzle was very smaller than that of the close range nozzle on the travelling distance, which was estimated by the changing of turning radius of flowing course in nozzle. f) Interaction effect between two factors in the medium range nozzle was more significant than that of the close range nozzle on the travelling distance.

• Structural Engineering and Mechanics
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• 제49권4호
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• pp.427-448
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• 2014

At present, the time of easy oil and gas is over. Now, the largest part of fossil fuels is concentrated in the deepest levels of tectonic structures and in the sea shelves. One of the most cumbersome operations of their extraction is the bore-hole drilling. In connection with austere tectonic and climate conditions, their drivage every so often is associated with great and diversified technological difficulties causing emergencies on frequent occasions. As a rule, they are linked with drill string accidents. A key role in prediction of these situations should play methods of theoretical modelling. For this reason, there is a growing need for development and implementation of new numerical methods for computer simulation of critical and post-critical behavior of drill strings (DSs). In this paper, the processes of non-linear deforming of a DS in cylindrical cavity of a deep bore-hole are considered. On the basis of the theory of curvilinear flexible rods, non-linear constitutive differential equations are deduced. The effects of the longitudinal non-uniform preloading, action of torque and interaction between the DS and the bore-hole surface are taken into account. Owing to the use of curvilinear coordinates in the constraining cylindrical surface and a specially chosen concomitant reference frame, it became possible to separate the desired variables and to reduce the total order of the equation system. To solve it, the method of continuation the solution by parameter and the transfer matrix technique are applied. As a result of the completed numerical analysis, the critical states of the DS loading in the cylindrical channels of inclined bore-holes are found. It is shown that the modes of the post-critical deforming of the DS are associated with its irregular spiral curving prevailing in the zone of bottom-hole-assembly. The possibility of invariant state generation during post-critical deforming is established, condition of its bifurcation is formulated. It is shown that infinite variety of loads can correspond to one geometrical configuration of the DS. They differ each from other by contact force functions.

• 한국음향학회지
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• 제1권1호
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• pp.92-96
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• 1982

In this paper, the interaction of electron and phonon in metals is expressed using Hamiltonian operator as follows. By excahnging phonon energy with in the vicinity of isotropical Fermi surface and using following electron and hole operators. We obtain the interaction of electron and phonon. And new Feynman Graphs are tried with the following conditions on. First, when state transfer state, phonon cannot be created. Second, when state transfer state, phonon cannot be destroyed. Third, when state transfer state, phonon can be created or destroyed. Fourth, when state transfer state, phonon can be created or destroyed.

• 세라미스트
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• 제21권2호
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• pp.19-28
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• 2018

Coulomb drag is an effective probe into interlayer interaction between two electron systems in close proximity. For example, it can be a measure of momentum, phonon, or energy transfer between the two systems. The most exotic phenomenon would be when bosonic indirect excitons (electron-hole pairs) are formed in double layer systems where electrons and holes are populated in the opposite layers. In this review, we present various drag phenomena observed in different double layer electron systems, e.g. GaAs/AlGaAs heterostructures and two-dimensional material based heterostructures. In particular, we address the different behavior of Coulomb drag depending on its origin such as momentum or energy transfer between the two layers and exciton condensation. We also discuss why it is difficult to achieve electron-hole pairs in double layer electron systems in equilibrium.