• Title/Summary/Keyword: Hole Injection

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The Study of Hole Injection Characteristics in Solution-Processed Copper (I) Thiocyanate (CuSCN) Film (용액 공정 처리된 구리(I) 티오시아네이트(CuSCN) 필름의 정공 주입 특성 연구)

  • Eun-Jeong Jang;Baeksang Sung;Sungmin Kwon;Yoonseuk Choi;Jonghee Lee;Jae-Hyun Lee
    • Applied Chemistry for Engineering
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    • v.35 no.1
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    • pp.61-65
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    • 2024
  • The effectiveness of CuSCN as a hole injection layer in large-area organic light-emitting diodes, organic solar cells, and thin-film transistors has been well demonstrated. Therefore, in this study, the surface, optical, and electrical analyses of CuSCN were carried out according to the solution process conditions in order to propose optimized film conditions. Various CuSCN solution concentrations were prepared to determine the film surface characteristics and to determine whether the film surface affects the electrical performance of the device. When the CuSCN solution concentration was low, the CuSCN film was not formed and coated in the form of islands, and when the solution concentration was increased, the CuSCN film was formed uniformly, which contributed to improving the conductivity of the device. In addition, a hole-only device was fabricated to demonstrate the role of CuSCN as a hole transport layer.

A Study on the Spray Atomization Characteristics of a Multi-Hole Diesel Nozzle using PDPA System (PDPA계측에 의한 다공 디젤 노즐의 분무 미립화 특성에 관한 연구)

  • Lee, J.K.;Oh, J.H.;Kang, S.J.;Rho, B.J.
    • Journal of ILASS-Korea
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    • v.4 no.1
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    • pp.45-54
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    • 1999
  • The spray characteristics of a direct injection multi-hole diesel nozzle having the 2-spring nozzle holder were investigated by using the image processing system and a PDPA(phase Bowler particle analyzer) system. The spray tip penetration, the spray angle, and the droplet diameter and velocity with the variation of the pump speed, injection quantity were measured. From, the experiments, we know that there are small droplets which are not to be detected with spray image around the leading edge of the spray. In order to represent the mean characteristics of the intermittent spray very well, it is very important to set the time windows accurately. From the measurements along the axis of the spray, close to the nozzle, the initially injected droplets are overtaken by droplets that follow them. And also there are the maximum axial mean velocity and SMD at the following part of the leading edge of the spray.

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Effect on Electrical Characteristics of OLEDs According to Energy Gap for HIL of Amorphous Fluoropolymer Materials by Simulation (모의시험에서 정공 주입층 물질 AF의 에너지 갭이 OLED의 전기적 특성에 미치는 영향)

  • Han, Hyun-Seok;Kim, Jung-Sik;Kim, Weon-Jong;Lee, Jong-Yong;So, Byung-Mun;Kim, Tae-Wan;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.33-33
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    • 2010
  • Electrical properties of organic light-emitting diodes (OLEDs) were simulated by S.co's program. The OLEDs have stable operating parameters, high luminance, and high efficiency in simulation. The AF stands for amorphous fluoropolymer in simulation, and it was used as a hole-injection layer. In the five structure of OLEDs, an AF layer is sandwiched between the hole-transport layer and the ITO layer to increase the external quantum efficiency. By considering organic light-emitting diodes using an optimal energy gap of AF, it could contribute to the improvement of the efficiency of the device in the simulation.

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A Study on the Optimization of Fuel Injection Nozzle Geometry for Reducing NOx Emission in a Large Diesel Engine (대형 디젤 엔진의 연료 분사 노즐 형상이 NOx 발생량 및 연료소비율에 미치는 영향 연구)

  • Kim Ki-Doo;Ha Ji-Soo;Yoon Wook-Hyeon
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.7
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    • pp.1123-1130
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    • 2004
  • Numerical simulations have been carried out to investigate the effect of nozzle hole geometry on the combustion characteristics of the large diesel engine. 6S90MC-C. Spray and combustion phenomena were examined numerically using FIRE code. Wane breakup and Zeldovich models were adopted to describe the atomization characteristics and NOx formation processes. Predictions on the cylinder peak pressure and NOx emission were first verified with the experimental data to confirm the reliability of numerical calculations. The comparison results showed good agreements within the range of 0.64% and 4.6% respectively. Finally, the effects of fuel spray angle and diameter on the engine performance were investigated numerically to find the optimum nozzle hole geometry considering fuel consumption, NOx emission and heat flux of the combustion chamber wall. It was concluded that the combustion gas recirculation in cylinder by changing fuel injection direction is an effective method to reduce NOx emission by about 10% with increasing fuel oil consumption, 1.4% in a large diesel engine.

Effect of Fuel Nozzle Configuration on the Reduction of NOx Emission in Medium-speed Marine Diesel Engine (연료분사 노즐 형상이 선박용 중형 디젤 엔진의 NOx에 미치는 영향 연구)

  • Yoon, Wook-Hyeon;Kim, Byong-Seok;Ryu, Sung-Hyup;Kim, Ki-Doo;Ha, Ji-Soo
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.13-14
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    • 2005
  • Multi-dimensional combustion analysis and experiment has been carried out to investigate the effects of the injector nozzle hole diameter and number on the NOx formation and fuel consumption in HYUNDAI HiMSEN engine. The behavior of spray and combustion phenomena in diesel engine was examined by FIRE code. Wave breakup and Zeldovich models were adopted to describe the atomization characteristics and NOx formation. Wallfilm model suggested by Mundo, et al. and auto-ignition model suggested by Theobald and Cheng were adopted to investigate the spray-wall interaction characteristics and ignition delay. The information of spray angle and spray tip penetration length was extracted from fuel spray visualization experiment and the fuel injection rate profile was extracted from fuel injection system experiment as an input and verification data for the combustion analysis. Next, the nine different nozzle configurations were simulated to evaluate the effect of injector hole diameter and number on the NOx formation and fuel consumption.

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Improvement of Hybrid EL Efficiency in Nanoparticle EL Devices by Insertion of the Layers of PVK and BaF2

  • Lee, Jun-Woo;Cho, Kyoung-Ah;Kim, Hyun-Suk;Park, Byoung-Jun;Kim, Sang-Sig;Kim, Sung-Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.3
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    • pp.101-105
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    • 2005
  • Electroluminescence(EL) and current-voltage(I-V) characteristics of hybrid EL devices containing Pr and Mn co-doped ZnS nanoparticles were investigated in this study. For the insertion of a hole transport layer of poly (N-vinyl carbazole)(PVK), the current level became lower due to the accumulation of electrons at the interface between PVK and nanoparticles. When both PVK and buffer layer $BaF_2$ were simultaneously introduced, the enhanced EL efficiency and improved I-V characteristics were obtained. This results from the additional increase of hole injection owing to the internal field induced by the significant accumulation of electrons at the interface. The presence of buffer layer $BaF_2$ together with PVK makes it possible the charge accumulation enough to induce the sufficient internal field for further hole injection.

Effects of Hole-Injection Buffer Layer in Organic Light-Emitting Diodes (유기 발광 소자에서 정공 주입 버퍼층의 효과)

  • 정동희;김상걸;오현석;홍진웅;이준웅;김영식;김태완
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.816-825
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    • 2003
  • Current-voltage-luminance characteristics of organic light-emitting diodes (OLEDs) were measured in the temperature range of 10 K~300 K. Indium-tin-oxide (ITO) was used as an anode and aluminum as a cathode in the device. Organic of N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) was used for a hole transporting material, and tris (8-hydroxyquinolinato) aluminum (Alq$_3$) for an electron transporting material and emissive material. And copper phthalocyanine (CuPc), poly(3,4-ethylenedi oxythiophene);poly(styrenesulfonate) (PEDOT:PSS), and poly(N-vinylcarbazole) (PVK) were used for hole-injection buffer layers. From tile analysis of electroluminescence (EL) and photoluminesccnce (PL) spectra of the Alq$_3$, the EL spectrum is more greenish then that of PL. And the temperature-dependent current-voltage characteristics were analyzed in the double and multilayer structure of OLEDS. Electrical conduction mechanism was explained in the region of high-electric and low-electric field. Temperature-dependent luminous efficiency and operating voltage were analyzed from the current-voltage- luminance characteristics of the OLEDS.

Emission Characteristics of Poly(3-alkylthiophene) with TPD Addition (TPD 첨가에 따른 poly(3-alkylthiophene)의 발광특성)

  • 서부완;김주승;구할본;이경섭;박복기;조재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.308-311
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    • 2000
  • The organic electroluminescene (EL) device has gathered much interested because of its potential in materials and simple device fabrication. We fabricated EL device which have a mixed single emitting layer containing N,N'-diphenyl-N,N'-(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine [TPD] and poly(3-hexylthiophene) [P3HT]. The molar ratio between P3HT and TPD chaged with 1:1, 3:1, 5:1, 3:2 and 5:2. EL intensity of ITO/P3HT+TPD/Mg:In devices is enhanced by addition of TPD into P3HT. This can be explained that the energy transfer occurs from TPD to P3HT. Recombination probability increases in emitting layer because that TPD as hole transport material plays a role more injection hole and Mg:In (3.7eV) electrode has low work function make easily electron injection. ITO/P3HT+TPD(5:2)/Mg:In devices emit orange-red light at 28V.

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Comparison of Developmental Efficiency of Murine Somatic Cell Nuclear Transfer Protocol

  • Moon, Jeonghyeon;Jung, Miran;Roh, Sangho
    • Journal of Embryo Transfer
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    • v.32 no.3
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    • pp.81-86
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    • 2017
  • The Somatic cell nuclear transfer (SCNT) method can be applied to various fields such as species conservation, regenerative medicine, farming industries and drug production. However, the efficiency using SCNT is very low for many reasons. One of the troubles of SCNT is that it is highly dependent on the researcher's competence. For that reason, four somatic cell nuclear injection methods were compared to evaluate the effect of hole-sealing process and existence of cytochalasin B (CB) on efficiency of murine SCNT protocol. As a results, the microinjection with the hole-sealing process, the oocyte plasma membrane is inhaled with injection pipette, in HCZB with CB was presented to be the most efficient for the reconstructed in SCNT process. In addition, we demonstrated that the oocytes manipulated in Hepes-CZB medium (HCZB) with CB does not affect the developmental rate and the morphology of the blastocyst during the pre-implantation stage. For this reason, we suggest the microinjection involving hole-sealing in HCZB with CB could improve SCNT process efficiency.

The Properties of Hole Injection and Transport Layers on Polymer Light Emitting Diode (정공 주입층 및 수송층에 따른 고분자 유기발광다이오드의 특성 연구)

  • Shin, Sang-Baie;Chang, Ho-Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.4
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    • pp.37-42
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    • 2007
  • We fabricated the polymer light emitting diodes (PLEDs) with ITO/PEDOT:PSS/PVK/PFO:MEH-PPV/LiF/Al structures. The effect of the thickness of PEDOT:PSS hole injection layer(HIL) on the electrical and optical properties of PLEDs was investigated. In addition, PVK hole transport layer(HTL) was introduced in the PLED device, and compared the properties of the PLEDS with and without PVX layer. All organic film layers were prepared by the spin coating method on the plasma treated ITO/glass substrates. As the thickness of PEDOT:PSS film layer decreased from about 80 nm to 50 nm, the luminance of PLED device increased from $220cd/m^2$에서 $450cd/m^2$. This may be ascribed to the increased transportation efficiency of the holes into the emission layer of PLED. The maximum current density and luminance were obtained fir the PLED device with PVX hole transport layer, showing that the current density and luminance were $268mA/cm^2\;and\;540cd/m^2$ at 12V, respectively. This values were improved by about 14% and 22% in current density and luminance compared with the PLED device without PVK layer.

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